Interpretation of Na–Cl–Br Systematics in Sedimentary Basin Brines: Comparison of Concentration, Element Ratio, and Isometric Log-ratio Approaches

Mathematicians and geochemists have long realized that compositional data intrinsically exhibit a structure prone to spurious and induced correlations. This paper demonstrates, using the Na–Cl–Br system, that these mathematical problems are exacerbated in the study of sedimentary basin brines by such processes as the evaporation or dissolution of salts owing to their high salinities. Using two published datasets of Na–Cl–Br data for fluids from the Appalachian Basin, it is shown that log concentration and Na/Br versus Cl/Br methods for displaying solute chemistry may lead to misinterpretation of mixing trends between meteoric waters (for example shallow drinking water aquifers) and basinal brines, partially due to spurious mathematical relationships. An alternative approach, based on the isometric log-ratio transformation of molar concentration data, is developed and presented as an alternative method, free from potential numerical problems of the traditional methods. The utility, intuitiveness, and potential for mathematical problems of the three methods are compared and contrasted. Because the Na–Cl–Br system is a useful tool for sourcing solutes and investigating the evolution of basinal brines, results from this research may impact such critical topics as evaluating sources of brine contamination in the environment (possibly related to oil and gas production), evaluating the behavior of fluids in the reservoir during hydraulic fracturing, and tracking movement of fluids as a result of geologic CO₂ sequestration.     

Network concepts to describe channel importance and change in multichannel systems: test results for the Jamuna River,Bangladesh

Most of the largest rivers on Earth have multiple active channels connected at bifurcations and confluences. At present a method to describe a channel network pattern and changes in the network beyond the simplistic braiding index is unavailable. Our objectives are to test a network approach to understand the character, stability and evolution of a multi‐channel river pattern under natural discharge conditions. We developed a semi‐automatic method to derive a chain‐like directional network from images that represent the multi‐channel river and to connect individual network elements through time. The Jamuna River was taken as an example with a series of Landsat TM and ETM+ images taken at irregular intervals between 1999 and 2004. We quantified the overall importance of individual channels in the entire network using a centrality property. Centrality showed that three reaches can be distinguished along the Jamuna with a different network character: the middle reach has dominantly one important channel, while upstream and downstream there are about two important channels. Temporally, relatively few channels changed dramatically in both low‐flow and high‐flow periods despite the increase of braiding index during a flood. Based on the centrality we calculated a weighted braiding index that represents the number of important channels in the network, which is about two in the Jamuna River and which is larger immediately after floods. We conclude that the network measure centrality provides a novel characterization of river channel networks, highlighting properties and tendencies that have morphological significance. Copyright © 2013 John Wiley & Sons, Ltd.     

Space observations of Transient Luminous Events and associated emissions in the upper atmosphere above thunderstorm areas

Sprites, jets and elves called Transient Luminous Events (TLE), observed in the middle and upper atmosphere above thunderstorms, are the manifestation of intense energy exchanges between the troposphere, stratosphere and mesosphere. Different types of luminous emissions have been identified by ground-based observations, showing the complexity of these phenomena. Space missions showed that transient emissions in the Earth atmosphere are very broad including Radio Frequency (RF), IR to FUV radiations and X-gamma ray emissions called Terrestrial Gamma Flashes (TGF) with energies reaching 30 Mev. However, there are no global observations of these events together. This paper reviews space observations performed up to now and emphasizes the challenges of the future space missions in global measurements of all possible emissions together for the understanding of the physical mechanisms at the origin of these phenomena and their effects on the Earth environment.     

Late Quaternary stratigraphic signature, offshore from the Dutch barrier shoreline

More than 400 km of high-resolution, partially digitally acquired seismic data were collected in a 30 × 60 km area offshore from the Dutch mesotidal barrier island shoreline, in order to analyze the Holocene transgressive sequence.

The investigated area was subaerially exposed during the most recent (Weichselian) Pleistocene lowstand and glaciated during the previous (Saale/Illinoian) glacial period. Sea level was probably at a level comparable to that of the present during the intervening Eem/Sangamonian highstand.

The area's seismic signature is characterized by several levels of channelization, separated by major, area-wide high-amplitude reflectors. The lowermost aerial reflector represents the Saale boulder clay. The largest channel system, which cuts this reflector, was incised during the Older Dryas cooling event and filled during the Allerød warming period. It was subsequently re-incised during the Younger Dryas and refilled during the early Holocene. The most pronounced and extensive reflector represents the base of the Holocene, and almost everywhere equals the planed-off top of the Eem highstand section. This reflector is overlain by aggradational facies, separated by one level of channelization and one planed-off (ravinement?) surface. The most prominent type of seismic facies above the lowermost level of channelization is a set of progradational clinoforms, which is interpreted as a preserved ebb-tidal delta system. This system is associated with the first Holocene shoreline of ca. 7500 yrs BP.

The eastern part of the study area contains sand ridges with a complex pattern of internal cross-stratification. Ridge-crest sediments are very well-sorted with a mean grain size of 2.8-2.6 φ (ca. 0.15 mm), whereas sediments in the troughs are well-sorted with a mean grain size of 1.8-0.8 φ (0.25–0.5 mm). Origin of these ridges is tentatively thought to be related to reworking since 5000 yrs BP, when the dynamic regime was more or less similar to that of the present and sediment supply had decreased substantially.     

A qualitative Natech damage scale for the impact of floods on selected industrial facilities

There is increasing evidence that natural disasters can trigger technological accidents and damage. These so-called Natech accidents can pose a significant risk to regions that are unprepared for responding to them. The European Commission’s Joint Research Centre has recognised the risk associated with Natech events and has started systematic research into Natechs and their underlying dynamics. This work investigates the risk associated with the flooding of industrial installations through an analysis of past case histories and using expert judgement. The potential impact of three levels of flood severity on selected industrial facilities storing and/or processing (eco-)toxic, flammable or explosive materials is analysed qualitatively and a scale is developed that links the flood intensity to the level of potential damage. Our analysis indicates that natural disasters have the potential for triggering hazmat releases and other types of technological accidents. Hence, natural disasters should be considered as separate accident-triggering events in the planning, design and operating stages of industrial facilities that process or store hazardous substances. Our work revealed a lack of detailed information on the occurrence of Natech events which indicates not necessarily a scarcity of Natechs but rather a lack of standardised reporting and record keeping.     

THE IMPACT OF POLITICAL SYSTEMS UPON GEOGRAPHY: THE CASE OF THE FEDERAL REPUBLIC OF GERMANY AND THE GERMAN DEMOCRATIC REPUBLIC

Considering the influence of German geography on the historic development of the discipline in North America, surprisingly little communication takes place between German-speaking and English-speaking geographers today. This report is intended to provide readers of THE PROFESSIONAL GEOGRAPHER with a review of recent events in the German-speaking countries of Europe, giving special attention to ways in which ideological differences have influenced geographic research in the two parts of divided Germany. It also traces the emergence of theoretical-quantitative geography in German research, the rise of applied research, and recent trends in regional geography.     

Palaeosecular variation in Central Mexico over the last 30 000 years: the record from lavas

13 lava flows of known age (ages from ¹⁴C dating), which have been erupted in the last 30 000 years, have been studied to determine the palaeosecular variation of the geomagnetic field in Central Mexico. Samples were taken from two different monogenetic volcanic fields: the Michoacan-Guanajuato volcanic field (six sites) and the Chichinautzin Formation (seven sites), both part of the Transmexican Volcanic Belt. The lavas were studied in detail using rock magnetic methods (magnetic susceptibility at room temperature, low-temperature susceptibility behaviour, hysteresis loops, Curie temperatures), combined with reflected light microscopy, in order to deduce their magnetic mineralogy and the domain states of the magnetic minerals. The magnetic carriers are titanomagnetites, which show differing degrees of high-temperature deuteric oxidation, and seem to be predominantly pseudo-single domain (PSD), though in many cases are probably a mixture of domain states. Mean palaeomagnetic directions and palaeointensity values using Shaw and Thellier techniques were obtained using several specimens from each flow. Our data seem to indicate a sharp easterly swing in declination about 5000 years ago, which is also observed in lake sediments from Central Mexico. The calculated values of the virtual dipole moment (VDM) range from 3.1 to 14.9 × 10²² A m². Our data indicate that the virtual dipole moment seems to have increased gradually in magnitude over the last 30 kyr, with a peak at about 9000 years BP. These are features that have been observed in other parts of the globe and are probably caused by variations in the dipole part of the geomagnetic field.     

Lithostratigraphic and structural controls of ‘tsavorite’ deposits at Lemshuku,Merelani area,Tanzania

The first study of the Lemshuku ‘tsavorite’ mining district is presented. From bottom to top, the lithostratigraphic column corresponds to a metasedimentary sequence composed of quartzite, fine-grained graphitic gneiss, kyanite-graphite gneiss, biotite-almandine gneiss, metasomatized graphitic gneiss and dolomitic marble. ‘Tsavorite’ occurs in quartz veins and rarely as nodular concretions. Two factors control mineralization: (1) lithostratigraphy, with ‘tsavorite’ in association with pyrite and graphite confined to quartz veins within the metasomatized graphitic gneiss; and (2) structure, with the mineralized veins characteristically controlled by tight isoclinal folds associated with shearing.