Palaeoecological tools for improving the management of coastal ecosystems: a case study from Lake King (Gippsland Lakes) Australia

Since European settlement began over 200 years ago, many southeast Australian coastal lakes and lagoons have experienced substantial human impacts, including nutrient enrichment. Present day management and conservation efforts are often hampered by a lack of data on pre-impact conditions. We used a palaeoecological approach at Lake King, Gippsland Lakes, southeast Australia in order to determine its pre-impact condition and to establish the nature and direction of subsequent environmental changes, including responses to the construction of a permanent entrance to the sea in 1889. A 120 cm sediment core was analysed for diatoms, chlorophyll a, total carbon, nitrogen and sulphur, and dated using ²¹⁰Pb. Past phosphate and salinity concentrations were reconstructed using diatom-phosphate and diatom-salinity transfer functions developed from a calibration set based on 53 sites from 14 southeast Australian coastal lakes and lagoons. Results show changes in the diatom assemblage that record a shift from a brackish-water to marine diatom flora since construction of the permanent entrance. Phosphate concentrations increased at the same time and experienced major peaks in the 1940s and 1950s to >100 μg/l. Chlorophyll a concentrations were generally below 24 μg/l/gTOC in the core, but there has been a clear increase since the 1980s, peaking at 120 μg/l/gTOC, likely associated with a recorded increase in the frequency of nuisance algal blooms. These results indicate that the Lake King environment is now very different to that present during early European settlement. We conclude that by identifying the nature and direction of environmental change, palaeoecological studies can contribute towards developing realistic and well-informed management, conservation and restoration strategies in Australian coastal ecosystems.     

Farmers’ coping response to the low flows in the lower Yellow River: A case study of temporal dimensions of vulnerability

Water scarcity in northern China has been a topic of concern in China for many years, but the increased frequency and duration of “no-flow” events in the Yellow River in the 1990s created a flurry of recent activity in the academic and policy arenas. These low-flow events severely disrupted the supply of irrigation water for agriculture in the lower reaches of the Yellow River and posed a substantial threat to farmers’ livelihoods. Within a broader effort to assess farmers’ vulnerability to water shortages, this qualitative research focuses on the coping mechanisms and adaptive strategies adopted by farming households in three villages in Shandong Province (Ma, Ding, and Xing). With increasing water stress and other stresses from land degradation and lack of market access, farmers’ coping mechanisms have evolved, expanding from one-time adjustments to long-term adaptations, and switching focus from securing reliable water sources to improving irrigation efficiency and diversifying both on-farm and off-farm production. The three villages have different vulnerability profiles and adopted different patterns of adaptive processes that reveal the key roles played by community leaders and the early innovators. The research presented here contributes a temporal and dynamic dimension to the study of vulnerability which is largely missing from the current literature, and provides practical insights about how to improve farmers’ adaptive capacities in the face of water shortages in northern China.     

Analysis of Water Saturation, NAPL Content, Degradation Half-Life, and Lower Boundary Conditions on VOC Transport Modeling: Implications for Closure of Soil Venting Systems

Simulations using a one-dimensional, analytical, vadose zone, solute-transport screening code (VFLUX) were conducted to assess the effect of water saturation, NAPL saturation, degradation half-life, and boundary conditions at the vadose zone/ground water interface on model output. At high initial soil concentrations, model output was significantly affected by input parameters and lower boundary conditions yet still resulted in consistent decision-making to initiate or continue venting application. At lower soil concentrations, however, typical of what is observed after prolonged venting application, differences in model input and selection of lower boundary conditions resulted in inconsistent decision-making. Specifically, under conditions of low water saturation, use of a first-type, time-dependent lower boundary condition indicated that the primary direction of mass flux was from ground water to the vadose zone, suggesting little benefit from continued venting application. Use of a finite, zero-gradient lower boundary condition, though, indicated continued mass flux from the vadose zone to ground water, suggesting a continued need for venting application. In this situation, sensitivity analysis of input parameters, selection of boundary conditions, and consideration of overall objectives in vadose zone modeling become critical in regulatory decision-making.     

A critical assessment of the analysis and distributions of scytonemin and related UV screening pigments in sediments

High performance liquid chromatography-mass spectrometry has been used to identify the cyanophyta-derived ultraviolet screening pigment scytonemin and its reduced counterpart in an Antarctic lake sediment. The formation of an artefact during the analysis has been demonstrated, enabling the recovery of improved estimates of the scytonemin and reduced scytonemin signals. The overall pigment composition records a primary producer community comprising both oxygenic and anoxygenic photoautotrophs, with variations in the abundance of scytonemin relative to the chlorophylls and carotenoids that are consistent with changes in response to variations in the light regime over time.     

Wave propagation and soil–structure interaction on a cliff crest during the 1999 Athens Earthquake

During the 1999 Athens Earthquake the town of Adàmes, located on the eastern cliff of the Kifissos river canyon, experienced unexpectedly heavy damage. Despite the significant amplification potential of the slope geometry, topography effects cannot alone explain the uneven damage distribution within a 300 m zone behind the crest, characterized by a rather uniform structural quality. This paper illustrates the important role of soil stratigraphy, material heterogeneity, and soil–structure interaction on the characteristics of ground surface motion. For this purpose, we first perform elastic two-dimensional wave propagation analyses utilizing available geotechnical and seismological data, and validate our results by comparison with aftershock recordings. We then conduct non-linear time-domain simulations that include spatial variability of soil properties and soil–structure interaction effects, to reveal their additive contribution in the topographic motion aggravation.     

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.     

Beach profile evolution as an inverse problem

Beach evolution models are normally applied in a prognostic fashion, with parameters and boundary conditions estimated from previous experience or other forecasts. Here, we use observations of beach profiles to solve a beach profile evolution equation in an inverse manner to determine model parameters and source function. The data used to demonstrate the method are from Christchurch Bay in Dorset, UK. It was found that there is a significant contribution from diffusive processes to the morphodynamic evolution of the beach profiles and that the development and disappearance of near-shore coastal features such as upper beach berms and inter- and sub-tidal bars are well captured by the source function in the governing equation.     

Tectonic controls on Miocene sedimentation in the Southern Taranaki Basin and implications for New Zealand plate boundary deformation

Miocene strata in the southern Taranaki Basin (STB), up to 3 km thick, provide a distal record of erosion associated with plate boundary deformation in New Zealand. 2D and 3D seismic reflection data tied to drillhole stratigraphy have been used to constrain four main phases of basin development. These are: (a) Early Miocene (22–19 Ma) subsidence, dominantly bathyal water depths and deposition of minor submarine fans along the eastern basin margin. (b) Middle Miocene (19–14 Ma) widespread submarine fan deposition on a bathyal basin floor in the central STB. (c) Rapid Middle–Late Miocene (14–7 Ma) progradation of the shelf break northwards across the STB. (d) Widespread uplift and erosion of the STB during the latest Miocene–Pliocene (7–4.5 Ma). Bathyal water depths and fan deposition in the Early Miocene were influenced by vertical motions on major reverse faults and regional subsidence produced by subduction of the Pacific plate beneath northern New Zealand. Subsequent submarine fan deposition and northward shelf‐break progradation reflect increasing input of terrigenous material, primarily eroded from an uplifting region to the south of the STB. Sedimentation patterns in the STB are consistent with the age and locations of conglomerates deposited in onshore West Coast basins, related to this uplift and erosion. Sediment transport in the West Coast region was mainly parallel to NNE trending active reverse faults, and in the STB was perpendicular to the NE‐SW orientated shelf break, especially from ca. 14–7 Ma, when sedimentation rates exceeded fault‐displacement rates. Increases in sedimentation rates in the STB coincide with regional increases in the rates of shortening that appear to reflect plate boundary‐wide events and have been attributed to, or correlated with, increases in the plate convergence rate. Miocene sedimentation patterns in the STB thus reflect both intra‐basinal deformation and tectonic signals from the wider developing New Zealand plate boundary.