Distribution and alteration of amino acids in bulk DOM along a transect from bay to oceanic waters

A systematic survey of the concentrations and composition of total hydrolyzable amino acids (THAA) in bulk dissolved organic matter (DOM) was conducted at 11 stations along the 137°E transect from bay to oceanic areas in the northwestern Pacific. Concentrations of THAA and their contributions to dissolved organic carbon were high in the bay and coastal areas, declined toward the oceanic area and decreased with depth in the water columns. From the distribution patterns of the relative abundances of amino acids along the transect, individual amino acids were divided into four groups. One group included tyrosine, valine, isoleucine, phenylalanine, leucine and tryptophan, and was considered to represent easily degradable THAA, while glycine and alanine belonged to a more biorefractory group of THAA. Principal components analysis (PCA) was conducted to quantitatively differentiate patterns of amino acid composition. Amino acid groups based on PCA agreed with the groups classified by distribution patterns, indicating that first principal component scores reflected the degree of degradation of THAA in DOM, and were defined as a degradation index (DI). Two amino acids, glycine and alanine, increased in relative abundance with increasing DI, while valine, isoleucine, phenylalanine and leucine decreased with decreasing DI. The agreement indicated that the degradation process was the key factor controlling the quantity and quality of THAA in bulk DOM.     

Intrusion of less saline shelf water into the Kuroshio subsurface layer in the East China Sea

The possible origin and cause of the less saline shelf water detected in the Kuroshio subsurface layer around the shelf edge of the East China Sea are investigated using observational results obtained in May 1998–2001 in conjunction with a dataset archived by Japan Oceanographic Data Center and a numerical model. The observations show that subsurface intrusions of less saline water are always detected in May in layers above 24.5σθ isopycnal surface, and that salinity inversions (i.e., areas in which the less saline water lies beneath the saline water) are detected around the trough of the Kuroshio frontal eddy (or wave). Analyses of the archived dataset reveal that the isopycnal surface of 24.5σθ is the deepest layer of the Kuroshio pycnocline outcropping to the sea surface on the shallow shelf in early spring. Outcropping isopycnals above 24.5σθ encounter a less saline water plume originating from the Changjiang, especially in the western East China Sea. Thereafter, the less saline water moves along isopycnal layers and reaches the Kuroshio front around the shelf edge. Numerical models demonstrate that, when the frontal wave captures the less saline water, the shelf water takes the form of a salinity inversion in the trough because isohalines in the frontal wave have a phase lag between the upper and lower layers in consequence of the baroclinic instability.     

Symmetropy of earthquake patterns: asymmetry and rotation in a disordered seismic source

We demonstrate that the idea of symmetropy can be used for quantification of earthquake patterns. The symmetropy can be considered as a measure of asymmetry. A pattern is richer in asymmetry when the symmetropy is smaller. The specific results of its applications are obtained as follows. In a discrete model of a seismic source with self-organized criticality, the spatial patterns of earthquakes during critical states and sub-critical states are distinguished by the behaviour of the symmetropy: sub-critical patterns show that the symmetropy is approximately a constant but this has various values during critical states. The critical patterns show asymmetric property without any asymmetric force from the outside and without asymmetric intracellular rule. We show that the emergence of asymmetric patterns is a generic feature of dynamic ruptures in our model. Such a generic asymmetry results from the model which is an inherently discrete system consisting of finite-sized cells. These cells may represent geometrical disordered fault zones. We further discuss rotational motions that generate seismic rotational waves. In micromorphic continuum theory, such rotations are attributed to dynamic ruptures in disordered systems. We note that the concept of disorder in this theory is expressed by a set of finite-sized microstructures and is consistent with the concept of disorder modelled in the present study. Thus, we suggest that the spatially asymmetric patterns of earthquakes might be related to the rotational motions, because both come from dynamic ruptures in a discrete fault zone without a well-defined continuum limit.     

Concentrations of 222 Rn, Its Short-Lived Daughters And 212 Pb And Their Ratios Under Complex Atmospheric Conditions And Topography

Atmospheric activity concentrations of ²¹²Pb and short-lived ²²²Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof ²²²Rn, equilibrium-equivalent concentration of ²²²Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of²²²Rn is almost the same as the atmospheric activity concentration of short-lived²²²Rn daughters.The activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of ²²⁰Rn and ²²²Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of ²¹²Pb to that of the short-lived ²²²Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of²²²Rn (the activity concentration of short-lived ²²²Rn daughters) tothe activity concentration of ²²²Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived²²²Rn daughters to that of ²²²Rn during the three observation periods.These differences can be explained by the submergence of paddy fields.     

Configuration of subducting Philippine Sea plate and crustal structure in the central Japan region

A seismic experiment with six explosive sources and 391 seismic stations was conducted in August 2001 in the central Japan region. The crustal velocity structure for the central part of Japan and configuration of the subducting Philippine Sea plate were revealed. A large lateral variation of the thickness of the sedimentary layer was observed, and the P-wave velocity values below the sedimentary layer obtained were 5.3–5.8 km/s. P-wave velocity values for the lower part of upper crust and lower crust were estimated to be 6.0–6.4 and 6.6–6.8 km/s, respectively. The reflected wave from the upper boundary of the subducting Philippine Sea plate was observed on the record sections of several shots. The configuration of the subducting Philippine Sea slab was revealed for depths of 20–35 km. The dip angle of the Philippine Sea plate was estimated to be 26° for a depth range of about 20–26 km. Below this depth, the upper boundary of the subducting Philippine Sea plate is distorted over a depth range of 26–33 km. A large variation of the reflected-wave amplitude with depth along the subducting plate was observed. At a depth of about 20–26 km, the amplitude of the reflected wave is not large, and is explained by the reflected wave at the upper boundary of the subducting oceanic crust. However, the reflected wave from reflection points deeper than 26 km showed a large amplitude that cannot be explained by several reliable velocity models. Some unique seismic structures have to be considered to explain the observed data. Such unique structures will provide important information to know the mechanism of inter-plate earthquakes.     

Subaqueous sand blow deposits induced by the 1995 Hyogo-ken Nanbu Earthquake, Japan

Abstract The 1995 Hyogo-ken Nanbu Earthquake (Mw 6.9) occurred in the region around Kobe City and Awaji Island in south-west Japan. Co-seismic liquefaction caused subsidence of the land and damage to sea wall caissons on the man-made Port Island at Kobe City. A zone 2–3 m wide behind the caissons of the northern wharf on the island subsided into the intertidal zone and a sandy deposit settled into this subsided zone. The depos-it consists of upward-fining sequences that are subdivided into three parts, in ascending order: graded coarse- to medium-grained sand, parallel-laminated fine- to very-fine-grained sand, and massive mud. Grain fabric analysis (employing the anisotropy of magnetic susceptibility method and microscopic measurement) of these sequences shows that there is a remarkable contrast in grain fabric between the lowest portion of the graded sand division and the laminated sand division. The former has a high q -value (magnetic lineation/foliation) and a unimodal orientation of elongate grains in the horizontal plane, but random orientation in the vertical plane. Conversely, the latter is characterized by a low q -value and a grain fabric in which the long axes of the grains have random orientations and are nearly parallel to the plane of deposition. This result shows that the main depositional processes changed from a combination of flow and allied processes to the force of gravity. As still water is essential for gravity to be the dominant factor in deposition, this deposit is regarded as subaqueous sand blow deposits. If this interpretation is correct, the grain fabric produced by gravity alone is a useful criterion for distinguishing between subaqueous sand blow deposits and other liquefaction-induced deposits.     

Victoria Carbonate-Base Metal Gold Deposit and Its Significance in the Mankayan Mineral District, Luzon, Philippines

Abstract. The Victoria gold deposit is a low-sulfidation style epithermal carbonate-base metal gold deposit discovered in 1995 in the Mankayan mineral district, northern Luzon, Philippines. It occurs just south of a high-sulfidation copper-gold orebody (Lepanto enargite deposit) and a porphyry copper-gold orebody (Far Southeast (FSE) deposit). Radiometric dating of the Victoria mineralization yields ages from 1.6 to 1.1 Ma, similar to ages of the Lepanto enargite deposit. Mineralogical, geochemical, fluid inclusion and sulfur isotope studies suggest that the Victoria deposit is not directly related to the late stage of hydrothermal activity that produced the FSE porphyry copper-gold and the Lepanto enargite deposits. The hydrothermal fluids from which Victoria was formed appear to have been derived from the south, and not from the FSE intrusive center to the northeast. This would suggest a regional south to north hydrothermal gradient, consistent with the similar flow within the FSE porphyry-Lepanto enargite system. On a district scale, structures similar to those of the Victoria deposit in trend and nature would be highly prospective, especially if they occur north of identified plutons and volcanic centers.