Impacts of Coagulation Pretreatment on MF Filtration and a Comparative Study of Different Membrane Module Types

Changes in the regulatory requirements and the forthcoming Disinfectant/Disinfection By-Products （D/DBP） Rule will require that drinking water treatment facilities be operated to achieve maximum removals of particles and disinfectant tolerant microorganisms as well as natural organic matter （NOM）. For drinking water production, the use of membrane filtration processes such as microfiltration and ultrafiltration （MF/UF） alone to satisfy the turbidity, particle and microorganism removal a requirement of the surface water treatment regulation （SWTR） is not enough. MF/UF treatment processes can achieve only nominal （10 percent） removal of disinfection by-products （DBP） precursors （James, et al., 1995）. On the other hand, too fast fouling can make the filtration processes more difficult to carry on. To solve these problems, many authors have been interested in installing coagulation pretreatment before membrane filtration to improve membrane performance. However, previous studies reported conflicting results. Some supported the effectiveness of coagulation pretreatment, while others contended that coagulation aggravated membrane performance. This research aims to identify the effects of coagulation pretreatment on membrane filtration through a pilot study using PVDF membrane in combination with analyzing the rationale of coagulation. Another objective of this research was to evaluate the different impacts on membrane performance of using different membrane modules （the submerged module and pressured module）. The results showed that coagulation pretreatment greatly improved the membrane performance, extending the filtration time as well as reducing the permeated organic level, and that the submerged module is much more efficient than the pressured module.     

中国金伯利岩中的钛铁矿

本文研究了金伯利岩中,作为巨晶和粗晶,基质相矿物,与金云母、镁铝榴石、铬尖晶石等矿物的连生体,金刚石中包裹体矿物及金伯利岩地幔岩包裹体矿物产出的钛铁矿的大小,形态、皮壳及化学成分、端元组分、环带及成分变异趋势。并与其他岩类中的钛铁矿作了对比。探讨了不同产状、共生组合类型的钛铁矿的成因。指出了与金刚石紧密伴生的钛铁矿的标型特征及找矿意义。     

青岛即墨月亮湾岸滩开发利用与岸线整治保护工程方案分析

从整治工程区海域由于受潮流、波浪影响侵蚀和严重蚀退的海岸线,防治现状岸线入手,对工程区域的工程环境进行了综合研究,对岸滩开发利用整治与岸线保护工程方案进行了比选分析.结果表明,该工程区域采用斜坡堤护岸结构形式对岸线进行保护是较合理的.这样,可以对优化工程环境,保护当地的海洋岸线,防治岸线蚀退,美化岸滩自然环境取得更好的...     

关于勒让德函数的一组特殊定积分递推公式

根据勒让德函数理论的基本递推公式和基本性质 ,详细推导了在重力梯度调和分析中出现的一组特殊定积分的递推公式 ;并且指出 ,这组递推公式对于物理大地测量的调和分析理论也具有一定的价值。     

Adsorption of aqueous Pb(II), Cu(II), Zn(II) ions by amorphous tin(VI) hydrogen phosphate: an excellent inorganic adsorbent

Amorphous tin(VI) hydrogen phosphate (ATHP) was synthesized using the liquid phase precipitation method and served as an adsorbent to remove Pb(II), Cu(II), and Zn(II) from aqueous solutions. The ATHP was characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption–desorption techniques. Adsorption properties were evaluated as a function of pH, reaction time, concentration of reactants, and salinity. Their equilibrium adsorption data were modeled using Freundlich, Langmuir, and Dubinin–Kaganer–Radushkevich isotherms, respectively. The results revealed that adsorption equilibrium reached within 180 min. ATHP indicated good adsorption even below the pH_ZPC, and best adsorption at pH 5 for Pb(II) and Cu(II) and at pH 5.5 for Zn(II) was observed. Equilibrium data fitted better to the Langmuir model for Pb(II) and Cu(II) and fitted better to the Freundlich model for Zn(II). The saturated adsorption capacities deduced from the Langmuir model were 2.425, 1.801, and 0.600 mmol/g for Cu(II), Pb(II), and Zn(II), respectively, indicating an adsorption affinity order of Cu > Pb > Zn. There is a negative correlation between the concentration of NaCl and adsorption capacity of ATHP, yet ATHP still exhibited excellent adsorption having an adsorption capacity of 19.35, 15.16, 6.425 mg/g when the concentration of NaCl was 0.6 mol/L. The free energy (E) was 12.33, 10.70, and 14.74 kJ/mol for Pb(II), Cu(II), and Zn(II), respectively. An adsorption mechanism based on ion exchange between heavy metal ions and H⁺ in the ATHP is proposed. Furthermore, the used ATHP was regenerated by HCl solution and the adsorbent was used repeatedly.     

南天山巴音布鲁克花岗岩岩体成因:锆石U-Pb定年、Hf同位素及其地球化学证据

巴音布鲁克岩体为南天山北缘出露不多的代表性早古生代花岗岩体,由二长花岗岩和钾长花岗岩构成,两类岩石均显示富集Rb、Ba、Th、K和Pb等LILE,亏损Nb、Ta、Ti等HFSE的活动陆缘弧岩浆地球化学特征。其中,二长花岗岩相对低SiO_2和K_2O,略高CaO、Fe_2O_3T和MgO,具轻重稀土中等分馏、弱负Eu异常的稀土元素分布模式。钾长花岗岩明显高SiO_2,富K_2O,低CaO和MgO,强烈亏损Sr、Ba、Eu、Ti和P,高DI指数(94.31~95.52)和高Rb/Sr比值,轻重稀土中等分馏,呈现出强负Eu异常的稀土分布模式,指示岩浆经历了较高程度演化。二长花岗岩和钾长花岗岩分别获得464.5±3.5Ma和430.2±3.2 Ma的形成年龄,对应的锆石εHf(t)分别为-8.66~-6.56和-5.33~-2.19,Hf陆壳模式年龄TDMC分别为1.58~1.69Ga和1.33~1.49Ga,明显高于其形成年龄,表明岩浆主要源自中元古代基底陆壳物质的部分熔融。结合南天山北缘和中天山南缘类似的同期花岗岩的广泛出现认为,巴音布鲁克岩体中的二长花岗岩和钾长花岗岩分别代表了南天山洋早期俯冲消减活动陆缘弧岩浆和晚期成熟岩浆演化的结果,表明其大洋俯冲消减作用一直持续到志留世仍未结束。     

遥感信源色彩信号的提取与复现

提出遥感信源色彩信号的提取及复现理论,给出了可操作的技术路线,设计了提取与复现程序,用MODIS(中等分辨率航天成像光谱仪)数据提取并复现了色彩信号,生成了色彩信号图像。未进行大气校正的色彩信号图像等效于太空对地摄影,从图像可看出,地物被笼罩在瑞利散射形成的蓝色“云雾”下。经瑞利散射纠正后的色彩信号图像接近于地面真彩色摄影,非专业人员能根据地物颜色及阴影判读出常见地物。理论可用于遥感信源地面真彩色图像重建、色彩信号不完整信源彩色仿真、航天对地真彩色摄影、信源质量评价。     

The effect of aerosol representation on cloud microphysical properties in Northeast Asia

This study performed a three-dimensional regional-scale simulation of aerosol and cloud fields using a meso-scale non-hydrostatic model with a bin-based cloud microphysics. The representation of aerosols in the model has been improved to account for more realistic multi-modal size distribution and multiple chemical compositions. Two case studies for shallow stratocumulus over Northeast Asia in March 2005 were conducted with different aerosol conditions to evaluate model performance. Improved condensation nuclei (CN) and cloud condensation nuclei (CCN) are attributable to the newly constructed aerosol size distribution. The simulated results of cloud microphysical properties (cloud droplet effective radius, liquid water path, and optical thickness) with improved CN/CCN number are close to the retrievals from satellite-based observation. The effects of aerosol on the microphysical properties of shallow stratocumulus are investigated by model simulation, in terms of columnar aerosol number concentration. Enhanced aerosol number concentration results in increased liquid water path in humid case, but invariant liquid water path in dry case primarily due to precipitation occurrence. The changes of cloud microphysical properties are more predominant for small aerosol burden than for large aerosol burden with the retarded changes in cloud mass and size due to inactive condensation and collision-coalescence processes. Quantitative evaluation of sensitivity factor between aerosol and cloud microphysical properties indicates a strong aerosol-cloud interaction in Northeast Asian region.     

Tropical Pacific impacts of convective momentum transport in the SNU coupled GCM

Impacts of convective momentum transport (CMT) on tropical Pacific climate are examined, using an atmospheric (AGCM) and coupled GCM (CGCM) from Seoul National University. The CMT scheme affects the surface mainly via a convection-compensating atmospheric subsidence which conveys momentum downward through most of the troposphere. AGCM simulations—with SSTs prescribed from climatological and El Nino Southern Oscillation (ENSO) conditions—show substantial changes in circulation when CMT is added, such as an eastward shift of the climatological trade winds and west Pacific convection. The CMT also alters the ENSO wind anomalies by shifting them eastward and widening them meridionally, despite only subtle changes in the precipitation anomaly patterns. During ENSO, CMT affects the low-level winds mainly via the anomalous convection acting on the climatological westerly wind shear over the central Pacific—so that an eastward shift of convection transfers more westerly momentum toward the surface than would occur without CMT. By altering the low-level circulation, the CMT further alters the precipitation, which in turn feeds back on the CMT. In the CGCM, CMT affects the simulated climatology by shifting the mean convection and trade winds eastward and warming the equatorial SST; the ENSO period and amplitude also increase. In contrast to the AGCM simulations, CMT substantially alters the El Nino precipitation anomaly patterns in the CGCM. Also discussed are possible impacts of the CMT-induced changes in climatology on the simulated ENSO.     

Ocean–atmosphere coupling and the boreal winter MJO

The influence of ocean–atmosphere coupling on the simulation and prediction of the boreal winter Madden–Julian Oscillation (MJO) is examined using the Seoul National University coupled general circulation model (CGCM) and atmospheric—only model (AGCM). The AGCM is forced with daily SSTs interpolated from pentad mean CGCM SSTs. Forecast skill is examined using serial extended simulations spanning 26 different winter seasons with 30-day forecasts commencing every 5 days providing a total of 598 30-day simulations. By comparing both sets of experiments, which share the same atmospheric components, the influence of coupled ocean–atmosphere processes on the simulation and prediction of MJO can be studied. The mean MJO intensity possesses more realistic amplitude in the CGCM than in AGCM. In general, the ocean–atmosphere coupling acts to improve the simulation of the spatio-temporal evolution of the eastward propagating MJO and the phase relationship between convection (OLR) and SST over the equatorial Indian Ocean and the western Pacific. Both the CGCM and observations exhibit a near-quadrature relationship between OLR and SST, with the former lagging by about two pentads. However, the AGCM shows a less realistic phase relationship. As the initial conditions are the same in both models, the additional forcing by SST anomalies in the CGCM extends the prediction skill beyond that of the AGCM. To test the applicability of the CGCM to real-time prediction, we compute the Real-time Multivariate MJO (RMM) index and compared it with the index computed from observations. RMM1 (RMM2) falls away rapidly to 0.5 after 17–18 (15–16) days in the AGCM and 18–19 (16–17) days in the CGCM. The prediction skill is phase dependent in both the CGCM and AGCM.