Tidal variability in benthic silicic acid fluxes and microphytobenthos uptake in intertidal sediment

Silicic acid (DSi) benthic fluxes play a major role in the benthic–pelagic coupling of coastal ecosystems. They can sustain microphytobenthos (MPB) development at the water–sediment interface and support pelagic diatoms when river DSi inputs decrease. DSi benthic fluxes have been studied at the seasonal scale but little is known about their dial variations. This study measured the amplitude of such variations in an intertidal area over an entire tidal cycle by following the alteration of DSi pore water concentrations at regular intervals over the flood/ebb period. Furthermore we independently estimated the potential DSi uptake by benthic diatoms and compared it to the variations of DSi pore water concentrations and fluxes. The microphytobenthos DSi demand was estimated from primary production measurements on cells extracted from the sediment. There were large changes in DSi pore water concentration and a prominent effect of tidal pumping: the DSi flushed out from the sediment at rising tide, occurs in a very short period of time, but plays a far more important role in fueling the ecosystem (800 μmol-Si m⁻² d⁻¹), than diffusive fluxes occurring throughout the rest of the tidal cycle (2 μmol-Si m⁻² d⁻¹). This process is not, to our knowledge, currently considered when describing the DSi cycling of intertidal sediments. Moreover, there was a large potential MPB requirement for DSi (812 μmol-Si m⁻² d⁻¹), similar to the advective flow periodically pumped by the incoming tide, and largely exceeded benthic diffusive fluxes. However, this DSi uptake by benthic diatoms is almost undetectable given the variation of DSi concentration profiles within the sediment.     

Thermal infrared (8-13 μm) spectra of 29 asteroids: the Cornell Mid-Infrared Asteroid Spectroscopy (MIDAS) Survey

We report the results of the Cornell Mid-IR Asteroid Spectroscopy (MIDAS) survey, a program of ground-based observations designed to characterize the 8-13 μm spectral properties of a statistically significant sample of asteroids from a wide variety of visible to near-IR spectral classes. MIDAS is conducted at Palomar Observatory using the Spectrocam-10 (SC-10) spectrograph on the 200-in Hale telescope. We have measured the mid-infrared spectra of twenty-nine asteroids and have derived temperature estimates from our data that are largely consistent with the predictions of the standard thermal model. We have also generated relative emissivity spectra for the target asteroids. On only one asteroid, 1 Ceres, have we found emissivity features with spectral contrast greater than 5%. Our spectrum of 4 Vesta suggests emissivity variation at the 2-3% level. Published spectra of several of the small number of asteroids observed with ISO (six of which are also included in our survey), which appeared to exhibit much stronger emissivity features, are difficult to reconcile with our measurements. Laboratory work on mineral and meteorite samples has shown that the contrast of mid-IR spectral features is greatly reduced at fine grain sizes. Moreover, the NEAR mission found that 433 Eros is covered by a relatively thick fine-grained regolith. If small bodies in general possess such regoliths, their mid-IR spectral features may be quite subtle. This may explain the evident absence of strong emissivity variation in the majority of the MIDAS spectra.     

ISO Observations of Classical Novae

We describe the ISO programme to observe classical novae. The programme includes observations of novae during and shortly after eruption, and old novae. ISO observations of far infrared fine structure lines are providing us with information about physical conditions in nova ejecta which complement and extend knowledge obtained from ground-based observations. Surprisingly, we are getting little information about dust in nova systems, despite the fact that many novae are prolific dust-producers. This revised version was published online in August 2006 with corrections to the Cover Date.     

Greenhouse gases mitigation against climate change: United States-Mexico border study case

Solar radiation is one of the most important energy resources of our planet. The interest in its use as a renewable and clean energy to mitigate the greenhouse gases (GHG) effects has increased significantly. This paper evaluates the measurements of global solar radiation and its energy potential and presents a comparison between both of them, as an example of the effort to reduce GHG emissions. The measurements were made with pyranometers installed in the city of Mexicali, Baja California, located in northwestern Mexico, and the city of Yuma, Arizona, located in the southwestern United States. Separated by a distance of 96 km, both cities have a sustained development and are climatically similar, since they present numerous sunny days, extreme hot temperatures and little precipitation. The results presented show differences in their behavior and in the solar radiation measurement values, especially for the critical spring and summer seasons, with values 15.73% (0.042 kW/m²) higher in Mexicali with respect to Yuma. Energy power is estimated, and it is discussed with some variables as global solar radiation, rainfall, air temperature, relative humidity and climatology of clear, partly cloudy, and cloudy days. With this estimation, the solar energy used and GHG avoided is projected for Mexicali. It is assessed that 291 tons of GHG are prevented. The Mexicali values of potential energy are higher than those of Yuma; therefore, this solar and energy comparative study provides reasons to develop these technologies in Mexico, but solar technologies should be deployed also in Yuma. The measured data at the regional level demonstrate their importance, and the relevance of the proposed mitigation strategy for climate change.     

Application of the chemometric approach to evaluate the spatial variation of water chemistry and the identification of the sources of pollution in Langat River, Malaysia

The current study presents the application of selected chemometric techniques—hierarchical cluster analysis (HCA) and principal component analysis (PCA)—to evaluate the spatial variation of the water chemistry and to classify the pollution sources in the Langat River. The HCA rendered the sampling stations into two clusters (group 1 and group 2) and identified the vulnerable stations that are under threat. Group1 (LY 1 to LY 14) is associated with seawater intrusion, while group 2 (LY 15 to LY 30) is associated with agricultural and industrial pollution. PCA analysis was applied to the water datasets for group 1 resulting in four components, which explained 85 % of the total variance while group 2 extracted six components, explaining 88 % of the variance. The components obtained from PCA indicated that seawater intrusion, agricultural and industrial pollution, and geological weathering were potential sources of pollution to the study area. This study demonstrated the usefulness of the chemometric techniques on the interpretation of large complex datasets for the effective management of water resources.     

Integrative assessment of sediment quality in terms of chemical contamination in Jinhae Bay,South Korea

The assessment of sediment quality by considering chemical contaminants is required for the effective management of coastal environments. In this study, complex data sets of heavy metals and organic pollutants were integrated to evaluate sediment quality. Thirty-two target pollutants were quantitatively determined in surface sediments from 80 stations in Jinhae Bay, South Korea. A sediment quality index (SQI) was derived by combining the functions of “scope” (the number of variables that do not meet guideline objectives) and “amplitude” (the magnitude by which these variables exceed the guideline objective). The SQI reflects the spatial gradient and differences in the contamination status with regard to heavy metals and organic pollutants in Jinhae Bay. Fifty-nine out of eighty stations surveyed (74%) were classified as being in “excellent” or “good” condition according to the SQI, and no stations were in a “poor” condition. The mean sediment quality guideline quotient (mSGQq) ranged from 0.06 to 0.31 (from nontoxic to marginally toxic). Acute sediment toxicity leading to amphipod mortality was recorded at 17 stations (21%) of the 80 surveyed, where the mortality rate was slightly over 20%. No significant relationship was observed between sediment toxicity and the concentration of each toxicant or mSQGq.     

Total Suspended Sediments Mapping by Using ALOS Imagery Over the Coastal Waters of Langkawi Island, Malaysia

Remote sensing has been extensively used for water delineation and has played an important role in water quality evaluation and environmental management strategies. Suspended sediments are important determinants of water quality in coastal zones. Remote sensing enables the effective monitoring of total suspended sediments (TSS) and the detection of areas with critical water quality issues. This study aims to develop and implement regression models for estimating and mapping TSS concentrations from Advanced Land Observation Satellite (ALOS) images over the coastal waters of Langkawi Island, Malaysia. The algorithm was developed based on the water reflectance model, which is a function of the inherent optical properties of water. Such properties can then be linked to TSS concentration. In this study, an ALOS Advanced Visible and Near Infrared Radiometer type 2 device was used as the imaging sensor system. Concurrent complementary in-situ water samples were collected within the area coverage of the sensor, and digital numbers (DN) for each band corresponding to the sea-truth locations were determined. The extracted DN values were converted into reflectance values and then regressed with their respective sea-truth data. An algorithm was proposed to obtain the regression coefficient. This algorithm can estimate TSS concentrations with a high correlation coefficient (R²?=?0.96) and low root-mean-square error (RMSE?=?1.98 mg/l). Finally, a map of the TSS concentration was generated by using the proposed algorithm. This study found that TSS mapping can be conducted by using ALOS data over the coastal waters of Langkawi Island, Malaysia.     

Effects of Lime‐Based Waste Materials on Immobilization and Phytoavailability of Cadmium and Lead in Contaminated Soil

Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.     

Historical record of metal accumulation and lead source in the southeastern coastal region of Korea

Concentrations of heavy metals and Pb isotopes were measured in the 1-M HCl leaching fraction of core sediments spanning the last 400 years. This sedimentary record of pollution history in metal concentrations shows a good correlation with the increases in industrialization, urbanization, and energy consumption since 1901s. Notably, the Pb concentration and the ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios were constant before the 1910s (16.7 μg/g, 0.844, and 2.098, respectively), whereas they increased steadily up to 21.9 μg/g, 0.848, and 2.101 after the 1910s. The correlations between Pb isotope ratios (²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb) showed different linear regression trends for core sediments before and after the 1910s, indicating differences in Pb sources. Our interpretation suggests that the source of anthropogenic Pb in Korean coastal region and the Yellow Sea shelf was presumed to be Chinese coals or ores, which have also played a major role as sources of atmospheric particulate Pb.     

Numerical study on wave dynamics and wave-induced bed erosion characteristics in Potter Cove, Antarctica

Wave generation, propagation, and transformation from deep ocean over complex bathymetric terrains to coastal waters around Potter Cove (King George Island, South Shetland Islands, Antarctica) have been simulated for an austral summer month using the Simulating Waves Nearshore (SWAN) wave model. This study aims to examine and understand the wave patterns, energy fluxes, and dissipations in Potter Cove. Bed shear stress due to waves is also calculated to provide a general insight on the bed sediment erosion characteristics in Potter Cove.A nesting approach has been implemented from an oceanic scale to a high-resolution coastal scale around Potter Cove. The results of the simulations were compared with buoy observations obtained from the National Data Buoy Center, the WAVEWATCH III model results, and GlobWave altimeter data. The quality of the modelling results has been assessed using two statistical parameters, namely the Willmott’s index of agreement D and the bias index. Under various wave conditions, the significant wave heights at the inner cove were found to be about 40–50 % smaller than the ones near the mouth of Potter Cove. The wave power in Potter Cove is generally low. The spatial distributions of the wave-induced bed shear stress and active energy dissipation were found to be following the pattern of the bathymetry, and waves were identified as a potential major driving force for bed sediment erosion in Potter Cove, especially in shallow water regions. This study also gives some results on global ocean applications of SWAN.