Crustal structure in Alaska

Knowledge of the crustal structure is still fragmentary, despite the stimulus to geophysical work provided by the earthquake of March 28, 1964 (GMT), the underground nuclear explosion LONGSHOT, and the June 1967 series of earthquakes in the Fairbanks area. The most reliable information about struc ture has come from a combination of seismic explosion-refraction profiles, gravity surveys, and magnetic surveys. This report is a summary of recent investigations, but the results are not adequate to permit unambiguous generalizations about crustal structure.     

Neotectonics and seismicity of Erzurum pull-apart basin,East Turkey

The study area is the Erzurum pull-apart basin located in the East Anatolian Tectonic Block (EATB), which is under the control of a strike-slip neotectonic regime since the beginning of Quaternary. The Quaternary Erzurum pull-apart basin is an about 1-30 km wide, 90 km long and actively growing strike-slip depression. It is bounded by the Erzurum-Dumlu sinistral strike-slip fault zone to the east-southeast, by the Askale sinistral strike-slip fault zone to the north-northwest, and by the Baskoy-Kandilli reverse fault zone and the N-S-trending Ilica oblique-slip normal fault set to the west. The Erzurum pull-apart basin was evolved by the deformation and subdivision of an E-W-trending older intermontane basin. The new basin has a 0.5 km thick, flat-lying (undeformed) and uconsolidated fill, which overlies, with an angular unconformitry, the deformed (folded and faulted) basement rocks of pre-Quaternary age. Basin fill consists of coarser-grained marginal facies (fault terrace, fan, fan-apron and superimposed fan deposits) and finer-grained depocentral facies represented by flood plain to organic material-rich marsh deposits. All gradations are seen among these lithofacies.The seismicity of the Erzurum pull-apart basin is quite high. The magnitude of the peak earthquake to be sourced from the active faults (e.g., the Erzurum fault) is about Mw = 7.0. This was proved by both the historical and recent earthquakes. Numerous settlements in the size of a large city (e.g., Erzurum), county, town and small villages with a total population of over 766,000 are located in and along the active fault-bounded margins of the Erzurum pull-apart basin. They are under the threat of destructive earthquakes to be sourced from the margin-boundary faults. Therefore, based on both the active fault parameters and the water-saturated basin fill, a large-scale earthquake hazard map has to be prepared. This map has to be used in both the earthquake hazard to risk analyses and the redesign of city planning and all type of constructions in Erzurum and other settlements in this region.     

Seasonal and spatial changes in water and sediment quality variables in Bafa Lake

The brackish Bafa Lake located in the southwestern part of Turkey is under stress because of both natural and untreated wastewater effluents. The purpose of this research is to determine spatiotemporal distributions of some physicochemical variables in water column (temperature, salinity, pH, conductivity, dissolved oxygen, NH₄–N, NO₂–N, NO₃–N, oPO₄–P, TPO₄–P, chlorophyll-a, total suspended solids) and sediment (TN, TC, TOC, TP) and their relationships at coastal stations. In the water column, nitrate and phosphate concentrations showed seasonal variations with high values recorded in winter period. Ammonium was determined as a main source of TIN component. During summer period, a large amount of total phosphorus was found as dissolved organic form. However, in the winter period, inorganic phosphate levels increased at sampling stations. N limitation was a common feature throughout the lake where P-limitation was only observed in summer period. The total phosphorus levels which showed hypereutrophic condition at the western part of the lake changed between 1.55 and 4.99 μM and did not remain in the range for uncontaminated condition. In the lake sediment, a strong relationship was found between TOC and TC levels. Generally, the mean TOC concentrations constitute small amount of TC values in the sampling stations. The results also indicated that a strong correlation exists between TOC and TN values, and TN was greatly regulated by organic sources. In the lake, TOC:TN ratios changed between 5 and 13; the ratio greater than 10 could be an indicator of algal and land plant sources mixing as an organic matter.     

滇池微囊藻水华多糖的提取和化学特征

为了研究"水华"微囊藻多糖及其对水体化学和生态特性的影响,以去离子水、pH5的缓冲液和pH9.2的缓冲液为提取液,分别在4℃和80℃条件下从滇池"水华"微囊藻中提取多糖,并对其所提多糖部分化学特征进行分析.结果表明pH9.2的缓冲液所提多糖总得率最高,为2.25%;pH5的磷酸盐缓冲液所提多糖总得率最低,为0.383%.溶解性分析表明,不同提取液所提多糖在所试验的几种溶剂中表现为不溶、分散或部分溶解,未能找到将多糖完全溶解的溶剂.气相色谱和气-质联用分析表明,不同提取液所提多糖都含有中性单糖鼠李糖、阿拉伯糖、甘露糖、葡萄糖、半乳糖和一个未知糖.硫酸-咔唑法分析显示不同提取液所提多糖含有糖醛酸.电感耦合等离子光谱显示去离子水4℃条件下所提多糖含有很高的金属元素钙和镁,分别为2.15%和0.4%.初步研究显示,"水华"微囊藻多糖为酸性杂多糖,低溶解性显示在自然水体中它易形成多糖颗粒,有较高含量的金属元素说明它会影响到这些金属元素在滇池中的溶解、沉积、生物利用和循环,特别是钙和镁.     

Isotopic fractionation of nitrogen and carbon in Paleoarchean cherts from Pilbara craton, Western Australia: Origin of N-depleted nitrogen

Nitrogen and carbon isotopic compositions, together with mineralogy and trace element geochemistry, were studied in a few kerogen-rich Paleoarchean cherts, a barite and a dolomitic stromatolite belonging to the eastern (Dixon Island Formation) and western (Dresser and Strelley Pool Chert Formations; North Pole Dome and Marble Bar) terranes of Pilbara Craton, Western Australia. The aim of the study was to search for ¹⁵N-depleted isotopic signatures, often found in kerogens of this period, and explain the origin of these anomalies. Trace elements suggest silica precipitation by hydrothermal fluids as the main process of chert formation with a contamination from volcanoclastic detritus. This is supported by the occurrence of hydrothermal-derived minerals in the studied samples indicating precipitation temperatures up to 350 °C. Only a dolomitic stromatolite from Strelley Pool shows a superchondritic Y/Ho ratio of 72 and a positive Eu/Eu^* anomaly of 1.8, characteristic of chemical precipitates from the Archean seawater. The bulk δ¹³C vs. δ¹⁵N values measured in the cherts show a roughly positive co-variation, except for one sample from the North Pole (PI-85-00). The progressive enrichment in ¹⁵N and ¹³C from a pristine source having δ¹³C ? −36‰ and δ¹⁵N ? −4‰ is correlated with a progressive depletion in N content and to variations in Ba/La and Co/As ratios. These trends have been interpreted as a progressive hydrothermal alteration of the cherts by metamorphic fluids. Isotopic exchange at 350 °C between NH₄⁺_(rock) and N_2(fluid) may explain the isotopic and elemental composition of N in the studied cherts. However, we need to assume isotopic exchange at 350 °C between carbonate C and graphite to explain the large ¹³C enrichment recorded. Only sample PI-85-00 shows a large N loss (90%) with a positive δ¹⁵N value (+11‰), while C (up to 120 ppm and δ¹³C −38‰) seems to be unaffected. This pattern has been interpreted as the result of devolatilization and alteration (oxidation) of graphite by low-temperature fluids. The ¹⁵N-¹³C-depleted pristine source has δ ¹⁵N values from −7‰ to −4‰ and ⁴⁰Ar/³⁶Ar ratios from 30,000 to 60,000, compatible with an inorganic mantle N source, although the elemental abundance ratios N/C and ⁴⁰Ar/C are not exactly the same with the mantle source. The component alternatively could be explained by elemental fractionation from metabolic activity of chemolithoautotrophs and methanogens at the proximity to the hydrothermal vents. However, ambiguities between mantle vs organic sources of N subsist and need further experimental work to be fully elucidated.     

Characterization of drying-induced deformation behaviour of Opalinus Clay and tuff in no-stress regime

The drying-induced deformation behaviour of Opalinus Clay and tuff, which are being investigated under international and local collaborative projects for nuclear waste disposal in Switzerland and Japan, was investigated under a no-stress condition in the laboratory to evaluate their generic susceptibility to the formation of excavation damaged zone. The cylindrical core samples of Opalinus Clay and tuff were prepared to a one-dimensional drying condition and submitted to an uncontrolled laboratory environment. The strain evolution, evaporative water loss and environmental entities, such as temperature and relative humidity, were recorded simultaneously and quasi-continuously. It was observed that the drying phase induced significant strain magnitude and damage in Opalinus Clay samples, which was evidenced by the formation of hairy cracks on the surface parallel to the bedding. On the contrary, the strain occurrences in tuff samples were relatively insignificant, and no tendency of cracking was observed. In addition, the quasi-continuous availability of volumetric strains was further used in poroelastic relation for the estimation of capillary suction evolution. The calculated results were validated with pore size distributions obtained from mercury intrusion porosimetry.