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The compatibility of vanadium (V) during mantle melting is a function of oxygen fugacity (fO2): at high fO2’s, V becomes more incompatible. The prospects and limitations of using the V content of peridotites as a proxy for paleo-fO2 at the time of melt extraction were investigated here by assessing the uncertainties in V measurements and the sensitivity of V as a function of degree of melt extracted and fO2. V-MgO and V-Al2O3 systematics were found to be sensitive to fO2 variations, but consideration of the uncertainties in measurements and model parameters indicates that V is sensitive only to relative fO2 differences greater than ∼2 log units. Post-Archean oceanic mantle peridotites, as represented by abyssal peridotites and obducted massif peridotites, have V-MgO and -Al2O3 systematics that can be modeled by 1.5 GPa melting between FMQ − 3 and FMQ − 1. This is consistent with fO2’s of the mantle source for mid-ocean ridge basalts (MORBs) as determined by the Fe3+ activity of peridotitic minerals and basaltic glasses. Some arc-related peridotites have slightly lower V for a given degree of melting than oceanic mantle peridotites, and can be modeled by 1.5 GPa melting at fO2’s as high as FMQ. However, the majority of arc-related peridotites have V-MgO systematics overlapping that of oceanic mantle peridotites, suggesting that although some arc mantle may melt under slightly oxidizing conditions, most arc mantle does not. The fact that thermobarometrically determined fO2’s in arc peridotites and lavas can be significantly higher than that inferred from V systematics, suggests that V retains a record of the fO2 during partial melting, whereas the activity of Fe3+ in arc peridotitic minerals and lavas reflect subsequent metasomatic overprints and magmatic differentiation/emplacement processes, respectively.Peridotites associated with middle to late Archean cratonic mantle are characterized by highly variable V-MgO systematics. Tanzanian cratonic peridotites have V systematics indistinguishable from post-Archean oceanic mantle and can be modeled by 3 GPa partial melting at ∼FMQ − 3. In contrast, many South African and Siberian cratonic peridotites have much lower V contents for a given degree of melting, suggesting at first glance that partial melting occurred at high fO2’s. More likely, however, their unusually low V contents for a given degree of melting may be artifacts of excess orthopyroxene, a feature that pervades many South African and Siberian peridotites but not the Tanzanian peridotites. This is indicated by the fact that the V contents of South African and Siberian peridotites are correlated with increases in SiO2 content, generating data arrays that cannot be modeled by partial melting but can instead be generated by the addition of orthopyroxene through processes unrelated to primary melt depletion. Correction for orthopyroxene addition suggests that the South African and Siberian peridotites have V-MgO systematics similar to those of Tanzanian peridotites. Thus, if the Tanzanian peridotites represent the original partial melting residues, and if the South African and Siberian peridotites have been modified by orthopyroxene addition, then there is no indication that Archean cratonic mantle formed under fO2’s significantly greater than that of modern oceanic mantle. Instead, the fO2’s inferred from the V systematics in these three cratonic peridotite suites are within range of modern oceanic mantle. This also suggests that the transition from a highly reducing mantle in equilibrium with a metallic core to the present oxidized state must have occurred by late Archean times. 相似文献
24.
E. J. Palin M. T. Dove S. A. T. Redfern C. I. Saniz-Díaz W. T. Lee 《Physics and Chemistry of Minerals》2003,30(5):293-304
As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques
have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K2
[6](Al3Mg)[4](Si7Al)O20(OH)4. Values of the atomic exchange interaction parameters J
n
used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied
and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral
sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst
we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets
alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the
T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range
order was observed.
Received: 8 August 2002 / Accepted: 14 February 2003
Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed
on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility. 相似文献
25.
Determination and application of the weights for landslide susceptibility mapping using an artificial neural network 总被引:38,自引:0,他引:38
The purpose of this study is the development, application, and assessment of probability and artificial neural network methods for assessing landslide susceptibility in a chosen study area. As the basic analysis tool, a Geographic Information System (GIS) was used for spatial data management and manipulation. Landslide locations and landslide-related factors such as slope, curvature, soil texture, soil drainage, effective thickness, wood type, and wood diameter were used for analyzing landslide susceptibility. A probability method was used for calculating the rating of the relative importance of each factor class to landslide occurrence. For calculating the weight of the relative importance of each factor to landslide occurrence, an artificial neural network method was developed. Using these methods, the landslide susceptibility index (LSI) was calculated using the rating and weight, and a landslide susceptibility map was produced using the index. The results of the landslide susceptibility analysis, with and without weights, were confirmed from comparison with the landslide location data. The comparison result with weighting was better than the results without weighting. The calculated weight and rating can be used to landslide susceptibility mapping. 相似文献
26.
John M. Senko Brian S. Campbell James R. Henriksen Mostafa S. Elshahed Lee R. Krumholz 《Geochimica et cosmochimica acta》2004,68(4):773-780
Barite (BaSO4) deposits generally arise from mixing of soluble barium-containing fluids with sulfate-rich fluids. While the role of biological processes in modulating barium solubility has been shown, no studies have shown that the biological oxidation of sulfide to sulfate leads to barite deposition. Here we present an example of microbially mediated barite deposition in a continental setting. A spring in the Anadarko Basin of southwestern Oklahoma produces water containing abundant barium and sulfide. As emergent water travels down a stream to a nearby creek, sulfate concentration increases from 0.06 mM to 2.2 mM while Ba2+ concentration drops from 0.4 mM to less than 7 μM. Stable isotope analysis, microbial activity studies, and in situ experiments provide evidence that as sulfide-rich water flows down the stream, anaerobic, anoxygenic, phototrophic bacteria play a dominant role in oxidizing sulfide to sulfate. Sulfate then precipitates with Ba2+ producing barite as travertine, cements, crusts, and accumulations on microbial mats. Our studies suggest that phototrophic sulfide oxidation and concomitant sulfur cycling could prove to be important processes regulating the cycling of barium in continental sulfur-containing systems. 相似文献
27.
The reflection of plane waves in a poroelastic half-space saturated with inviscid fluid 总被引:8,自引:2,他引:8
Chi-Hsin Lin Vincent W. Lee Mihailo D. Trifunac 《Soil Dynamics and Earthquake Engineering》2005,25(3):205-223
This paper discusses surface displacements, surface strain, rocking, and energy partitioning during reflection-of-plane waves in a fluid-saturated poroelastic half-space. The medium is modeled by Biot's theory, and is assumed to be saturated with inviscid fluid. A linear porosity-modulus relation based on experimental data on sandstones is used to determine the material parameters for Biot's model. Numerical results in terms of angle of incident waves and Poisson's ratio are illustrated for various porosities and degrees of solid frame stiffness. The results show that the amount of solid frame stiffness controls the response of a fluid-saturated porous system. A poroelastic medium with essentially dry-frame stiffness behaves like an elastic medium, and the influence of pore fluid increases as dry-frame stiffness is reduced. The effects of a second P-wave become noticeable in poroelastic media with low dry-frame stiffness. 相似文献
28.
Ji-Hoon Kim Jeongho Lee Tae-Jin Cheong Rak-Hyeon Kim Dong-Chan Koh Jong-Sik Ryu Ho-Wan Chang 《Journal of Hydrology》2005,300(1-4):188-198
The purpose of this study is to apply time series analysis to investigate whether the groundwater quality in the coastal area is affected by the tide. Continuous and regular in situ monitoring data of electrical conductivity (EC) and groundwater level, and tidal level data measured by the National Oceanographic Research Institute were used for the time series analysis. Through the time series analysis, it is known that EC and groundwater level conspicuously fluctuate with two periodicities (15.4 and 0.52-day), which is very similar to those of the tide. Also the behaviors of their fluctuations vary in accordance with the tidal period. These indicate that the groundwater quality has been mainly controlled by the tidal level, and the strength of tidal effect on the groundwater quality is different according to the tidal period. 相似文献
29.
30.
This paper presents a detailed account of the effect of shipping activity on the increasing trends of air temperatures in the Canadian Arctic region for the period of 1980–2018. Increasing trend of temperature has gained significant attention with respect to shipping activities and sea ice area in the Canadian Arctic. Temperature, sea ice area and shipping traffic datasets were investigated, and simple linear regression analyses were conducted to predict the rate of change(per decade) of the average temperature, considering winter(January) and summer(July) seasons. The results indicate that temperature generally increased over the studied region. Significant warming trend was observed during July, with an increase of up to 1℃, for the Canadian Arctic region. Such increasing trend of temperature was observed during July from the lower to higher latitudes. The increase in temperature during July is speculated to increase the melting of ice. Results also show a decline in sea ice area has a significant positive effect on the shipping traffic, and the numbers of marine vessel continue to increase in the region. The increase in temperature causes the breaking of sea ice due to shipping activities over northern Arctic Canada. 相似文献