Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine Carbonates

Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO₂ through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ¹¹B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ¹¹B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ¹¹B; and (c) to provide well‐constrained consensus δ¹¹B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.     

Quaternary reactivation of Tertiary faults in the southeastern Korean Peninsula: Age constraint by optically stimulated luminescence dating

Abstract   Two groups of Quaternary faults occur in the southeastern Korean Peninsula. The first group is north-northeast-striking, high-angle dextral strike–slip faults. The second group is north-northeast-striking, low-angle reverse faults that represent the reactivation of the pre-existing normal faults. Optically stimulated luminescence dating of Quaternary sediments cut by one of the reverse faults constrains the faulting age to post-32 Ka. These faults seem to be capable of further slip under the current tectonic stress regime, as determined by recent earthquake events in northeast Asia. Therefore, the traditional concept that the southeastern Korean Peninsula is seismically stable should be reappraised.     

Sea surface shape derivation above the seismic streamer

The rough sea surface causes perturbations in the seismic data that can be significant for time‐lapse studies. The perturbations arise because the reflection response of the non‐flat sea perturbs the seismic wavelet. In order to remove these perturbations from the received seismic data, special deconvolution methods can be used, but these methods require, as input, the time varying wave elevation above each hydrophone in the streamer. In addition, the vertical displacement of the streamer itself must also be known at the position of each hydrophone and at all times. This information is not available in conventional seismic acquisition. However, it can be obtained from the hydrophone measurements provided that the hydrophones are recorded individually (not grouped), that the recording bandwidth is extended down to 0.05 Hz and that data are recorded without gaps between the shot records. The sea surface elevation, and also the wave‐induced vertical displacement of the streamer, can be determined from the time‐varying pressure that the sea waves cause in the hydrophone measurements. When this was done experimentally, using a single sensor seismic streamer without a conventional low cut filter, the wave induced pressure variations were easily detected. The inversion of these experimental data gives results for the sea surface elevation that are consistent with the weather and sea state at the time of acquisition. A high tension approximation allows a simplified solution of the equations that does not demand a knowledge of the streamer tension. However, best results at the tail end of the streamer are obtained using the general equation.     

Processes governing the predictability of the Atlantic meridional overturning circulation in a coupled GCM

The processes that govern the predictability of decadal variations in the North Atlantic meridional overturning circulation (MOC) are investigated in a long control simulation of the ECHO-G coupled atmosphere?Cocean model. We elucidate the roles of local stochastic forcing by the atmosphere, and other potential ocean processes, and use our results to build a predictive regression model. The primary influence on MOC variability is found to come from air?Csea heat fluxes over the Eastern Labrador Sea. The maximum correlation between such anomalies and the variations in the MOC occurs at a lead time of 2?years, but we demonstrate that the MOC integrates the heat flux variations over a period of 10?years. The corresponding univariate regression model accounts for 74.5% of the interannual variability in the MOC (after the Ekman component has been removed). Dense anomalies to the south of the Greenland-Scotland ridge are also shown to precede the overturning variations by 4?C6?years, and provide a second predictor. With the inclusion of this second predictor the resulting regression model explains 82.8% of the total variance of the MOC. This final bivariate model is also tested during large rapid decadal overturning events. The sign of the rapid change is always well represented by the bivariate model, but the magnitude is usually underestimated, suggesting that other processes are also important for these large rapid decadal changes in the MOC.     

Objective comparison of mass fragmentograms by principal components analysis: method and results

The multivariate statistical method of Principal Components Analysis is used to classify gas chromatographic-mass spectrometric data. The specific examples comprise sterane and triterpane regions of GC-MS analyses of branched/cyclic fractions. The statistical model provides an objective analogue to visual comparison and classification of mass fragmentograms. Sources of experimental error influencing the statistical results include insufficient sample size, short integration times, and peak skewing. The method successfully groups samples of oils, oil sand, and polluted beach sand according to geographic origin: beach sand groups with type of crude spilled; laboratory biodegraded and untreated Nigerian crudes group together. Applications of three-mode Principal Components Analysis can range from study of geologic processes acting on organic compounds to classification of unknown pollutants.     

Far-infrared photometry of Titan and Iapetus

Titan was observed in four broad passbands between 35 and 150 μm. The brightness temperature in this interval is roughly constant at 76 ± 3°K. Integrating Titan's spectrum from 5 to 150 μm yields an effective temperature of 86 ± 3°K. Both the bright and dark hemispheres of Iapetus were observed in one broadband filter with λ_e ～ 66 μm. The brightness temperatures for these two sides of Iapetus are 96 ± 9°K and 114 ± 10°K, respectively. The bright-side Bond albedo is calculated to be 0.61_?0.22^+0.16.     

Les végétaux (Macrofossiles) du crétacé moyen de l'Europe occidentale et du Sahara. Végétations et paléoclimats

Cette note expose un ensemble de synthèses régionales sur les thèmes suivants: les macrofossiles de l'Angleterre; les bois de l'Albien du Boulonnais; les végétaux de Normandie du Crétacé moyen; les milieux forestiers littoraux du Cénomanien inférieur de l'Anjou et des Charentes; les macroflores du Crétacé moyen continental de l'Espagne; les gisements de l'Italie et du Sahara.L'esquisse d'une évolution possible de quelques végétations de ces contrées est proposée, ainsi que les arguments paléoclimatiques que l'on peut en déduire.This paper presents a regional synthesis concerning mid-Cretaceous plant megafossils from England, Normandy, Northern and Western France, Spain, Italy, and the Sahara. A possible evolution pattern is offered for these floras during mid-Cretaceous time; some climatic arguments are presented.