Phase relations of biotite and stilpnomelane in the greenschist facies

Phase relations of biotite and stilpnomelane and associated silicate minerals have been studied in rocks of the greenschist facies, chiefly from Otago, New Zealand and western Vermont, but also from Scotland, Minnesota-Michigan iron range, and northwest Washington. That stilpnomelane in the greenschicht facies crystallizes initially with nearly all iron in the ferrous state is indicated by chemical analyses, high p-T experiments, and phase relationships. Alteration of stilpnomelane after metamorphism not only oxidizes iron but leaches potassium; corrections for both effects must be made in using analyses of brown stilpnomelane in studies of phase relations. Two discontinuous reactions which produce biotite at the biotite isograd have been identified:

1. muscovite+stilpnomelane+actinolite→ biotite+chlorite+epidote
2. chlorite+microcline→ biotite+muscovite. Biotite produced by the first of these reactions has a limited range of variation in Fe/Mg. As grade advances within the biotite zone more magnesian and ferruginous biotites become stable in consequence of the two continuous reactions:
3. muscovite+actinolite+chlorite→ biotite (Mg-rich)+epidote
4. muscovite+stilpnomelane→ biotite (Fe-rich)+chlorite.

Stilpnomelane is stable in muscovite-free rocks throughout the biotite zone, and even up to the grade at which hornblende becomes stable. Phengitic muscovite is stable throughout the biotite zone in New Zealand and thus apparently does not contribute to the formation of biotite until a higher grade is reached.     

Electrodynamic Disaggregation: Does it Affect Apatite Fission-Track and (U-Th)/He Analyses?

Apatite fission-track and (U-Th)/He analyses require the liberation of intact idiomorphic apatite grains from rock samples. While routinely being carried out by mechanical methods, electrodynamic disaggregation (ED) offers an alternative approach. The high-voltage discharges produced during the ED process create localised temperature peaks (10000 K) along a narrow plasma channel. In apatite, such high temperatures could potentially reduce the length of fission tracks, which start to anneal at temperatures > 60 °C, and could also enhance He diffusion, which becomes significant at 30–40 °C over geological time scales. A comparison of fission-track analyses and (U-Th)/He ages of apatites prepared both by mechanical (jaw crusher, disk mill) and ED processing provides a way of determining whether heating during the latter method has any significant effect. Apatites from three samples of different geological settings (an orthogneiss from Madagascar, the Fish Canyon Tuff, and a muscovite-gneiss from Greece) yielded statistically identical track length distributions compared to samples prepared mechanically. Additionally, (U-Th)/He ages of apatites from a leucogranite from Morocco prepared by both methods were indistinguishable. These first results indicated that during electrodynamic disaggregation apatite crystals were not heated enough to partially anneal the fission tracks or induce significant diffusive loss of He.     

From economic integration to socioeconomic inclusion: day labor worker centers as social intermediaries

Day labor worker centers have emerged as an important mode of regulatory action in the informal economy of major US cities. Research suggests that these organizations are beneficial in improving employment outcomes experienced by migrant workers engaged in this labor market sector. Yet, the extent to which these organizations impact the social integration of this working population remains relatively undeveloped in the literature. Using data from the National Day Labor Survey, we examine the impact of day labor worker centers on the level of social inclusion experienced by migrant day laborers. We find that worker centers have a modest, but statistically significant, impact on the levels of social integration experienced by this working population and that this varies from city to city. Ultimately we argue that the social intermediary role of these organizations may offer a type of counter mobilization necessary to promote the socioeconomic integration of this working population, but that issues of capacity remain.     

Comparison of ground-based and Viking Orbiter measurements of Martian water vapor: Variability of the seasonal cycle

Earth-based observations of Mars atmospheric water vapor, made from McDonald Observatory, are presented for the 1975–1976, 1977–1978, and 1983 apparitions. Comparisons are made with near-simultaneous spacecraft measurements made from the Viking Orbiter MarsAtmospheric Water Detection experiment during 1976–1978 and with previous Earth-based measurements (made since 1964). Differences occur between the behavior in the different years, and may be related to the Mars climate. Measurements during the southern summer in 1969 indicate a factor of three times as much water as is present at this same season in other years.This difference may have resulted from the sublimation of water from the south polar residual cap upon removal of most or all of the CO₂ ice present; sublimation of all the CO₂ ice during some years could be a result of a greater thermal load being placed on the cap due to the presence of differing amounts of atmospheric dust. If substantiated, the water vapor variability will turn out to be a very sensitive indicator of yearly variability in the Martian climate.     

Estimating macropore and matrix flow using the hydrograph separation procedure in an experimental forest plot

This study was conducted to estimate macropore space, macropore flow and matrix flow in an experimental forest plot in the Ouachita Mountains of Arkansas. Lateral soil water fluxes and soil capillary potentials were observed in the isolated plot during applied rainfall experiments. Rainfalls were applied 17 times during the period 17 July to 10 October 1991. The subsurface hydrograph separation technique was used to estimate macropore space, macropore flux and matrix flux. The boundary between macropore and matrix flow was statistically determined by covariance analysis. The maximum estimated lateral macropore space was approximately 0.006 (cm³ cm^?3). The maximum estimated lateral macropore and matrix flow were 0.042 and 0.00066 cm s^?1, respectively. This report also emphasizes the need for further research on the hydrograph separation procedure for estimating macropores and macropore flow.     

Spatial mining of migration patterns from web demographics

Volunteered Geographic Information, social media, and data from Information and Communication Technology are emerging sources of big data that contribute to the development and understanding of the spatiotemporal distribution of human population. However, the inherent anonymity of these crowd-sourced or crowd-harvested data sources lack the socioeconomic and demographic attributes to examine and explain human mobility and spatiotemporal patterns. In this paper, we investigate an Internet-based demographic data source, personal microdata databases publicly accessible on the World Wide Web (hereafter web demographics), as potential sources of aspatial and spatiotemporal information regarding the landscape of human dynamics. The objectives of this paper are twofold: (1) to develop an analytical framework to identify mobile population from web demographics as an individual-level residential history data, and (2) to explore their geographic and demographic patterns of migration. Using web demographics of Vietnamese–Americans in Texas collected in 2010 as a case study, this paper (1) addresses entity resolution and identifies mobile population through the application of a Cost-Sensitive Alternative Decision Tree (CS-ADT) algorithm, (2) investigates migration pathways and clusters to include both short- and long-distance patterns, and (3) analyze the demographic characteristics of mobile population and the functional relationship with travel distance. By linking the physical space at the individual level, this unique methodology attempts to enhance the understanding of human movement at multiple spatial scales.     

The Invasive Species Challenge in Estuarine and Coastal Environments: Marrying Management and Science

Despite the widely acknowledged threat posed by invasive species in coastal estuaries, there are substantial gaps at the intersection of science and policy that are impeding invasive species management. In the face of pressing management needs in coastal and estuarine environments, we advocate that introduced species should receive the kind of management effort dedicated, for example, to reducing pollution. We support our argument with some examples of economic costs of estuarine and coastal introduced species and a summary of recent evidence for the ecological costs. We highlight some of the issues that either thwart or facilitate the successful marriage between science and management of introduced species, including the regulatory framework for management. We use the available information on coastal eradication programs, including case histories of the programs for Caulerpa taxifolia and Spartina alterniflora (and hybrids) in the western USA, to indicate the feasibility of managing introduced species and to help point out how management and science can improve the outcome. We close with a research agenda that focuses primarily on science that will really assist with invasive species management and reflects our own experience and the opinions of managers directly involved with this issue.     

Modeling the effects of bond environment on equilibrium iron isotope fractionation in ferric aquo-chloro complexes

Four or five sets of ab initio models, including Unrestricted Hartree Fock (UHF) and hybrid Density Functional Theory (DFT) are calculated for each species in a series of aqueous ferric aquo-chloro complexes: , , , FeCl₃(H₂O)₃, FeCl₃(H₂O)₂, , FeCl₅H₂O²⁻, , ) in order to determine the relative isotopic fractionation among the complexes, to compare the results of different models for the same complexes, to examine factors that influence the magnitude of the isotopic fractionation, and to compare bond-partner-driven fractionation with redox-driven fractionation.Relative to , all models show a nearly linear decrease in ⁵⁶Fe/⁵⁴Fe as the number of Cl⁻ ions per Fe³⁺ ion increases, with slopes of −0.8‰ to −1.0‰ per Cl⁻ at 20 °C. At 20 °C, 1000 ln β (β = ⁵⁶Fe/⁵⁴Fe reduced partition function ratio relative to a dissociated Fe atom) values range from 8.93‰ to 9.73‰ for , 8.04-9.12‰ for , 7.61-8.73‰ for , 7.14-8.25‰ for , and 3.09-4.41‰ for . The fractionation between and ranges from 1.5‰ to 2.6‰, depending on the model; this is comparable in magnitude to fractionation effects due to Fe³⁺/Fe²⁺ redox reactions. β values from the UHF models are consistently higher than those from the hybrid DFT models.Isotopic fractionation is shown to be sensitive to differences in ligand bond stiffness (above), coordination number, bond length, and the frequency of the asymmetric Fe-X stretching vibrational mode, as predicted by previous theoretical studies. Complexes with smaller coordination numbers have higher 1000 ln β (7.46‰, 5.25‰, and 3.48‰ for , ,, respectively, from the B3LYP/6-31G(d) model). Species with the same number of chlorides but fewer waters also show the effect of coordination number on 1000 ln β: (7.46‰ vs. 7.05‰ for FeCl₃(H₂O)₂ vs. FeCl₃(H₂O)₃ and 5.25‰ vs. 4.94‰ for vs. FeCl₅H₂O²⁻ with the B3LYP/6-31G(d) model). As more Fe-Cl bonds substitute for Fe-OH₂ bonds (with a resulting decrease in β), the lengths of the Fe-Cl bonds and the Fe-O bonds increase.Preliminary modeling of shows an Fe³⁺/Fe²⁺ fractionation of 3.2‰ for the B3LYP/6-31G(d) model, in agreement with previous studies. The addition of an explicit outer hydration sphere of 12 H₂O molecules to models of improves agreement with measured vibrational frequencies and bond lengths; 1000 ln β increases by 0.8-1.0‰. An additional hydration sphere around increases 1000 ln β by only 0.1‰.Isotopic fractionations predicted for this simple system imply that ligands present in an aqueous iron environment are potentially important drivers of fractionation, and suggest that significant fractionation effects are likely in other aqueous systems containing sulfides or organic ligands. Fractionation effects due to both speciation and redox must be considered when interpreting iron isotope fractionations in the geological record.     

Space debris — The short term orbital evolution in the earth gravity field

Two aspects of the orbital evolution of space debris — the long-term evolution and the short-term one — are of interest for an exploration of the near-Earth space. The paper presents some results concerning the estimation of the accuracy of predicted positions of Earth-orbiting objects for the short-term: a few revolutions or a time-span interval of a few days. Calculations of predicted positions take into account the influence of an arbitrary number of spherical coefficients of the Earth gravity potential. Differences in predicted positions due to differences in the best contemporary geopotential models (JGM-2, JGM-3 and GRIM4-S4) are estimated with the use of an analytical theory of motion and a numerical integration.     

Dissipating waves in a hot,compressible, magnetic,structured atmosphere

The damping of ducted, fast, magnetohydrodynamic (MHD) waves by ion viscosity and electron heat conduction in a radiating, optically thin, warm, structured atmosphere has been evaluated. Dissipation is more effective in a warm plasma than in a cold one but, for waves ducted by solar coronal loops, dissipation is only efficient if the periods of the waves are shorter than a few tens of seconds and only if the background magnetic field is less than about 15 G. It appears that MHD waves of longer periods and in stronger magnetic fields will survive the dissipative mechanisms considered here and may be manifest as observable coronal oscillations.