The distribution and preferential biological uptake of cadmium at 6°W in the Southern Ocean

The spatial and temporal distribution of cadmium (Cd) and phosphate in the Southern Ocean are related to biology and hydrography. During a period of 18 days between transects 5/6 and 11, a phytoplankton spring bloom developed in the Polar Frontal region. Upper water Cd concentrations were not depleted and ranged from 0.2 to 0.8 nM at about 10 m depth. These relatively high Cd concentrations are attributed to upwelling of Upper Circumpolar Deep Water (0.5–1.2 nM in the core) in combination with low biological productivity (0.2 to 0.3 mg m⁻³ chlorophyll-a, 0.3 g C m⁻² d⁻¹). Total particulate Cd concentrations at 40 m depth were between 0.02 and 0.14 nM with the maximum in concentration in the Polar Frontal region. Most of the particulate Cd at this depth (85–94%) was detected in the first phase of a sequential chemical leaching treatment which includes adsorbed Cd as well as Cd incorporated in algae. The Polar Frontal region was characterized by minima in Cd concentration and Cd/phosphate ratio of seawater at both transects; values were the lowest at transect 11 after development of the spring bloom which was dominated by diatoms. This decreasing Cd/phosphate ratio in seawater during spring bloom development was attributed to preferential Cd gross uptake which more than compensated the process of preferential Cd recycling. Within the Upper Circumpolar Deep Water, Cd showed a maximum in concentration similar to that of the major nutrients. Both the Cd concentration and the Cd/phosphate ratio of the deeper water increased in southern direction, from 0.4 to 0.7 nM and from 0.2 to 0.3 nM/μM, respectively. Antarctic Intermediate Water has a Cd concentration of 0.21 nM with a Cd/phosphate ratio of 0.10 nM/μM. In Antarctic Bottom Water, Cd concentrations ranged from 0.60 to 0.82 nM.     

Influence of Obstacles on the Aerodynamic Roughness of the Netherlands

The aim of this study was to analyse the influence of large- and small-scale obstacles (orography, tree lines, and dikes) on the effective aerodynamic roughness of the Netherlands, a relatively flat, small-scale landscape. The roughness averaging approach was based on drag coefficients. The effective roughness was locally dominated by small-scale obstacles such as tree lines and dikes. Even at a regional scale (40,000 km2), the small-scale obstacle drag was of the same order of magnitude as the shear stress due to landuse. The neglect of those obstacles on a regional scale would result in approximately 10% overestimated averaged windspeed at 10~m above the surface. It was concluded that small-scale obstacles need to be taken into account to calculate the aerodynamic roughness of flat landscapes. Orography was of minor importance in this lowland country.     

Spectroscopic evidence for two-pole accretion in the intermediate polar RX J0558+5353

We report on time-series optical spectrophotometry of the low-inclination intermediate polar RX  J0558+5353. This object exhibits coherent continuum and Hα line variations on both the orbital and white dwarf spin cycles. Despite the absence of a well-determined conjunction phase, the spectroscopic ephemeris combined with a favourable comparison with better-studied systems suggests that the impact between gas stream and accretion disc, or magnetosphere, drives orbital phenomena. Continuum variations over the spin cycle are consistent with previous broad-band data and indicate that accretion occurs on two poles of the primary star. We find no significant spin pulsations in the integrated line emission, but do detect variations in the resolved line profiles of Hα. Pulsed profiles are also suggestive of two-pole accretion. Double-peaked Hα line profiles and the non-detection of beat behaviour between the orbital and spin frequencies provide evidence for partial-disc transport in the system.     

Comparative yttrium and rare earth element chemistries in seawater

Comparisons of yttrium and rare earth stability constants for organic ligands indicate that Y(III)-organic complexation behavior most closely resembles, on average, the complexation characteristics of Sm(III). Yttrium organic complexation behavior distinctly differs from the behavior of Ho(III), whose ionic radius is most similar to that of yttrium. However, our stability constant comparisons demonstrate that the most reliable basis for predicting Y(III) organic stability constants are predictions based on the complexation behavior of Ho(III). Linear free energy relationships between Ho(III) and Y(III) exhibit better fits than those obtained for other rare earth elements, and much better fits than those obtained between Sm(III) and Y(III).The comparative abundances and distributions of yttrium and the rare earths in seawater are controlled by competitive equilibria between inorganic solution ligands and organic surface ligands. Due to yttrium solution complexation with hard inorganic ligands resembling that of Ho(III) and, yttrium surface complexation with soft organic ligands resembling that of light rare earth elements, the input normalized abundances of yttrium and the rare earths should be decoupled in seawater. In its seawater scavenging behavior, yttrium should act as a pseudolanthanide even heavier than the heaviest rare earth element, lutetium.     

Dynamics of the Kuroshio large meander

The bimodality of the Kuroshio path is studied numerically with a barotropic inflow-outflow model. The dynamics that determines the path depends on the Rossby number,Ro (proportional to inlet velocity) and the Reynolds number (representing effects of viscosity). At lowRo (<Ro ₁) only a meander path occurs, while at highRo(Ro ₂) only a straight path is developed. Between these critical values (Ro ₁RoRo₂) either of the two paths can occur (multiple states), and the choice of path is determined by its history. Increase (decrease) inRo acrossRo ₂ (Ro ₁) leads to catastrophic transition from one path to the other. In the intermediate range (Ro ₁RoRo₂), the straight path is conditionally unstable to finite amplitude disturbances, and abrupt changes to the meander path take place. Absolute vorticity is almost conserved along the meander path, while along the straight path it is dissipated in large amount near the coast. At low Re, the flow tends to a viscous flow, and steady states are obtained. At highRe, time variations with different periods for the meander and straight paths become dominant. Intermittent transitions from one state to the other without any changes of external parameters are found at intermediateRo and at highRe.     

δ30Si and δ29Si Determinations on USGS BHVO-1 and BHVO-2 Reference Materials with a New Configuration on a Nu Plasma Multi-Collector ICP-MS

We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the ¹⁴N¹⁶O and ¹⁴N₂ interferences overlying the ³⁰Si and the ²⁸Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ³⁰Si and δ²⁹Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ³⁰Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ³⁰Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites.     

A Method for Reinforcing the Ground Adjacent to the Footing Using Micropiles

The in-situ application of micropiles has gradually increased in limited spaces of downtown areas because the micropile has various advantages, such as low vibration and noise and compact machine size. In this study, model tests were carried out to understand the reinforcement effect induced by the mechanical interaction between the micropile and soil. The micropiles were installed in the soil adjacent to footings. Factors such as reinforced range (W) with piles, spacing (S) between piles, the installed angle (θ) of piles, and pile length (L) were considered variables in the tests. The reinforced angle (θ) was a more critical factor than the others for restraining the settlement and increasing soil stiffness in the model test results. The reinforcement effect rapidly increased around the reinforced range (W) of 2B (B: the width of a footing), the reinforced angle (θ) of 45 ～ 75°, and the pile length (L) of 3B. Based on the results of the experimental analyses, the purpose of this study is to improve the reinforcement efficiency of micropiles by recommending the most effective pattern and design method for installing them.     

Age determination and growth rate of <Emphasis Type="Italic">Mactra chinensis</Emphasis> (Bivalvia: Mactridae) by external rings and chondrophore growth bands

Age, growth and mortality of Mactra chinensis were investigated during the period from October 2012 to September 2013 in Busan, South Korea. The monthly variation of the marginal index (MI) of the shell and chondrophore showed that the ring of this species was formed once a year during July. We estimated the age of M. chinensis by reading the external rings on the shell and the growth bands of the chondrophore to compare growth parameters between the two growth characters. The age of this species ranged from 0 to 8 years (shell-based age reading) and from 0 to 10 years (chondrophore-based age reading). Based on external rings and growth bands of chondrophore for the same period, the von Bertalanffy growth functions were expressed by the equation, L _t = 101.53[1-exp {-0.15(t + 0.75)}] and L _t = 90.03[1-exp {-0.20(t + 0.50)}], respectively. The likelihood test showed that there was a significant difference in L _∞ (P < 0.001), K (P < 0.001), to (P < 0.001) estimated from non-linear regression between the two growth characters.     

Hydraulic Fracturing In Situ Stress Estimations in a Potential Geothermal Site,Seokmo Island,South Korea

We conducted hydraulic fracturing (HF) in situ stress measurements in Seokmo Island, South Korea, to understand the stress state necessary to characterize a potential geothermal reservoir. The minimum horizontal principal stress was determined from shut-in pressures. In order to calculate the maximum horizontal principal stress (S _Hmax) using the classical Hubbert–Willis equation, we carried out hollow cylinder tensile strength tests and Brazilian tests in recovered cores at depths of HF tests. Both tests show a strong pressure rate dependency in tensile strengths, from which we derived a general empirical equation that can be used to convert laboratory determined tensile strength to that suitable for in situ. The determined stress regime (reverse-faulting) and S _Hmax direction (ENE–WSW) at depths below ~300 m agrees with the first order tectonic stress. However the stress direction above ~300 m (NE–SW) appears to be interfered by topography effect due to a nearby ridge. The state of stress in Seokmo Island is in frictional equilibrium constrained by optimally oriented natural fractures and faults. However, a severe fluctuation in determined S _Hmax values suggests that natural fractures with different frictional coefficients seem to control stress condition quite locally, such that S _Hmax is relatively low at depths where natural fractures with low frictional coefficients are abundant, while S _Hmax is relatively high at depths where natural fractures with low frictional coefficients are scarce.     

X射线光电光谱表征金属氧化物的酸碱性

本文探讨了氧配位的八面体及四面体的金属配合物中氧原子的价态变化及其酸碱性差异之间的关系。首先利用X射线光电光谱（XPS）分别推导出了氧原子在碱及碱土铝酸盐、铬酸盐、高铁酸盐、钼酸盐及钨酸盐中的价态,随后对氧原子的价态及氧化物的酸碱性质进行了比较。研究结果表明,氧原子的价态在这两种配位构型的化合物中没有显著的差别,其酸碱性的不同在于四面体配位的金属化合物中O2p态在非成键和成键的电子密度中高价带的分裂。