Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Elm bark beetle in Holocene peat deposits and the northwest European elm decline

The elm decline of 5000 ¹⁴C yr ago has been the most widely discussed phenomenon in post‐glacial vegetation history. This pan‐European reduction of elm populations, echoed in the decimation of elmwoods in Europe during the twentieth century, has attracted a series of interrelated hypotheses involving climate change, human activity, disease and soil deterioration. The elm bark beetle (Scolytus scolytus L.) is an essential component of disease explanations. We present evidence for the presence of the beetle over a prolonged period (ca. 7950–4910 yr BP [8800–5660 cal. yr BP]) from a lowland raised mire deposit in northeast Scotland, with its final appearance at this site, and the first and only appearance in another mire of a single scolytid find, around the time of the elm decline. The subfossil S. scolytus finds are not only the first from Scotland, but they also represent the most comprehensive sequence of finds anywhere. Copyright © 2004 John Wiley & Sons, Ltd.     

Cygnus A

Cygnus A was the first hyper-active galaxy discovered, and it remains by far the closest of the ultra-luminous radio galaxies. As such, Cygnus A has played a fundamental role in the study of virtually all aspects of extreme activity in galaxies. We present a review of jet theory for powering the double-lobed radio emitting structures in powerful radio galaxies, followed by a review of observations of Cygnus A in the radio, optical, and X-ray relevant to testing various aspects of jet theory. Issues addressed include: jet structure from pc- to kpc-scales, jet stability, confinement, composition, and velocity, the double shock structure for the jet terminus and the origin of multiple radio hotspots, the nature of the filamentary structure in the radio lobes, and the hydrodynamic evolution of the radio lobes within a dense cluster atmosphere, including an analysis of pressure balance between the various gaseous components. Also discussed are relativistic particle acceleration and loss mechanisms in Cygnus A, as well as magnetic field strengths and geometries both within the radio source, and in the intracluster medium. We subsequently review the classification, cluster membership, and the emission components of the Cygnus A galaxy. The origin of the activity is discussed. Concentrating on the nuclear regions of the galaxy, we review the evidence for an obscured QSO, also given the constraints on the orientation of the radio source axis with respect to the sky plane. We present an overview of models of central engines in AGN and observations of Cygnus A which may be relevant to testing such models. We conclude with a brief section concerning the question of whether Cygnus A is representative of powerful high redshift radio galaxies. Received October 10, 1995     

Urban geology: Glasgow's hidden industrial heritage

The growth of Glasgow from a small town into a heavily industrialised conurbation depended greatly on its local geological riches. Extensive mining and quarrying of a range of minerals took place from the 18th century onwards. The early underground stoop and room (pillar and stall) workings, and the backfilled quarries, together with variably consolidated natural superficial deposits, have bequeathed to the city a heritage of unwanted engineering problems which cannot easily be quantified. Recent work by the British Geological Survey (BGS) illustrates the scale of both geological and man-made problems.     

Long-Term Changes of Polar Activity of the Sun

We discuss long-time changes of polar activity of the Sun using the new observational data sets in the optical range during 1872–2001. A study of the secular and cycle variations of the magnetic activity at the high-latitude regions is the main goal that includes polar magnetic field reversals during 1872–2001 and secular changes of the duration of polar activity cycles. The secular increase of the area of polar zones during the minimum activity in the last 120 years and as consequence a decrease of coronal temperature of the Sun in the high-latitude zones during the last 50 years. Correlation between the polar cycles of Caii-K bright points with the Wolf sunspot numbers cycles, W(t), and the 22-year polar magnetic cycles of Caii-K bright points at the high latitudes during 1905–1995 is discussed.     

Instrument development to search for biomarkers on mars: Terrestrial acidophile, iron-powered chemolithoautotrophic communities as model systems

Recent findings by the MER rover opportunity confirming the presence of iron minerals that can only be formed in the presence of water emphasize the study of analogous environments to Mars on Earth. The study of chemolithoautotrophic communities living in acidic iron-rich habitats is highly relevant in order to identify Mars analog environment-specific biomarkers. Iron oxidizing bacteria like Leptospirillum ferrooxidans and Acidithiobacillus ferrooxidans have ways of life for which it is feasible to identify a past or present hypothetical niche on Mars. We have developed a strategy for biomarker identification based on: (i) search for biosignatures on acid and metal-rich environments; (ii) development of an immunosensor microarray; and (iii) integration into an instrument for autonomous and remote operation. The instrument that we have built, called Signs Of LIfe Detector (SOLID), is capable of processing a variety of samples for the detection of specific biomarkers. Antibodies against several bacterial strains have been developed and tested in a microarray biosensor on SOLID. Tests with field samples have been successfully performed, allowing the detection of L. ferrooxidans, A. ferrooxidans present in sediment samples.