On correction of loss of mass during Thellier experiments

Determination of geomagnetic paleointensity by the Thellier method compares the decay of natural remanent magnetisation with the gain of a laboratory induced thermoremanent magnetisation. If fragile samples lose some amount of their material after each heating step, the Thellier experiment will be systematically disturbed and paleointensity will be over-estimated. For a lost of 5% of the sample’s mass an over-estimate of 10% in paleointensity is observed. This can easily be corrected by a normalisation to the initial mass of the unheated sample. This is necessary for any fragile materials such as baked clays or when a specimen breaks into pieces during the Thellier experiment.     

Short life-span of the ore-forming system at the Porgera gold deposit, Papua New Guinea: laser 40Ar/39Ar dates for roscoelite, biotite, and hornblende

The Porgera gold deposit, Papua New Guinea, is associated with sodic-alkalic, hypabyssal intrusions of alkali basaltic to mugearitic composition. The intrusions were emplaced into Cretaceous mudstones and siltstones in the latest Miocene, and both igneous and sedimentary rocks are mineralized. Three types of veins occur: (1) magnetite-sulfide - Au-carbonate veins; (2) base-metal sulfide - Au-carbonate veins; and, economically most important, (3) quartz-roscoelite-Au veins and breccias. Magmatic hornblende and biotite, hydrothermal biotite from alteration selvages associated with the magnetite-sulfide - Au veins, and roscoelite were dated using the laser ⁴⁰Ar/³⁹Ar step-heating technique. Magmatic biotite yielded a date of 5.99ǂ.11 Ma (2C error; MSWD=3.7), and two samples of magmatic hornblende provided dates of 6.35ǂ.23 Ma (MSWD=1.0) and 6.3ǂ.7 Ma (MSWD=2.6). Hydrothermal biotite provided a date of 5.98ǂ.13 Ma (MSWD=2.7), and analyses of two roscoelite samples yielded dates of 5.92ǂ.09 Ma (MSWD=2.0) and 5.92ǂ.17 Ma (MSWD=2.0). The date of the magmatic biotite is interpreted to represent the age of the intrusions more accurately than the hornblende dates because small amounts of excess ⁴⁰Ar were present in the hornblende samples. The date for hydrothermal biotite is interpreted to be the age of the alteration associated with the magnetite-sulfide - Au veins (the paragenetically earliest veins), and thus reflects the age of the onset of the mineralizing activity at Porgera. Based on the two dates for roscoelite, the age of the main ore deposition event is interpreted to be 5.92ǂ.08 Ma. The apparent ages for the intrusive and the mineralizing events are thus identical within error, and suggest that the magmatic and ore-forming system at Porgera was short-lived.     

Palaeosecular variation in Central Mexico over the last 30 000 years: the record from lavas

13 lava flows of known age (ages from ¹⁴C dating), which have been erupted in the last 30 000 years, have been studied to determine the palaeosecular variation of the geomagnetic field in Central Mexico. Samples were taken from two different monogenetic volcanic fields: the Michoacan-Guanajuato volcanic field (six sites) and the Chichinautzin Formation (seven sites), both part of the Transmexican Volcanic Belt. The lavas were studied in detail using rock magnetic methods (magnetic susceptibility at room temperature, low-temperature susceptibility behaviour, hysteresis loops, Curie temperatures), combined with reflected light microscopy, in order to deduce their magnetic mineralogy and the domain states of the magnetic minerals. The magnetic carriers are titanomagnetites, which show differing degrees of high-temperature deuteric oxidation, and seem to be predominantly pseudo-single domain (PSD), though in many cases are probably a mixture of domain states. Mean palaeomagnetic directions and palaeointensity values using Shaw and Thellier techniques were obtained using several specimens from each flow. Our data seem to indicate a sharp easterly swing in declination about 5000 years ago, which is also observed in lake sediments from Central Mexico. The calculated values of the virtual dipole moment (VDM) range from 3.1 to 14.9 × 10²² A m². Our data indicate that the virtual dipole moment seems to have increased gradually in magnitude over the last 30 kyr, with a peak at about 9000 years BP. These are features that have been observed in other parts of the globe and are probably caused by variations in the dipole part of the geomagnetic field.     

The Bayesian bridge between simple and universal kriging

Kriging techniques are suited well for evaluation of continuous, spatial phenomena. Bayesian statistics are characterized by using prior qualified guesses on the model parameters. By merging kriging techniques and Bayesian theory, prior guesses may be used in a spatial setting. Partial knowledge of model parameters defines a continuum of models between what is named simple and universal kriging in geostatistical terminology. The Bayesian approach to kriging is developed and discussed, and a case study concerning depth conversion of seismic reflection times is presented.     

Modeling Geospatial Uncertainty of Geometallurgical Variables with Bayesian Models and Hilbert–Kriging

Mathematical Geosciences - In mine planning, geospatial estimates of variables such as comminution indexes and metallurgical recovery are extremely important to locate blocks for which the energy...     

The contribution of urban runoff to organic contaminant levels in harbour sediments near two Norwegian cities

The main aim of the present study was to compare the quality of particle emissions (urban runoff and settling particles in rivers and harbours) to the quality of top-layer bed sediments, for two Norwegian harbours (Oslo and Drammen). A sub-aim was to investigate whether non-industrial urban runoff contributed to the organotin load of sediments, apart from leaching from ship hulls. Time-integrated samples of stormwater runoff were obtained in an innovative manner, by sampling man-holes in the stormwater system. Settling particles were sampled with sediment traps. The study focused on PAHs, PCBs and organotin compounds. Contaminant levels were generally a factor of 2-10 (PAHs) and 3-30 (TBT) lower in emitted riverine and runoff particles than in top-layer bed sediments, except for PCBs in Oslo harbour (only 20-30% lower). Significant levels of tributyltin (TBT; median 140mug/kg) were shown in runoff particles, showing that TBT can also be emitted via urban sources, since the sampled man-holes were not in areas where dry-docking activities take place. Possible land-based TBT sources include long-lasting house paint and use of TBT as PVC stabilizer and timber preservative. Since there are ongoing emissions into the two studied harbour areas, it is concluded that the addition of an actively sorbing capping material such as activated carbon might be the best remediation alternative.