Evidence for Hesperian impact-induced hydrothermalism on Mars

Several hydrated silicate deposits on Mars are observed within craters and are interpreted as excavated Noachian material. Toro crater (71.8°E, 17.0°N), located on the northern edge of the Syrtis Major Volcanic Plains, shows spectral and morphologic evidence of impact-induced hydrothermal activity. Spectroscopic observations were used to identify extensive hydrated silicate deposits, including prehnite, chlorites, smectites, and opaline material, a suite of phases that frequently results from hydrothermal alteration in terrestrial craters and also expected on Mars from geochemical modeling of hydrothermal environments. When combined with altimetry and high-resolution imaging data, these deposits appear associated predominantly with the central uplift and with portions of the northern part of the crater floor. Detailed geologic mapping of these deposits reveals geomorphic features that are consistent with hydrothermal activity that followed the impact event, including vent-like and conical mound structures, and a complex network of tectonic structures caused by fluid interactions such as fractures and joints. The crater age has been calculated from the cumulative crater size-frequency distributions and is found to be Early Hesperian. The evidence presented here provides support for impact-induced hydrothermal activity in Toro crater, that extends phyllosilicate formation processes beyond the Noachian era.     

Eco-hydrological role of deep aquifers in the Salado sedimentary basin in the Province of Buenos Aires,Argentina

Although not well known, the eco-hydrological functions of deep aquifers (those having no contact with surface hydrological events) play an important role in the hydrological regime because they can affect the type of habitats, the availability of water and nutrients and the salinity of the medium, among other environmental features. This work aims at characterizing the deep Tertiary hydrogeological units of the Salado sedimentary basin in the Province of Buenos Aires, Argentina, at a regional scale, and to determine their environmental importance in the hydrological cycle. The geological characterization of the study area is based on the drilling profiles from oil exploration wells bored by different oil companies between 1948 and 1994, and also from the existing literature. The conclusion is that water exchange between quaternary surface aquifers in contact with atmospheric events and deep tertiary aquifers is one of the main processes that keep the hydrologic balance of the region. Not only is this crucial for the conservation of the numerous and well-developed ecosystems in the basin wetlands, but also significant for the agricultural and cattle-raising activities of the region.     

Enhancement of the benthic communities around an isolated island in the Antarctic Ocean

Insular marine biotas are often richer in faunal diversity than those from the open sea in the same geographical region. The existence of particular island effects were tested under polar conditions by comparing infaunal benthic assemblages on Peter I Island with those of similar latitudes in the open ocean at the Bellingshausen Sea and also from the coast of the Antarctic Peninsula. Sampling was carried out aboard the R/V Hespérides during the expedition named BENTART-2003 from 24 January to 3 March 2003. Benthic samples were collected at 18 stations ranging from 90 to 2 044 m depth, using an USNEL-type box corer (BC) dredge. Representatives of 32 higher taxa of invertebrates were found. Univariate and multivariate analyses revealed various patterns in the data. First, significant differences in polychaete abundance were detected between the stations located in the open sea and the remaining sites (island plus mainland sites). Bivalve abundances were also distinct between island and mainland sampling sites. Sediment columns taken from the island seafloor exhibited the highest rate of bioturbation by the infauna. These findings confirm the model that islands develop distinct assemblages characterized by the enhancement of the benthic communities even in cold waters. Several abiotic factors were measured simultaneously at the seafloor and along the water column to investigate faunal distribution patterns. Significant correlations were found between the benthic assemblages and a combination of two environmental variables: "island effect" (measured as a categorical variable) and the redox state of sediments. Richer and more complex benthic assemblages were found in Peter I Island’s sea bottom, whereas the more depauperate bottoms remained in the open sea.     

Magnetic field modulated dust streams from Jupiter in interplanetary space

High speed dust streams emanating from near Jupiter were first discovered by the Ulysses spacecraft in 1992. Since then the phenomenon has been re-observed by Galileo in 1995, Cassini in 2000, and Ulysses in 2004. The dust grains are expected to be charged to a potential of , which is sufficient to allow the planet's magnetic field to accelerate them away from the planet, where they are subsequently influenced by the interplanetary magnetic field (IMF). A similar phenomenon was observed near Saturn by Cassini. Here, we report and analyze simultaneous dust, IMF and solar wind data for all dust streams from the two Ulysses Jupiter flybys. We find that compression regions (CRs) in the IMF – regions of enhanced magnetic field – precede most dust streams. Furthermore, the duration of a dust stream is roughly comparable with that of the precedent CR, and the occurrence of a dust stream and the occurrence of the previous CR are separated by a time interval that depends on the distance to Jupiter. The intensity of the dust streams and their precedent CRs are also correlated, but this correlation is only evident at distances from the planet no greater than 2 AU. Combining these observations, we argue that CRs strongly affect dust streams, probably by deflecting dust grain trajectories, so that they can reach the spacecraft and be detected by its dust sensor.     

Analysis of Titan CH4 3.3 μm upper atmospheric emission as measured by Cassini/VIMS

After molecular nitrogen, methane is the most abundant species in Titan’s atmosphere and plays a major role in its energy budget and its chemistry. Methane has strong bands at 3.3 μm emitting mainly at daytime after absorption of solar radiation. This emission is strongly affected by non-local thermodynamic equilibrium (non-LTE) in Titan’s upper atmosphere and, hence, an accurate modeling of the non-LTE populations of the emitting vibrational levels is necessary for its analysis. We present a sophisticated and extensive non-LTE model which considers 22 CH₄ levels and takes into account all known excitation mechanisms in which they take part. Solar absorption is the major excitation process controlling the population of the v₃-quanta levels above 1000 km whereas the distribution of the vibrational energy within levels of similar energy through collisions with N₂ is also of importance below that altitude. CH₄-CH₄ vibrational exchange of v₄-quanta affects their population below 500 km. We found that the ν₃ → ground band dominates Titan’s 3.3 μm daytime limb radiance above 750 km whereas the ν₃ + ν₄ → ν₄ band does below that altitude and down to 300 km. The ν₃ + ν₂ → ν₂, the 2ν₃ → ν₃, and the ¹³CH₄ν₃ → ground bands each contribute from 5% to 8% at regions below 800 km. The ν₃ + 2ν₄ → 2ν₄and ν₂ + ν₃ + ν₄ → ν₂ + ν₄ bands each contribute from 2% to 5% below 650 km. Contributions from other CH₄ bands are negligible. We have used the non-LTE model to retrieve the CH₄ abundance from 500 to 1100 km in the southern hemisphere from Cassini-VIMS daytime measurements near 3.3 μm. Our retrievals show good agreement with previous measurements and model results, supporting a weak deviation from well mixed values from the lower atmosphere up to 1000 km.     

On the Impact of Anthropogenic Heat Fluxes on the Urban Boundary Layer: A Two-Dimensional Numerical Study

The heat generated in buildings and the manner in which this heat is exchanged with the ambient environment can play an important role in urban climate. Recent studies have shown that anthropogenic heat from air-conditioning facilities can increase the exterior ambient temperature and should be taken into account for a more complete urban heat island (UHI) mitigation study. For this purpose, the first part of the present work is focused on the coupling of a new building energy model (BEM) and an urban canopy parameterisation (UCP). The new scheme is implemented in a finite volume mesoscale model (MM) and tested in a two-dimensional (2D) configuration of a city over flat terrain. A sensitivity study is performed with respect to different parameters in order to test the simulation system and enhance the understanding of the possible impacts of the BEM on the exterior microclimate.     

Plant community patterns in a gypsum area of NE Spain. II. Effects of ion washing on topographic distribution of vegetation

A model, based on the physico-chemical properties of gypsum, is postulated in order to interpret the regular distribution of plant communities associated with the topography and the main environmental stresses to which each vegetation type is subjected in a landscape unit.The leaf chemical composition of 28 representative plant species supports the main predictions of the model: species from low areas present large concentrations of Na, N and ash but low contents of Ca. It is demonstrated that the strong nutrient and salt downwashing in the hilly terrain is an important cause of the vegetation segregation observed on a large spatial scale.     

A new Building Energy Model coupled with an Urban Canopy Parameterization for urban climate simulations—part II. Validation with one dimension off-line simulations

Recent studies show that the fluxes exchanged between buildings and the atmosphere play an important role in the urban climate. These fluxes are taken into account in mesoscale models considering new and more complex Urban Canopy Parameterizations (UCP). A standard methodology to test an UCP is to use one-dimensional (1D) off-line simulations. In this contribution, an UCP with and without a Building Energy Model (BEM) is run 1D off-line and the results are compared against the experimental data obtained in the BUBBLE measuring campaign over Basel (Switzerland) in 2002. The advantage of BEM is that it computes the evolution of the indoor building temperature as a function of energy production and consumption in the building, the radiation coming through the windows, and the fluxes of heat exchanged through the walls and roofs as well as the impact of the air conditioning system. This evaluation exercise is particularly significant since, for the period simulated, indoor temperatures were recorded. Different statistical parameters have been calculated over the entire simulated episode in order to compare the two versions of the UCP against measurements. In conclusion, with this work, we want to study the effect of BEM on the different turbulent fluxes and exploit the new possibilities that the UCP–BEM offers us, like the impact of the air conditioning systems and the evaluation of their energy consumption.     

Clinopyroxene/liquid trace element partitioning in natural trachyte–trachyphonolite systems: insights from Campi Flegrei (southern Italy)

Trace element partition coefficients between clinopyroxenes and associated glassy matrix (^Cpx/L D) have been determined for 13 REE, HFSE^4+,5+, U, Th, Sr, Pb, Sc and V from combined LA-ICP-MS/EMP analyses in selected trachytes and trachyphonolites from Campi Flegrei. Composition of clinopyroxene and glass is pretty homogeneous in the trachyphonolites, pointing to an overall attainment of the equilibrium conditions. In trachytes, conversely, phases show some compositional heterogeneity (due to the presence of clinopyroxene xenocrysts) that requested a more careful petrographic and geochemical inspection of the samples to assess the equilibrium clinopyroxene composition. In the trachyte clinopyroxenes, REE are compatible from Nd to Lu (^Cpx/L D up to 2.9), like Y, Ti, Sc and V. The ^Cpx/L D for Eu is lower than those of the adjacent REE, highlighting Eu²⁺ contribution. High D values are also shown by U, Th, Pb, Zr, Hf, Nb and Ta relatively to basaltic and andesitic systems, whereas the D _Sr is roughly similar to that found for less evolved magmas. Trachyphonolites are characterized by an overall decrease of the ^Cpx/L D for highly-charged cations (with the exception of V), and by a slight increase of D _Sr. REE are still compatible from Nd to Lu (^Cpx/L D up to 2.1), like Ti, Y, Sc and V. This variation is also predicted for REE and Y by models based on the elastic strain theory, being consistent with the slightly lower polymerization degree estimated for the trachyphonolites. However, the observed ^Cpx/L D _(REE,Y) are matched by the modelled ones only considering very low T (≤825°C), which are believed unlikely. This mismatch cannot be attributed to effects induced by the water-rich composition of the trachyte–trachyphonolite suite, since they would lower the observed ^Cpx/L D _(REE,Y). Moreover, the anomalous inflections of measured ^Cpx/L D for HREE suggests some crystal-chemical control, such as the entrance of these elements in a site distinct from M2. It is concluded that the large ^Cpx/L D determined for trachytes and trachyphonolites are likely induced by hitherto unconstrained changes of the Z³⁺ activities related to the composition of melt and/or solid. All these considerations strongly highlight the importance of a direct characterization of trace element partitioning in natural samples from magmatic systems poorly characterized by experimental studies. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.