Secular evolution of the vertical column abundances of CHCIF2 (HCFC-22) in the Earth's atmosphere inferred from ground-based IR solar observations at the Jungfraujoch and at Kitt Peak,and comparison with model calculations

Series of high-resolution infrared solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, between 06/1986 and 11/1992, and at Kitt Peak National Observatory, Tucson, Arizona (U.S.A.), from 12/1980 to 04/1992, have been analyzed to provide a comprehensive ensemble of vertical column abundances of CHCIF₂ (HCFC-22; Freon-22) above the European and the North American continents. The columns were derived from nonlinear least-squares curve fittings between synthetic spectra and the observations containing the unresolved 2v ₆ Q-branch absorption of CHCIF₂ at 829.05 cm^–1. The changes versus time observed in these columns were modeled assuming both an exponential and a linear increase with time. The exponential rates of increase at one-sigma uncertainties were found equal to (7.0±0.35)%/yr for the Junfraujoch data and (7.0±0.23)%/yr for the Kitt Peak data. The exponential trend of 7.0%/yr found at both stations widely separated in location can be considered as representative of the global increase of the CHCIF₂ burden in the Earth's atmosphere during the period 1980 to 1992. When assuming two realistic vertical volume mixing ratio profiles for CHCIF₂ in the troposphere, one quasi constant and the other decreasing by about 13% from the ground to the tropopause, the concentrations for mid-1990 were found to lie between 97 and 111 pptv (parts per trillion by volume) at the 3.58 km altitude of the Jungfraujoch and between 97 and 103 pptv at Kitt Peak, 2.09 km above sea level. Corresponding values derived from calculations using a high vertical resolution-2D model and recently compiled HCFC-22 releases to the atmosphere, were equal to 107 and 105 pptv, respectively, in excellent agreement with the measurements. The model calculated lifetime of CHCIF₂ was found equal to 15.6 years. The present results are compared critically with similar data found in the literature. On average, the concentrations found here are lower by 15–20% than those derived from in situ investigations; this difference cannot be explained by the absolute uncertainty of ±11% assigned presently to the infrared remote measurements.     

Crystal-field spectra for blue and green diopsides synthesized in the join CaMgSi2O6-CaCrAlSiO6

Synthetic diopsides in the join CaMgSi₂O₆ CaCrAlSiO₆ have been studied by means of crystal-field theory. These diopsides are either blue or pale green in colour. The former forms at lower temperatures and the latter at higher temperatures. The optical spectra and colours can be unequivocally explained based on the assumption that Cr³⁺ions occupy both tetrahedral and octahedral sites in the diopsides. In the blue diopsides Cr³⁺ions are present in two kinds of spin state, i.e., tetrahedrally coordinated low spin and octahedrally coordinated high spin. On heating the blue diopsides, tetrahedral occupancy of chromium decreases sharply due to spin transformation from tetrahedral low spin to octahedral high spin. Above 1,160° C nearly all chromium ions are present in octahedral sites with high spin state and the diopsides become pale green in colour. Some petrogenetic applications of the resultes are discussed.     

Shaking table tests on a high‐rise RC building model having torsional eccentricity in soft lower storeys

A series of shaking table tests on a 1:12‐scale model using scaled TaftN21E earthquake records were conducted to investigate the seismic performance of a 17‐storey high‐rise reinforced concrete structure with a high degree of torsional eccentricity and soft‐storey irregularities in the bottom two storeys. Based on the analysis of test results, the following conclusions were drawn: (1) the model responded mainly in the coupled mode of translation and torsion or in the torsional mode. Under severe table shaking, the flexible side underwent large inelastic deformation, and the predominant mode of the model changed from the coupled mode to the torsional mode, resulting in greatly increased torsional stiffness, thereby limiting damage in the flexible frame; (2) the shear force and deformation of the flexible side were governed by the torsional behaviour, whereas those of the stiff side were affected mainly by the overturning deformation. The lateral stiffness of the shear wall in the torsional mode was about four times that in the coupled mode because the warping deformation due to torsion counteracted the flexural deformation due to overturning moment in the torsional mode; and (3) the reversed cyclic overturning moments predicted by linear elastic dynamic analysis in the direction transverse to the table excitations contradicted unilateral overturning moments of the serviceability‐level test results, which showed a bias towards tension or compression in the columns. Copyright © 2006 John Wiley & Sons, Ltd.     

Variations of the geomagnetic field at the time of reversals

Summary Paleomagnetic investigations of sediments from the Early Quaternary enabled the variations of the geomagnetic field during reversals to be studied. Regularities in the motion of the virtual geomagnetic N paleopole and the related changes in the intensity of the geomagnetic field were determined. The initial phase of the reversal, which took place in the Eastern Hemisphere, is accompanied by an increase in the intensity of the geomagnetic field. A strong decrease occurred at the time the N paleopole was moving around30°N geographic latitude. After the irreversible reversal had been concluded, the intensity of the geomagnetic field stabilized at values corresponding to the field intensity prior to the reversal. The reversible reversal is accompanied by an repeated increase in the itensity of the geomagnetic field.

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Contact conditions on seismoactive faults

Square plate models with a diagonally located slit in compression were studied photoelastically. The resulting stress field surrounding the discontinuity (slit) is evaluated before and after seismoactive (seismic-energy-releasing) shear displacement. The mechanism of the fast shear movement (stick-slip), including its radiation properties, in interpreted. The results confirm the existence of a central locked zone in the loaded slit, the limits of which coincide with the initiation points of stick-slip movements. The zone is interpreted as the source of the seismic energy release. The complementary measurements (direct optical and ultrasonic) are presented to verify the results of the photoelastic analysis. The results obtained are discussed in regard to the conclusions that follow from the theory of elasticity.     

Dating granulite-facies structures and the exhumation of lower crust in the Moldanubian Zone of the Bohemian Massif

Deformation of granulite-facies rocks in the Moldanubian Zone of the southern Bohemian Massif is expressed in two intersecting planar fabrics - steeply disposed (S₁) and flat-laying (S₂) - which correspond to two deformation stages (D₁) and (D₂). The existing Sm-Nd garnet ages from banded granulite gneisses, new U-Pb zircon data from deformed granite intrusions within the granulite gneisses, and the P-T and field structural relations constrain the ages and P-T conditions of the two deformation phases. The early deformation (D₁) was associated with a HP-HT metamorphic stage with a minimum age of ca. 354 Ma which was followed by a near-isothermal decompression. A concordant U-Pb zircon age of 318ǃ Ma dates the emplacement of intrusions of deformed granite into the granulite gneisses and constrains deformation phase (D₂). This phase was associated with an LP-HT metamorphism dated in the region at ca. 340-330 Ma. The available structural and isotopic data indicate that granulites in the southern Bohemian Massif were exhumed from lower to middle crust during compression. The structural relations and P-T-t data for the studied granulites are consistent with their exhumation by near-vertical extrusion of the softened orogenic root.     

Experimental investigation of adjacent buildings connected by fluid damper

Dynamic characteristic and harmonic response of adjacent buildings connected by fluid damper were experimentally investigated using model buildings and fluid damper. Two building models were constructed as two three-storey shear buildings of different natural frequencies. Model fluid damper connecting the two buildings was designed as linear viscous damper of which damping coefficient could be adjusted. The two buildings without fluid dampers connected were first tested to obtain their individual dynamic characteristics and responses to harmonic excitation. The tests were then carried out to determine modal damping ratios of the adjacent buildings connected by the fluid damper of different damping coefficients and at different locations. Optimal damper damping coefficient and location for achieving the maximum modal damping ratio were thus found. The measured modal damping ratios and harmonic responses of the building-fluid damper system were finally compared with those from the individual buildings. The comparison showed that the fluid damper of proper parameter could significantly increase the modal damping ratio and tremendously reduce the dynamic response of both buildings. Copyright © 1999 John Wiley & Sons, Ltd.     

Marine 3D seismic volumes from 2D seismic survey with large streamer feathering

Marine Geophysical Research - Strong ocean current influences a marine seismic survey and forces the streamer off-course from the survey line. The sideway drift of the streamer results in that the...     

The influence of a heavily polluted urban river on the adjacent aquifer systems

 Ankara Creek is often subjected to overflowing of sewage caused by rainfall or direct discharge of raw sewage. Alluvial aquifers adjacent to Ankara Creek and its tributaries have considerable groundwater potential. The present status of groundwater quality is far from drinking water standards. Groundwater contamination in Ankara is suspected to be caused by Ankara Creek which is heavily polluted by raw sewage discharge, surface runoff and other common sources. In order to investigate the influence of heavily polluted Ankara Creek on the groundwater contamination in the adjacent alluvial aquifers, five sampling stations on Ankara Creek and 25 water wells were monitored during 1996. At five different sampling periods, water samples were collected from both surface water and groundwater. Chemical analyses of basic ions, pollution parameters and heavy metals in natural waters were carried out. The organic pollution prevails in Ankara Creek whereas total dissolved solids (TDS) and heavy metal concentrations are considerably low. Starting from the idea that Ankara Creek somewhat influences the groundwater quality and the contaminants in groundwater should attenuate with respect to distance, a series of water wells in a certain area, each having different distance from the creek, were examined using four pollution parameters. It is concluded that Ankara Creek barely influences the aquifer systems in connection. This is attributed to two reasons: rapid attenuation of contaminants due to dilution in groundwater and a blanket of very fine sized materials covering the bottom of Ankara Creek. Received: 28. April 1997 · Accepted: 23. February 1998