Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

去冬渤海及黄海北部海域冰情严重

去年入冬以来,我国大部分地区连续受冷空气的影响,气温比常年有显著的下降趋势,从而也导致了渤海及黄海北部海域冰情较为严重.根据海洋观测站、遥感中心、航空监测的实测资料以及NOAA卫星图像分析:辽东湾、渤海湾、莱州湾及黄海北部流冰范围分别在90海里、20海里、5海里、25海里内;最大冰厚分别是50厘米、25厘米、15厘米、30厘米;结冰类型大部分是灰冰、莲叶冰、冰皮和少量的灰白冰.今年该海域的结冰现象是近十几年来最为严重的一年.     

塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。     

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.     

New Isophlebioid Dragonflies from the Middle Jurassic of Inner Mongolia,China(Insecta:Odonata:Isophlebioptera:Campterophiebiidae)

Three new species of fossil dragonflies assigned to Sinokaratawia Nel,Huang and Lin in family Campterophlebildae,i.e.S,daohugouica sp.nov.,S.magica sp.nov.and S.gloriosa sp.nov.,and new materials of male S.prokopi Nel,Huang and Lin,2007 are described from the Middle Jurassic of Daohugou,Inner Mongolia,China.An emended diagnosis of genus Sinokaratawia was proposed.     

水文时间序列周期识别的新思路与两种新方法

针对水文序列周期识别的困难,提出首先对原序列处理,再识别周期的新思路,同时提出两种新方法:一种是模拟延长序列法,即通过建模延长原序列,再应用最大熵谱分析法(MESA)对延长序列识别周期;另一种方法是构建主频序列法,应用小波重构法重构原序列主频部分,然后应用MESA对重构序列进行周期识别。结合实例,运用多种方法对同一序列进行周期识别。分析结果表明:由于受序列长度偏短、偏态性、复杂随机成分等因素的影响,传统单一处理方法(周期图法、FFT、MESA、小波分析)周期识别效果并不理想,而使用两种新方法可以有效地减小或消除上述因素的影响,周期识别效果有明显改善。     

Bringing GPS into harsh environments for fully automated deformation monitoring

Engineering projects that require deformation monitoring frequently utilize geodetic sensors to measure displacements of target points located in the deformation zone. In situations where control stations and targets are separated by a kilometer or more, GPS can offer higher precision position updates at more frequent intervals than can normally be achieved using total station technology. For large-scale deformation projects requiring the highest precision, it is therefore advisable to use a combination of the two sensors. In response to the need for high precision, continuous GPS position updates in harsh deformation monitoring environments, a software has been developed that employs triple-differenced carrier-phase measurements in a delayed-state Kalman filter. Two data sets were analyzed to test the capabilities of the software. In the first test, a GPS antenna was displaced using a translation stage to mimic slow deformation. In the second test, data collected at a large open pit mine were processed. It was shown that the delayed-state Kalman filter developed could detect millimeter-level displacements of a GPS antenna. The actual precision attained depends upon the amount of process noise infused at each epoch to accommodate the antenna displacements. Higher process noise values result in quicker detection times, but at the same time increase the noise in the solutions. A slow, 25 mm displacement was detected within 30 min of the full displacement with sigma values in E, N and U of ±10 mm or better. The same displacement could also be detected in less than 5 h with sigma values in E, N and U of ±5 mm or better. The software works best for detecting long period deformations (e.g., 20 mm per day or less) for which sigma values of 1–2 mm are attained in all three solution components. It was also shown that the triple-differenced carrier-phase observation can be used to significantly reduce the effects of residual tropospheric delay that would normally plague double-differenced observations in harsh GPS environments.

南襄盆地及邻域壳幔结构地球物理特征与油气条件分析

位于秦岭-大别造山带中部的南襄盆地,主要由泌阳凹陷、南阳凹陷和襄樊凹陷组成.该盆地及邻域的壳幔结构主要特点是中部地壳明显比两侧地带厚,而上部地壳和下部地壳薄于两侧;Moho界面起伏较大,盆地中部Moho界面深约30 km,盆地边缘约35 km;Moho界面起伏与盆地呈"镜像关系";地震软流圈顶部在盆地一带表现为凸起"柱状"形态,最浅约70 km.根据该盆地内控制凹陷的断层形态以及泌阳凹陷油气条件,预测该盆地具有良好的油气前景.     

A bootstrap based space–time surveillance model with an application to crime occurrences

This study proposes a bootstrap-based space–time surveillance model. Designed to find emerging hotspots in near-real time, the bootstrap based model is characterized by its use of past occurrence information and bootstrap permutations. Many existing space–time surveillance methods, using population at risk data to generate expected values, have resulting hotspots bounded by administrative area units and are of limited use for near-real time applications because of the population data needed. However, this study generates expected values for local hotspots from past occurrences rather than population at risk. Also, bootstrap permutations of previous occurrences are used for significant tests. Consequently, the bootstrap-based model, without the requirement of population at risk data, (1) is free from administrative area restriction, (2) enables more frequent surveillance for continuously updated registry database, and (3) is readily applicable to criminology and epidemiology surveillance. The bootstrap-based model performs better for space–time surveillance than the space–time scan statistic. This is shown by means of simulations and an application to residential crime occurrences in Columbus, OH, year 2000.     

山西省基础地理信息数据库的技术研究

山西省基础地理信息数据库是山西省空间数据基础设施建设的重要组成部分,主要介绍数据库建设的技术方案和关键技术.