Manganiferous smectite from tirebolu (NE-Turkey)

A pink-colored (HUE 5R-7/4), predominantly calcium saturated, clay mineral from Tirebolu, NE-Turkey, is shown to be a dioctahedral, high-charge manganiferous smectite. It is probably an alteration product of volcanic tuffs of rhyodactitic composition. Ionic formula: (Si_7.71Al_0.29)^IV(Al_3.04Fe _0.12 ³⁺ Fe _0.02 ²⁺ Mg_0.92Mn _0.07 ²⁺ )^VI O₂₀ (OH)₄ 0.79 M⁺ Cation exchange capacity: 92 me/100 g (air dry sample). Unit cell parameters (ca. 20 ° C; ca. 40% RH): a₀9.02 Å b₀5.21 Å Mg⁺⁺... Mn-smectite: c₀14.65 Å Ca⁺⁺... Mn-smectite: c₀14.83 Å K⁺... Mn-smectite: c₀12.10 Å

---

Zusammenfassung Ein rosa (HUE 5R-7/4), weitgehend Calcium-gesättigtes Tonmineral von Tirebolu (NO-Türkei) wurde als ein dioktaedrischer, hochgeladener manganhaltiger Smektit identifiziert. Er ist wahrscheinlich ein Umwandlungsprodukt eines rhyodazitischen Tuffs. Strukturformel: (Si_7.71Al_0.29)^IV(Al_3.04Fe _0.12 ³⁺ Fe _0.02 ²⁺ Mg_0.92Mn _0.07 ²⁺ )^VI O₂₀ (OH)₄ 0.79 M⁺ Kationaustauschkapazität: 92 me/100 g (luftgetrocknet). Gitterkonstanten (ca. 20° C; ca. 40% RF): a₀9.02 Å b₀5.21 Å Mg⁺⁺... Mn-Smektit: c₀14.65 Å Ca⁺⁺... Mn-Smektit: c₀14.83 Å K⁺... Mn-Smektit: c₀12.10 Å

     

Bimodal early proterozoic volcanism in the Grythytte field and associated volcano-plutonic complexes,Bergslagen, Central Sweden

The Grythytte field sequence forms a NNW belt of acid-basic metavolcanic and metasedimentary rocks. The geology shows characteristics of a dynamic process of trough-forming and infilling which to a large extent post-dates the Hjulsjö volcanoplutonic complex situated to the east. In the latter complex acid metapyroclastics strike around a centre of granite and granophyre, which cut and are cut by basic sills and dykes. Field and petrochemical evidence points to a distinct bimodal magmatism that ist manifested during one short phase of a rifting period.

---

Zusammenfassung Die Grythytte Schichtenfolge bildet einen NNW verlaufenden Gürtel aus sauren und basischen Metavulkaniten und Metasedimenten. Die geologischen Befunde weisen auf einen dynamischen Entstehungsprozeß von Grabenbildung und Füllung hin. Im weiter östlich gelegenen vulkanisch-plutonischen Hjulsjö-Komplex streichen älteren metamorphen pyroklastischen Gesteine rund ein Granit-Granophyr Zentrum. Dieser Komplex durchschneidet und wird durchschnitten von basischen Sills und Gängen. Feldgeologische und geochemische Untersuchungen weisen deutlich auf einen bimodalen Magmatismus hin, der während einer kurzen Phase der Grabenbildung stattfand.

---

Résumé La séquence de Grythytte forme une ceinture de roches métavolcaniques et métasédimentaires de direction NNO. La géologie fait apparaître les caractéristiques d'un processus dynamique de formation de fosse et de remplissage, qui s'est produit, pour la plus grande partie, après la formation du complexe volcano-plutonique de Hjulsjö situé à l'Est. Dans ce dernier complexe des produits pyroclastiques acides sont disposés autour d'un centre granitoïde et granophyrique, qui à son tour recoupe et est recoupé par des sills et des dykes basiques. Les observations de terrain et les faits pétrochimiques indiquent un procèssus magmatique distinctement bimodal qui s'est manifesté pendant une phase courte dans une période de «rifting».

---

Grythytte , NNW . . Hjulsj -- . . , , .

     

The role of hydrogen bonding in the thermal expansion and dehydration of brushite,di-calcium phosphate dihydrate

The unit-cell and atomic parameters of perdeuterated brushite have been extracted from Rietveld analysis of neutron powder diffraction data within the temperature range 4.2 to 470 K. The thermal expansion of brushite is anisotropic, with the largest expansion along the b axis due principally to the effect of the O(1)···D(4) and O(3)···D(2) hydrogen bonds. Expansion along the c axis, influenced by the Ow1···D(5) interwater hydrogen bond, is also large. The high temperature limits for the expansion coefficients for the unit-cell edges a, b and c are 9.7(5) × 10^–6, 3.82(9) × 10^–5 and 5.54(5) × 10^–5 K^–1, respectively, and for the cell volume it is 9.7(1) × 10^–5 K^–1. The angle displays oscillatory variation, and empirical data analysis results in = 1.28(3) × 10^–6sin(0.0105 T) K^–1, within this temperature range. The evolution of the thermal expansion tensor of brushite has been calculated between 50 T 400 K. At 300 K the magnitudes of the principal axes are ₁₁ = 50(6) × 10^{–6 K–1}, ₂₂ = 26.7(7) × 10^–6 K^–1 and ₃₃ = 7.0(5) × 10^–6 K^–1. The intermediate axis, ₂₂, is parallel to b, and using IRE convention for the tensor orthonormal basis, the axes ₁₁ and ₃₃ have directions equal to (–0.228, 0, –0.974) and (–0.974, 0, 0.228) respectively. Under the conditions of these experiments, the onset of dehydration occurred at temperatures above 400 K. Bond valence analysis combined with assessments of the thermal evolution of the bonding within brushite suggests that dehydration is precipitated through instabilities in the chemical environment of the second water molecule.     

An experimental performance analysis of real-time kinematic positioning with NASA’s Internet-Based Global Differential GPS

The Global Differential GPS (GDGPS) system developed by JPL aims at seamless global real-time positioning at the dm accuracy level for dual-frequency receivers either fixed or mobile, anywhere and at any time. The GDGPS system relies on GPS data transmitted in real-time to a central processing center at JPL from a global network of permanently operating GPS dual-frequency receivers. At the processing center, the Internet-based Global Differential GPS (IGDG) system, the heart of JPLs GDGPS, generates and disseminates over the open Internet special 1-s global differential corrections (IGDG corrections) to the GPS broadcast ephemerides. The IGDG corrections enhance the accuracy of GPS broadcast orbits and clocks down to the dm level and serve as the key-factor for high-precise real-time positioning of a stand-alone receiver. An experimental verification of the dm positional accuracy of the IGDG system was carried out in the Netherlands, by means of both a static and a kinematic test. During the static test GPS data were collected for 5 consecutive days using a fixed immobile receiver and processed as if in real-time. Within the framework of the kinematic test, an experiment was carried out using a kinematic platform. Our tests confirmed the dm accuracy of stand-alone receiver positioning with IGDG. The standard deviation for positioning both in static and kinematic mode appears to be 10 cm in each horizontal component and 20 cm in the vertical component. More than 99% of the IGDG corrections were received with the expected 1-s interval in the field via mobile communication, the latency of the corrections was generally from 7 to 8 s.     

Incoherent internal tidal currents in the deep ocean

Eleven months current meter observations from the deep Bay of Biscay were examined for the residual (incoherent internal tidal; icIT) signal, left after harmonic analysis using eight tidal constituents (large-scale barotropic or coherent baroclinic signal) within the semidiurnal band. This residual signal comprised 30% of the total tidal kinetic energy and, due to its flat spectral appearance, it was responsible for typically 5–7 days intermittency. Although icIT was part of the red noise internal wave band continuum, it was not attributable to instrumental noise. It consisted of quasi-harmonics at non-tidal harmonic frequencies having amplitudes larger than N₂, the third largest semidiurnal tidal constituent. It is suggested that the kinetic energy at these non-tidal frequencies reflects interaction between semidiurnal tidal motions and the slowly varying background conditions.Responsible Editor: Roger Proctor     

Siltation by sediment-induced density currents

This paper describes the results of numerical experiments with a three-dimensional hydrodynamic and mud transport model in which sediment–fluid interaction is taken into account through the effects of hindered settling, buoyancy destruction in the turbulence k– model and sediment-induced barocline pressure gradients in the momentum equations. The model was applied to a schematic case representing a coastal area with a tidal river, navigation channel and harbour basin, and a real-world case, viz. Rotterdam harbour area in The Netherlands. The results show that the sediment transport into the harbour area, and subsequent siltation rates, increase by a factor 3 to 5 due to the sediment–fluid interaction. It is shown that the larger contribution stems from an increase in vertical gradients in suspended sediment.Responsible Editor: Jens Kappenberg     

Deep-sea fan pinch-out geometries and their relationship to fan architecture,Tanqua Karoo basin (South Africa)

Exceptional exposures of Permian basin floor fans (fans 3, 4) and a slope fan (fan 5) in the Tanqua Karoo foreland basin of South Africa have enabled an investigation of the relation between the pinch-out geometries and fan architecture. The pinch-out geometry of fan 3 is characterized by the down dip transition from thin to medium bedded sheet deposits to pinch-out fingers, which are overlain by younger prograding sheet deposits. This geometry reflects the progradational stacking pattern of the fan. In contrast, the fan 4 pinch-out fingers consist of stacked channel fills in the same conduit. This pinch-out configuration relates to the dominant aggradational style observed on the mid and distal parts of fan 4. Fan 5 represents a slope fan comprising an axial channel conduit, which branches down slope into three distributary channels. The distal fan is characterized by larger channel fills, which may represent bypass channels to other basin floor fans. The very thick-bedded nature of the youngest channel fill unit suggests early bypass followed by retrogradation as indicated by the presence of thinner bedded heterolithic channel fill deposits along the axial conduit. Although some of the massive pinch-out channels exhibit basal scour, their depositional morphology suggests that they mainly originated due to the infill of subtle topographic depressions by low concentration turbidity currents. Instead of describing these features as channel fills, the use of the term pinch-out fingers is preferred.     

Strong magnetic linear dichroism in Fe <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript> and O <Emphasis Type="Italic">K</Emphasis> electron energy-loss near-edge spectra of antiferromagnetic hematite α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>

We report strong magnetic linear dichroism (MLD) at the Fe L₂₃ and O K edges of the antiferromagnetic compound hematite -Fe₂ O₃ in high-resolution orientation- and temperature-dependent electron energy-loss spectroscopy (EELS). Large intensity differences of corresponding spectral features are observed when the Fe L₂₃ and O K edges are measured with momentum transfer either parallel or perpendicular to the magnetization. The resultant difference spectra for the Fe L₂₃ edges is consistent with the MLD observed in X-ray absorption spectroscopy. For the first time we have observed MLD at the O K edge, where the magnetic origin of this dichroism is demonstrated by temperature-dependent investigations across the Morin transition temperature T_M= 263 K, at which the Fe electron spins, i.e. the magnetic moments, rotate by 90°. The O K edge MLD is interpreted in terms of superexchange between the spins of the Fe 3d and O 2p electrons through overlapping Fe 3d and O 2p orbitals. The experiments were performed in a transmission electron microscope (TEM), yielding information about the anisotropic electronic structure at nanoscale spatial resolution when operated with a focused electron probe. The effects of MLD at the Fe L₂₃ edges on the determination of Fe³⁺/Fe in hematite at submicrometre scale using different independent quantification methods are discussed.     

On the formation of continental silicic melts in thermochemical mantle convection models: implications for early Earth

Seafloor magnetotelluric (MT) data were collected at seven sites across the Hawaiian hot spot swell, spread approximately evenly between 120 and 800 km southwest of the Hawaiian-Emperor island chain. All data are consistent with an electrical strike direction of 300°, aligned along the seamount chain, and are well fit using two-dimensional (2D) inversion. The major features of the 2D electrical model are a resistive lithosphere underlain by a conductive lower mantle, and a narrow, conductive, ‘plume’ connecting the surface of the islands to the lower mantle. This plume is required; without it the swell bathymetry produces a large divergence of the along-strike and across-strike components of the MT fields, which is not seen in the data. The plume radius appears to be less than 100 km, and its resistivity of around 10 Ωm, extending to a depth of 150 km, is consistent with a bulk melt fraction of 5–10%.A seismic low velocity region (LVR) observed by Laske et al. [Laske, G., Phipp Morgan, J., Orcutt, J.A., 1999. First results from the Hawaiian SWELL experiment, Geophys. Res. Lett. 26, 3397–3400] at depths centered around 60 km and extending 300 km from the islands is not reflected in our inverse model, which extends high lithospheric resistivities to the edge of the conductive plume. Forward modeling shows that resistivities in the seismic LVR can be lowered at most to 30 Ωm, suggesting a maximum of 1% connected melt and probably less. However, a model of hot subsolidus lithosphere of 10² Ωm (1450–1500 °C) within the seismic LVR increasing to an off-swell resistivity of >10³ Ωm (<1300 °C) fits the MT data adequately and is also consistent with the 5% drop in seismic velocities within the LVR. This suggests a ‘hot, dry lithosphere’ model of thermal rejuvination, or possibly underplated lithosphere depleted in volatiles due to melt extraction, either of which is derived from a relatively narrow mantle plume source of about 100 km radius. A simple thermal buoyancy calculation shows that the temperature structure implied by the electrical and seismic measurements is in quantitative agreement with the swell bathymetry.