Low-frequency climate variability of an aquaplanet

The long-term variability of an aquaplanet climate is analyzed with a coupled atmosphere–ocean–sea ice general circulation model. The main result of the 20,000 years simulation is a very dominant low-frequency oscillation with a period of approximately 700 years. All compartments of the aquaplanet (atmosphere, ocean, and sea ice) are involved as the climate alternates between warmer and colder states. Comprehensive time series analyses, as well as a comparison between mean states of cold and warm phases, give a detailed picture of the life cycle of the low-frequency oscillation. The warm phases are characterized by ice-free polar waters and a weaker meridional overturning circulation. During cold phases, the poles are completely covered by sea ice (down to 65^° N/S) and the overturning cells in the ocean are stronger. The climate state changes throughout atmosphere and ocean; however, surface areas in high latitudes are especially affected due to the changing sea ice cover. The meridional energy transport in atmosphere and ocean alternates with the climate regime, since the ocean is more efficient in transporting heat poleward when the poles are ice-free.     

Experimental abiotic synthesis of methanol in seafloor hydrothermal systems during diking events

The abiotic synthesis of organic compounds in seafloor hydrothermal systems is one mechanism through which the subsurface environment could be supplied with reduced carbon. A flow-through, fixed-bed laboratory reactor vessel, the Catalytic Reactor Vessel (CRV) system, has been developed to investigate mineral–surface promoted organic synthesis at temperatures up to 400°C and pressures up to 30 MPa, conditions relevant to seafloor hydrothermal systems. Here we present evidence that metastable methanol can be directly synthesized from a gas-rich CO₂–H₂–H₂O mixture in the presence of a mineral substrate. Experiments have been performed without a substrate, with quartz, and with a mixture of quartz and magnetite. Temperatures and pressures in the experiments ranged from 200°C to 350°C and from 15 to 18 MPa, respectively. Maximum conversion of 5.8×10⁻⁴% CO₂ to CH₃OH per hour was measured using a mixture of magnetite and quartz in the reactor. After passivation of the stainless steel reactor vessel, experiments demonstrate that methanol is formed at temperatures up to 350°C in the presence of magnetite, and that the formation rate decreases over time. The experiments also show a loss of surface reactivity at 310°C and a regeneration of surface reactivity with increased temperature up to 350°C. Concentrations of CO₂ and H₂ used in the experiments simulate periodic, localized and dynamic conditions occurring within the seafloor during and immediately following magmatic diking events. High concentrations of CO₂ and H₂ may be generated by dike injection accompanied by exsolution of CO₂ and reaction of dissolved H₂O with FeO in the magma to form H₂. The experiments described here examine how the ephemeral formation of an H₂–CO₂-rich vapor phase within seafloor hydrothermal systems may supply reactants for abiotic organic synthesis reactions. These experiments show that the presence of specific minerals can promote the abiotic synthesis of simple organic molecules from common inorganic reactants such H₂O, CO₂ and H₂ under geologically realistic conditions.