Polymerization of silicate and aluminate tetrahedra in glasses,melts and aqueous solutions—II. The network modifying effects of Mg2+ , K+, Na+, Li+, H+, OH−, F−, Cl−, H2O,CO2 and H3O+ on silicate polymers

The effect of the group IA and VIIA ions, as well as Mg²⁺, and the molecules H₂O, CO₂, H₃O⁺ and OH^? on the energy of the Si-O bond in a H₆Si₂O₇ cluster has been calculated using semiempirical molecular orbital calculations (CNDO/2). Three types of elementary processes, i.e. substitution, addition, and polymerization reactions have been used to interpret data on the dynamic viscosity, surface tension and surface charge, hydrolytic weakening, diffusivity, conductivity, freezing point depression, and degree of polymerization of silicates in melts, glasses, and aqueous solutions. As a test of our calculational procedure, observed X-ray emission spectra of binary alkali silicate glasses were compared with calculated electronic spectra. The well known bondlength variations between the bridging bond [Si-O(br)] and the non-bridging bond [Si-O(nbr)] in alkali silicates are shown to be due to the propagation of oscillating bond-energy patterns through the silica framework. A kinetic interpretation of some results of our calculations is given in terms of the Bell-Evans-Polanyi reaction principle.     

地质雷达在岩溶地区岩土工程勘察中的应用

安徽省沿江及皖南一带石灰岩分布广泛,岩溶发育,由于岩溶溶洞具有隐伏性强、空间分布规律性差、岩溶塌陷难以预测等特点,因此岩溶区岩土工程勘察必需查清岩溶发育规律。本文结合铜陵一带岩溶区岩土工程勘察中几个实例,阐述在岩溶发育区,采用地质雷达结合钻探综合勘察方法,高效准确查清构筑物基础范围内岩溶溶洞发育情况,提高岩溶区勘察效益和勘察进度。     

Sr–Nd–Pb isotopic compositions of the Kovdor phoscorite–carbonatite complex, Kola Peninsula, NW Russia

The Sr, Nd and Pb isotopic compositions for the Kovdor phoscorite–carbonatite complex (PCC), Kola Peninsula, NW Russia, have been determined to characterize the mantle sources involved and to evaluate the relative contributions of a plume and subcontinental lithospheric mantle in the formation of the complex. The Kovdor PCC is a part of the Kovdor ultramafic–alkaline–carbonatite massif, and consists of six intrusions. The initial isotopic ratios of the analyzed samples, calculated at 380 Ma, display limited variations: ε_Nd, + 2.0 to + 4.7; ⁸⁷Sr/⁸⁶Sr, 0.70319 to 0.70361 (ε_Sr, − 12.2 to − 6.2); ²⁰⁶Pb/²⁰⁴Pb, 18.38 to 18.74; ²⁰⁷Pb/²⁰⁴Pb, 15.45 to 15.50; ²⁰⁸Pb/²⁰⁴Pb, 37.98 to 39.28. The Nd and Sr isotope data of the Kovdor PCC generally fit the patterns of the other phoscorites and carbonatites from the Kola Alkaline Province (KAP), but some data are slightly shifted from the mixing line defined as the Kola Carbonatite Line, having more radiogenic ⁸⁷Sr/⁸⁶Sr ratios. However, the less radiogenic Nd isotopic compositions and negative Δ7/4 values of Pb isotopes of the analyzed samples exclude crustal contamination, but imply the involvement of a metasomatized lithospheric mantle source. Isotopic variations indicate mixing of at least three distinct mantle components: FOZO-like primitive plume component, EMI-like enriched component and DMM-like depleted component. The isotopic nature of the EMI- and DMM-like mantle component observed in the Kovdor samples is considered to be inherited from metasomatized subcontinental lithospheric mantle. This supports the previous models invoking plume–lithosphere interaction to explain the origin of the Devonian alkaline carbonatite magmatism in the KAP.     

Input and system identification of the Hualien soil–structure interaction system using earthquake response data

This paper presents an input and system identification technique for a soil–structure interaction system using earthquake response data. Identification is carried out on the Hualien large‐scale seismic test structure, which was built in Taiwan for international joint research. The identified quantities are the input ground acceleration as well as the shear wave velocities of the near‐field soil regions and Young's moduli of the shell sections of the structure. The earthquake response analysis on the soil–structure interaction system is carried out using the finite element method incorporating the infinite element formulation for the unbounded layered soil medium and the substructured wave input technique. The criterion function for the parameter estimation is constructed using the frequency response amplitude ratios of the earthquake responses measured at several points of the structure, so that the information on the input motion may be excluded. The constrained steepest descent method is employed to obtain the revised parameters. The simulated earthquake responses using the identified parameters and input ground motion show excellent agreement with the measured responses. Copyright © 2003 John Wiley & Sons, Ltd.     

The Influence of Code Multipath on the Estimated Parameters of the Geometry-Free GPS Model

In this article, the influence of biases in GPS code observations on the estimated parameters of the geometry-free model is investigated. This is done for undifferenced as well as double-differenced data from short baselines, that is, baselines for which ionospheric effects may be assumed absent. It is shown how introducing a linear model for code multipath affects the original model parameters. The performance of the original and extended model is illustrated by analyzing data from a single receiver and a short baseline. ? 1999 John Wiley & Sons, Inc.     

Stellar science from a blue wavelength range

From stellar spectra, a variety of physical properties of stars can be derived. In particular, the chemical composition of stellar atmospheres can be inferred from absorption line analyses. These provide key information on large scales, such as the formation of our Galaxy, down to the small‐scale nucleosynthesis processes that take place in stars and supernovae. By extending the observed wavelength range toward bluer wavelengths, we optimize such studies to also include critical absorption lines in metal‐poor stars, and allow for studies of heavy elements (Z ≥ 38) whose formation processes remain poorly constrained. In this context, spectrographs optimized for observing blue wavelength ranges are essential, since many absorption lines at redder wavelengths are too weak to be detected in metal‐poor stars. This means that some elements cannot be studied in the visual‐redder regions, and important scientific tracers and science cases are lost. The present era of large public surveys will target millions of stars. It is therefore important that the next generation of spectrographs are designed such that they cover a wide wavelength range and can observe a large number of stars simultaneously. Only then, we can gain the full information from stellar spectra, from both metal‐poor to metal‐rich ones, that will allow us to understand the aforementioned formation scenarios in greater detail. Here we describe the requirements driving the design of the forthcoming survey instrument 4MOST, a multi‐object spectrograph commissioned for the ESO VISTA 4 m‐telescope. While 4MOST is also intended for studies of active galactic nuclei, baryonic acoustic oscillations, weak lensing, cosmological constants, supernovae and other transients, we focus here on high‐density, wide‐area survey of stars and the science that can be achieved with high‐resolution stellar spectroscopy. Scientific and technical requirements that governed the design are described along with a thorough line blending analysis. For the high‐resolution spectrograph, we find that a sampling of ≥2.5 (pixels per resolving element), spectral resolution of 18000 or higher, and a wavelength range covering 393–436 nm, is the most well‐balanced solution for the instrument. A spectrograph with these characteristics will enable accurate abundance analysis (±0.1 dex) in the blue and allow us to confront the outlined scientific questions. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

面向在线服务的地理框架数据体系构建

分析了在线服务对地理信息的需求,阐述了面向在线服务的地理框架数据体系构建技术实现方法,设计了适应多源数据协同服务的数据集成方式和满足多样化应用需求的地理框架数据内容构成与建模方法,并说明了其在国家地理信息公共服务平台公众版"天地图"中的应用。     

Evolution of the Dok Do seamounts,Ulleung Basin,East Sea: constraints based on the reconstruction of virtual geomagnetic poles using paleomagnetic data

In the Ulleung Basin, East Sea, the Dok Do seamount group comprises Dok Do (Dok Island), consisting of very small islets/rocks and a large submerged volcanic edifice, and two voluminous tablemounts, Simheungtaek and Isabu. We attempted to reconstruct the evolution of these seamounts, using virtual geomagnetic poles (VGPs) determined by the least-squares and the seminorm magnetization methods, with 1,500 m upward continued magnetic anomalies. The VGPs of Dok Do with normal dipole anomaly, and of Simheungtaek with normal dipole anomaly are located near the present magnetic pole. The VGP of Isabu with normal dipole anomaly is located at low latitude, presumably due to overprints of reversals in the Tertiary, and the distortion of magnetization and structures associated with volcanism after its formation. In contrast to the tablemounts, magnetic anomalies over Dok Do are a combination of both normal polarity and reversed polarity dipoles in the northern hemisphere, indicating that Dok Do has had at least two major eruptions, one during normal and another during reversed polarity intervals. From these results, and information on the ages of the seamounts (either published radiometric ages of subaerial volcanic rocks, or ages reconstructed in terms of reported elastic thickness incorporated into an existing cooling plate model), we tentatively propose that (1) Isabu formed first, during a normal polarity interval after the opening of the East Sea had ceased; (2) this was followed by an initial and subsequent large eruption of Dok Do during a normal polarity and a reversed polarity interval after about 5 Ma; and (3) the formation of Simheungtaek occurred in between that of Isabu and Dok Do in a normal polarity interval. The pattern of normal/reversed magnetization is not inconsistent with the geomagnetic polarity timescale for at least the last 5 Ma. Nevertheless, precise ages of formation would need verification by additional geophysical/geochemical constraints. Evaluating various possible models explaining the successive formation of the Dok Do seamounts, we currently favor fracturing and volcanism related to compression-induced weakening of the extensional field from the late Miocene to Pliocene after the opening of the East Sea.     

Repeated thermal resetting of phengites in the Mulhacen Complex (Betic Zone, southeastern Spain) shown byAr/Ar step heating and single grain laser probe dating

This study reports the results of the first⁴⁰Ar/³⁹Ar combined induction furnace and laser probe dating of phengites from the Mulhacen HP/LT metamorphic complex in the Betic Cordilleras, southern Spain. Laser step heating and spot fusion analyses on different halves of a split single grain were made with a continuous laser probe. Spot fusion analysis resulted in ages of about 30–31 Ma in the core and ages as low as 25–26 Ma in the rim. Laser step heating on the other half of the grain gave a spectrum with apparent ages increasing from about 25 Ma to 29.5 Ma. The age spectrum and the decreasing ages towards the rim of the grain may imply that resetting essentially occurred by volume diffusion of radiogenic⁴⁰Ar due to late stage reheating resulting from extensional tectonics. Ages around 30 Ma in the core of the grain are interpreted as minimum estimates of the cooling age of the main tectono-metamorphic phaseD₂.

Induction furnace step heating on phengite separates from mica schists and one gneiss resulted in two types of age spectra. Type I spectra show monotonously rising apparent ages from14.5 ± 1.9 Ma to20.7 ± 0.2 Ma, and in a second sample from16.9 ± 0.7 to29.7 ± 0.2 Ma. Type II spectra are characterized by plateaus of14.4 ± 0.1 Ma (the gneiss sample),17.3 ± 0.1 Ma and17.6 ± 0.1 Ma. Type II spectra show low temperature apparent ages significantly below the plateau age, implying resetting subsequent to initial cooling. Modelling of the age spectra demonstrated that the plateau ages are possibly the result of strong resetting (75–85% of argon loss) of an older isotope system. Total fusion of a number of phengite single grains from marbles taken close to type II mica schists yielded ages of15.4 ± 1.2 Ma and17.0 ± 0.7 Ma. The observed repeated resetting is coeval with major volcanic activity in basins adjacent to the metamorphic ranges, pointing to a resetting by advective fluid transport related to volcanism.