A method to infer past surface mass balance and topography from internal layers in martian polar layered deposits

Internal layers in ice masses can be detected with ice-penetrating radar. In a flowing ice mass, each horizon represents a past surface that has been subsequently buried by accumulation, and strained by ice flow. These layers retain information about relative spatial patterns of accumulation and ablation (mass balance). Internal layers are necessary to accurately infer mass-balance patterns because the ice-surface shape only weakly reflects spatial variations in mass balance. Additional rate-controlling information, such as the layer age, the ice temperature, or the ice-grain sizes and ice-crystal fabric, can be used to infer the absolute rate of mass balance. To infer mass balance from the shapes of internal layers, we solve an inverse problem. The solution to the inverse problem is the best set or sets of unknown boundary conditions or initial conditions that, when used in our calculation of ice-surface elevation and internal-layer shape, generate appropriate predictions of observations that are available. We also show that internal layers can be used to infer martian paleo-surface topography from a past era of ice flow, even though the topography may have been largely altered by subsequent erosion. We have successfully inferred accumulation rates and surface topography from internal layers in Antarctica. Using synthetic data, we demonstrate the ability of this method to solve the corresponding inverse problem to infer accumulation and ablation rates, as well as the surface topography, for martian ice. If past ice flow has affected the shapes of martian internal layers, this method is necessary to infer the spatial pattern and rate of mass balance.     

Spectrographic study of the eclipsing binary system SZ Camelopardalis

Thirteen high-dispersion spectrographs of the eclipsing binary star SZ Cam have been studied with a view of determining more accurate information on: (i) the spectral type and luminosity classifications, (ii) absolute parameters for the component stars, (iii) the stellar environment of SZ Cam. The main results in these categories are as follows: (i) O9.5 Vnk, (ii)m _g=19±2M _⊙,m _s=6.5±1M _⊙;r _g=9.7±3.6R _⊙,r _s=4.8±1.7R _⊙;T _e～30000 K,T _e～23000 K; (iii) there is a local concentration of absorbing material which may reach a density of 2M _⊙ pc^?3, and the distance of the star is found to be 600±150 pc. The determined overluminosity of the secondary star and the local concentration of absorbing material are two topics which provide the basis for a discussion section.     

Tesseral harmonic perturbations for high order and degree harmonics

A new formula has been derived for geopotential expressed in terms of orbital elements. The summation sequence was changed so that the terms of the same frequencies would be grouped and the generalized lumped coefficients were derived. The proposed formula has the same form for both odd and evenl-m.Applying Hori's perturbation method, new formulae were derived for tesseral harmonic perturbations in nonsingular orbital elements:l+g, h, e cosg,e sing, L, andH. We show the possibility of effective application of the derived formulae to the calculation of orbits of very low satellites taking into account the coefficients of tesseral harmonics of the Earth's gravitational field up to high orders and degrees. As an example the perturbations up to the order and degree of 90 for the orbit of GRM satellites were calculated. The calculations were carried out on an IBM AT personal computer.     

Near-infrared spectra of the Galilean satellites: Observations and compositional implications

We have obtained reflectivity spectra of the trailing and leading sides of all four Galilean satellites with circular variable filter wheel spectrometers operating in the 0.7- to 5.5-μm spectral interval. These observations were obtained at an altitude of 41,000 ft from the Kuiper Airborne Observatory. Features seen in these data include a 2.9-μm band present in the spectra of both sides of Callisto; the well-known 1.5-μm and 2.0-μm combination bands and the previously more poorly defined 3.1-μm fundamental of water ice observed in the spectra of both sides of Europa and Ganymede; and features centered at 1.35 ± 0.1, 2.55 ± 0.1, and 4.05 ± 0.05 μm noted in the spectra of both sides of Io. In an effort to interpret these data, we have compared them with laboratory spectra as well as synthetic spectra constructed with a simple multiple-scattering theory. We attribute the 2.9-μm feature of Callisto's spectra primarily to bound water, with the product of fractional abundance of bound water and mean grain radius in micrometers equaling approximately 3.5 × 10^?1 for both sides of the satellite. The fractional amounts of water ice cover on the trailing side of Ganymede, its leading side, and the leading side of Europa were found to be 50 ± 15, 65 ± 15, and 85% or greater, respectively. The bare ground areas on Ganymede have reflectivity properties in the 0.7- to 2.5-μm spectral region comparable to those of Callisto's surface and also have significant quantities of bound water, as does Callisto. Interpretation of the spectrum for the trailing side of Europa is complicated by magnetospheric particle bombardment which causes a perceptible broadening of strong bands, but the ice cover on this side is probably comparable to that on the leading side. These irradiation effects may be responsible for much of the difference in the visual geometric albedos of the two sides of Europa. Minor, but significant, amounts of ferrous-bearing material (either ferrous salts or alkali feldspars but not olivines or pyroxenes) account for the 1.35-μm feature of Io. The two longer wavelength bands are most likely attributable to nitrate salts. Ferrous salts and nitrates can jointly also account for much of the spectral variation in Io's visible reflectivity, thereby eliminating the need to postulate large quantities of sulfur. The absence of noticeable features near 3-μm wavelength in Io's spectra leads to upper bounds of 10% on the fractional cover of water and ammonia ice and 10^?3 on the relative abundance of bound water and hydroxylated material on Io. The two sides of Io have similar compositions. We suggest that the systematic increase in fractional water ice cover from Callisto to Ganymede to Europa is bought about by variations in efficiencies of recoating the satellite's surface by interior water brought to the surface, and by the deposition of extrinsic dust. The most important component of the latter is debris, derived from the outer irregular satellites of Jupiter, which impacts the Galilean satellites at relatively low velocities. Europa has the largest water ice cover because its crust is thinnest and thus the frequency of water recoating is the greatest, and because it is farthest from the sources of low-velocity dust. While models which depict Io's surface as consisting primarily of very fine-grained ice are no longer viable, we are unable to definitively distinguish between the salt assemblage and alkali feldspar models. The salt model can better account for Io's reflectivity spectrum from 0.3 to 5 μm, but the absence of appreciable quantities of bound water and hydroxylated material may not be readily understood within the context of that model.     

“Sweating meteorites”—Water‐soluble salts and temperature variation in ordinary chondrites and soil from the hot desert of Oman

The common appearance of hygroscopic brine (“sweating”) on ordinary chondrites (OCs) from Oman during storage under room conditions initiated a study on the role of water‐soluble salts on the weathering of OCs. Analyses of leachates from OCs and soils, combined with petrography of alteration features and a 11‐month record of in situ meteorite and soil temperatures, are used to evaluate the role of salts in OC weathering. Main soluble ions in soils are Ca²⁺, SO₄^2?, HCO₃^?, Na⁺, and Cl^?, while OC leachates are dominated by Mg²⁺ (from meteoritic olivine), Ca²⁺ (from soil), Cl^? (from soil), SO₄^2? (from meteoritic troilite and soil), and iron (meteoritic). “Sweating meteorites” mainly contain Mg²⁺ and Cl^?. The median Na/Cl mass ratio of leachates changes from 0.65 in soils to 0.07 in meteorites, indicating the precipitation of a Na‐rich phase or loss of an efflorescent Na‐salt. The total concentrations of water‐soluble ions in bulk OCs ranges from 600 to 9000 μg g^?1 (median 2500 μg g^?1) as compared to 187–14140 μg g^?1 in soils (median 1148 μg g^?1). Soil salts dissolved by rain water are soaked up by meteorites by capillary forces. Daily heating (up to 66.3 °C) and cooling of the meteorites cause a pumping effect, resulting in a strong concentration of soluble ions in meteorites over time. The concentrations of water‐soluble ions in meteorites, which are complex mixtures of ions from the soil and from oxidation and hydrolysis of meteoritic material, depend on the degree of weathering and are highest at W3. Input of soil contaminants generally dominates over the ions mobilized from meteorites. Silicate hydrolysis preferentially affects olivine and is enhanced by sulfide oxidation, producing local acidic conditions as evidenced by jarosite. Plagioclase weathering is negligible. After completion of troilite oxidation, the rate of chemical weathering slows down with continuing Ca‐sulfate contamination.     

Automatic optimized discovery, creation and processing of astronomical catalogs

We present the design of a novel way of handling astronomical catalogs in Astro-WISE in order to achieve the scalability required for the data produced by large scale surveys. A high level of automation and abstraction is achieved in order to facilitate interoperation with visualization software for interactive exploration. At the same time flexibility in processing is enhanced and data is shared implicitly between scientists. This is accomplished by using a data model that primarily stores how catalogs are derived; the contents of the catalogs are only created when necessary and stored only when beneficial for performance. Discovery of existing catalogs and creation of new catalogs is done through the same process by directly requesting the final set of sources (astronomical objects) and attributes (physical properties) that is required, for example from within visualization software. New catalogs are automatically created to provide attributes of sources for which no suitable existing catalogs can be found. These catalogs are defined to contain the new attributes on the largest set of sources the calculation of the attributes is applicable to, facilitating reuse for future data requests. Subsequently, only those parts of the catalogs that are required for the requested end product are actually processed, ensuring scalability. The presented mechanisms primarily determine which catalogs are created and what data has to be processed and stored: the actual processing and storage itself is left to existing functionality of the underlying information system.     

Theoretical estimates of equilibrium chlorine-isotope fractionations

Equilibrium chlorine-isotope (³⁷Cl/³⁵Cl) fractionations have been determined by using published vibrational spectra and force-field modeling to calculate reduced partition function ratios for Cl-isotope exchange. Ab initio force fields calculated at the HF/6-31G(d) level are used to estimate unknown vibrational frequencies of ³⁷Cl-bearing molecules, whereas crystalline phases are modeled by published lattice-dynamics models. Calculated fractionations are principally controlled by the oxidation state of Cl and its bond partners. Molecular mass (or the absence of C-H bonds) also appears to play a role in determining relative fractionations among simple Cl-bearing organic species. Molecules and complexes with oxidized Cl (i.e., Cl⁰, Cl⁺, etc.) will concentrate ³⁷Cl relative to chlorides (substances with Cl⁻). At 298 K, ClO₂ (containing Cl⁴⁺) and [ClO₄]⁻ (containing Cl⁷⁺) will concentrate ³⁷Cl relative to chlorides by as much as 27‰ and 73‰, respectively, in rough agreement with earlier calculations. Among chlorides, ³⁷Cl will be concentrated in substances where Cl is bonded to +2 cations (i.e., FeCl₂, MnCl₂, micas, and amphiboles) relative to substances where Cl is bonded to +1 cations (such as NaCl) by ∼2 to 3‰ at 298 K; organic molecules with C-Cl bonds will be even richer in ³⁷Cl (∼5 to 9‰ at 298 K). Precipitation experiments, in combination with our results, provide an estimate for Cl-isotope partitioning in brines and suggest that silicates (to the extent that their Cl atoms are associated with nearest-neighbor +2 cations analogous with FeCl₂ and MnCl₂) will have higher ³⁷Cl/³⁵Cl ratios than coexisting brine (by ∼2 to 3‰ at room temperature). Calculated fractionations between HCl and Cl₂, and between brines and such alteration minerals, are in qualitative agreement with both experimental results and systematics observed in natural samples. Our results suggest that Cl-bearing organic molecules will have markedly higher ³⁷Cl/³⁵Cl ratios (by 5.8‰ to 8.5‰ at 295 K) than coexisting aqueous solutions at equilibrium. Predicted fractionations are consistent with the presence of an isotopically heavy reservoir of HCl that is in exchange equilibrium with Cl⁻_aq in large marine aerosols.