Water-table and discharge changes associated with the 2016–2017 seismic sequence in central Italy: hydrogeological data and a conceptual model for fractured carbonate aquifers

A seismic sequence in central Italy from August 2016 to January 2017 affected groundwater dynamics in fractured carbonate aquifers. Changes in spring discharge, water-table position, and streamflow were recorded for several months following nine Mw 5.0–6.5 seismic events. Data from 22 measurement sites, located within 100 km of the epicentral zones, were analyzed. The intensity of the induced changes were correlated with seismic magnitude and distance to epicenters. The additional post-seismic discharge from rivers and springs was found to be higher than 9 m³/s, totaling more than 0.1 km³ of groundwater release over 6 months. This huge and unexpected contribution increased streamflow in narrow mountainous valleys to previously unmeasured peak values. Analogously to the L’Aquila 2009 post-earthquake phenomenon, these hydrogeological changes might reflect an increase of bulk hydraulic conductivity at the aquifer scale, which would increase hydraulic heads in the discharge zones and lower them in some recharge areas. The observed changes may also be partly due to other mechanisms, such as shaking and/or squeezing effects related to intense subsidence in the core of the affected area, where effects had maximum extent, or breaching of hydraulic barriers.

     

Variability of the apparent quantum efficiency of CO photoproduction in the Gulf of Maine and Northwest Atlantic

The photochemical oxidation of colored, dissolved organic matter (CDOM) is important for carbon cycling in the ocean. This oxidation process produces a number of products, including carbon monoxide (CO). While the photochemical production efficiency of CO (apparent quantum yield, AQY, defined in terms of CDOM absorbance) has been reported to be similar for many water types, a full evaluation of the observed natural variability in CO AQY requires additional study. Here we use a polychromatic irradiation system to determine twenty AQY spectra at sea on fresh samples ranging from the near coastal waters of the Gulf of Maine to the offshore waters of the Northwest Atlantic. Despite the geographic variability of these marine samples the AQY of CO production in the Gulf of Maine and Northwest Atlantic exhibited only a small degree of variability, none of which was not correlated with measured environmental parameters. Consequently, a single aggregate AQY spectrum _λ = e^{(−(9.134+0.0425(λ−290)))+e(−(11.316+0.0142(λ−290)))} was found to adequately represent the entire data set. Significantly, the accuracy of an AQY spectrum determined using this multispectral/statistical technique was confirmed with data obtained from a monochromatic irradiation technique on a single open ocean sample. Taken together, the AQY spectra determined in this study were similar in magnitude and shape to those previously published for marine samples and, overall, were somewhat lower than those previously reported for freshwater studies.     

Impact cratering in H2O‐bearing targets on Mars: Thermal field under craters as starting conditions for hydrothermal activity

Abstract– We present a case modeling study of impact crater formation in H₂O‐bearing targets. The main goal of this work was to investigate the postimpact thermal state of the rock layers modified in the formation of hypervelocity impact craters. We present model results for a target consisting of a mixture of H₂O‐ice and rock, assuming an ice/water content variable with depth. Our model results, combined with results from previous work using dry targets, indicate that for craters larger than about 30 km in diameter, the onset of postimpact hydrothermal circulation is characterized by two stages: first, the formation of a mostly dry, hot central uplift followed by water beginning to flow in and circulate through the initially dry and hot uplifted crustal rocks. The postimpact thermal field in the periphery of the crater is dependent on crater size: in midsize craters, 30–50 km in diameter, crater walls are not strongly heated in the impact event, and even though ice present in the rock may initially be heated enough to melt, overall temperatures in the rock remain below melting, undermining the development of a crater‐wide hydrothermal circulation. In large craters (with diameters more than 100 km or so), the region underneath the crater floor and walls is heated well above the melting point of ice, thus facilitating the onset of an extended hydrothermal circulation. These results provide preliminary constraints in characterizing the many water‐related features, both morphologic and spectroscopic, that high‐resolution images of Mars are now detecting within many Martian craters.     

Atmospheric input of nitrogen into the North Sea: ANICE project overview

The aim of the atmospheric nitrogen inputs into the coastal ecosystem (ANICE) project is to improve transport–chemistry models that estimate nitrogen deposition to the sea. To achieve this, experimental and modelling work is being conducted which aims to improve understanding of the processes involved in the chemical transformation, transport and deposition of atmospheric nitrogen compounds. Of particular emphasis within ANICE is the influence of coastal zone processes. Both short episodes with high deposition and chronic nitrogen inputs are considered in the project. The improved transport–chemistry models will be used to assess the atmospheric inputs of nitrogen compounds into the European regional seas (the North Sea is studied as a prototype) and evaluate the impact of various emission reduction strategies on the atmospheric nitrogen loads. Assessment of the impact of atmospheric nitrogen on coastal ecosystems will be based on comparisons of phytoplankton nitrogen requirements, other external nitrogen inputs to the ANICE area of interest and the direct nitrogen fluxes provided by ANICE. Selected results from both the experimental and modelling components are presented here. The experimental results show the large spatial and temporal variability in the concentrations of gaseous nitrogen compounds, and their influences on fluxes. Model calculations show the strong variation of both concentrations and gradients of nitric acid at fetches of up to 25 km. Aerosol concentrations also show high temporal variability and experimental evidence for the reaction between nitric acid and sea salt aerosol is provided by size-segregated aerosol composition measured at both sides of the North Sea. In several occasions throughout the experimental period, air mass back trajectory analysis showed connected flow between the two sampling sites (the Weybourne Atmospheric Observatory on the North Norfolk coast of the UK and Meetpost Noordwijk, a research tower at 9 km off the Dutch coast). Results from the METRAS/SEMA mesoscale chemistry transport model system for one of these cases are presented. Measurements of aerosol and rain chemical composition, using equipment mounted on a commercial ferry, show variations in composition across the North Sea. These measurements have been compared to results obtained with the transport–chemistry model ACDEP which calculates the atmospheric inputs into the whole North Sea area. Finally, the results will be made available for the assessment of the impact of atmospheric nitrogen on coastal ecosystems.     

Origin and emplacement of ultramafic–mafic intrusions in the Erro-Tobbio mantle peridotite (Ligurian Alps, Italy)

The Erro-Tobbio peridotites (Voltri Massif, Ligurian Alps) represent subcontinental lithospheric mantle tectonically exhumed during Permo–Mesozoic extension of the Europe–Adria lithosphere. Previous studies have shown that exhumation started during Permian times, and occurred along kilometer-scale lithospheric shear zones which enhanced progressive deformation and recrystallization from spinel- to plagioclase-facies conditions. Ongoing field and petrologic investigations have revealed that the peridotites experienced, during uplift, a composite history of diffuse melt migration and multiple episodes of ultramafic–mafic intrusions. In this paper we present the results of field, structural and petrologic–geochemical investigations into a sector of the Erro-Tobbio peridotite unit that preserves well this multiple intrusion history. Melt impregnation in the peridotites is evidenced by significant plagioclase enrichment and crystallization of unstrained orthopyroxene replacing kinked mantle olivine and clinopyroxene; impregnating melts were thus opx-saturated. Melt–rock interaction caused chemical changes in mantle minerals (e.g. Al decrease and REE increase in cpx; Ti and Cr# enrichment in spinel). Nevertheless, clinopyroxenes still exhibit LREE depletion (Ce_N/Sm_N = 0.006–0.011), indicating a depleted signature for the percolating melts. Melt impregnation was thus related to diffuse porous flow migration of depleted MORB-type melt fractions that modified their compositions towards opx saturation by mantle–melt interaction during ascent. The impregnated peridotites are intruded by a hectometer-scale stratified cumulate body, mostly consisting of troctolites and plagioclase wehrlites, showing gradational, interfingered contacts with the host mantle rocks. Subsequent intrusion events are revealed by the occurrence of olivine gabbros as decameter-wide lenses, variably thick (centimeter- to meter-scale) dykes and thin dykelets, which crosscut both the peridotite foliation and the magmatic layering in the cumulates. Overall, major and trace element compositions of minerals in the intrusives indicate that they represent variably differentiated cumulus products crystallized from rather primitive N-MORB-type aggregated melts. Slightly more evolved compositions are shown by olivine gabbros, relative to the troctolites and plagioclase wehrlites of the cumulate body. Mineral chemistry features (e.g. the Fo–An correlation and high Na, Ti, Mg# in cpx) indicate that the studied intrusive rocks crystallized at moderate pressure conditions (3–5 kbar, i.e. 9–15 km depth). Our study thus points to a progressive transition from porous flow melt migration to emplacement of magmas in fractures, presumably related to progressive change of lithospheric mantle rheology during extension-related uplift and cooling.     

Mitigation Lessons from the July 17, 1998 Papua New Guinea Tsunami

— The July 17, 1998 tsunami killed over 2,100 people, injured at least 800 severely enough to require hospitalization, permanently displaced over 10,000 and disrupted the social and economic framework of the coastal communities of eastern Saundaun Province, Papua New Guinea. Initial response to the disaster was delayed 16 hours because of the failure to communicate the magnitude of the impact outside the affected area. Once the scope of the disaster was known, international assistance was rapid and substantial. Medical teams, supplies, air transport and mobile field hospitals were provided to assist national medical personnel and facilities. Seven care centers were established for the displaced survivors. Nineteen countries and 17 NGOs (Non-Governmental Organizations) donated money, relief and rebuilding supplies valued at over 6 million US$ in addition to substantial contributions from national recovery funds and the Catholic Diocese. The three Malol villages, two Arop, four Sissano and the Warupu village were permanently abandoned and new villages established inland. Closure of the lagoon and restriction of coastal fishing impacted adjacent villages as well as tsunami survivors. By the second anniversary of the tsunami construction of schools, water and sanitation systems and some roads had been completed. Survivors were provided tools and building supplies to construct new homes, canoes and fishing equipment. Relief and recovery efforts were complicated by coordination difficulties among the many responding agencies and organizations, the disruption of daily routines for both survivors and villages hosting the care centers, and the intrusion of outside aid workers in a region that had been isolated before the disaster. Adaptation to the new village sites has been difficult due to their inland locations that are hotter, more insect-infested and have water and sanitation difficulties. The high number of casualties from the tsunami was the result of several factors: Population concentrated in the area of maximum tsunami impact. Date and time of occurrence. Siting of villages on vulnerable sand spits. Failure of residents to self-evacuate after feeling the earthquake. Substantial delay in mobilizing response. However, further losses were likely reduced because of the rapid deployment of air transport and medical teams, and massive international relief support. The tsunami has affected long-term tsunami mitigation in the Sissano region through the relocation of villages, heightened awareness and education programs. It has also had a significant effect on mitigation in other countries by illuminating the potential dangers of landslide-generated tsunamis and in media coverage of tsunami hazards.     

Arcellaceans (thecamoebians) as indicators of land-use change: settlement history of the Swan Lake area, Ontario as a case study

Arcellaceans have been used as indicators of a variety of paleolimnological conditions including pH, eutrophication, oxygen level, and heavy metal contamination, but there has only been limited application of the group to climate and land-use change research. The limnological evolution of Swan Lake in southwestern Ontario was documented using arcellaceans as proxies, and compared to the results of a palynological analysis, with which it closely correlated. The palynological record documents the rapid disappearance of forest by around 1850 as the area was cleared for agriculture and settlements. The change was characterized by a shift in the palynological record from the Woodland to High Diversity assemblages. Similarly the arcellacean fauna changed from the Pre-European Settlement Assemblage to the distinctive low diversity, stressed environment European Deforestation Assemblage. The introduction of high-yield chemical fertilizers in the post World War II era, and the resultant eutrophication of the lake, was clearly recognizable in the palynological record as indicated by the dramatic increase in the algae Pediastrum (High Nutrient Assemblage). This change in farming practice was also identifiable with arcellacean proxies, as indicated by the appearance of the algalphilic Eutrophication Assemblage. The arcellacean Ecologically Destabilized Assemblage dominated the lake for short intervals during the transition between the Pre-European Settlement and European Deforestation assemblages and again at the transition between the European Deforestation and Eutrophication Assemblages, indicative of periods of ecological destabilization as the lake adjusted to new trophic inputs. A stressed environment arcellacean Ecologically Destabilized Assemblage found in a portion of the core estimated to have been deposited between AD 1350 and AD 1700 may provide evidence of an earlier phase of deforestation associated with Huron Indian agricultural practices. The close correlation between the palynological and arcellacean proxy data clearly demonstrates the potential of arcellaceans as land-use change proxies, and indicates that changes in land-use had an almost immediate impact on the Swan Lake ecosystem. This observation raises concerns about the impact that rapid urbanization is having on the environmentally sensitive Oak Ridges Moraine watershed, of which Swan Lake is a part.     

Monitoring Colima Volcano,Mexico, using satellite data

The Colima Volcanic Complex at the western end of the Mexican Volcanic Belt is the most active andesitic volcano in Mexico. Short-wavelength infrared data from the Landsat Thematic Mapper satellite were used to determine the temperature and fractional area of radiant picture elements for two January data acquisitions in 1985 and 1986. The 1986 data showed four 28.5 m by 28.5 m pixels (picture elements) whose hot subpixel components had temperatures ranging from 511–774° C and areas of 1.8–13 m². The 1985 data had no radiating areas above background temperatures. Ground observations and measurements in November 1985 and February 1986 reported the presence of hot fumaroles at the summit with temperatures of 135–895° C. This study demonstrates the utility of satellite data for monitoring volcanic activity.     

Formal proposal for the Bathonian GSSP (Middle Jurassic) in the Ravin du Bès Section (Bas-Auran, SE France)

The Bathonian Global Stratotype Section and Point (GSSP) is proposed at the base of limestone bed RB071 (bed 23 in Sturani 1967) in the Ravin du Bès Section (43° 57′ 38′′ N, 6° 18′ 55′′ E), Bas-Auran area, “Alpes de Haute Provence” French department. The Ravin du Bès Section, as formal candidate GSSP for the base of the Bathonian Stage, satisfies most of the requirements recommended by the International Commission on Stratigraphy: 1) The exposure extends over 13 m in thickness. At the Bajocian-Bathonian transition, no vertical (bio-, ichno- or tapho-) facies changes, condensation, stratigraphic gaps or hiatuses have been recorded. Structural complexity, synsedimentary and tectonic disturbances, or important alterations by metamorphism are not relevant constraints. 2) There is a well-preserved, abundant and diverse fossil record across the boundary interval, with key markers (ammonites and nannofossils) for worldwide correlation. The base of the Bathonian Stage and Zigzag Zone in Bas-Auran corresponds to the first occurrence level of Gonolkites convergens Buckman, which coincides with the first occurrence of Morphoceras parvum Wetzel. Calcareous nannofossils, as secondary global marker, are present in all beds and allow characterizing the Bajocian-Bathonian transition. 3) Regional analyses of sequence stratigraphy and manganese chemostratigraphy are available. Spectral gamma-ray data corroborate an Early Bathonian deepening half-cycle of second order. 4) The criteria of accessibility, conservation and protection are assured by the “Réserve Naturelle Géologique de Haute Provence”. The Cabo Mondego Section (Portugal) is suggested as the Bathonian auxiliary section and point (ASSP) within this GSSP proposal.