Riphean fine-grained aluminosilicate clastic rocks in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh: Principal litho-geochemical characteristics

Analysis of the litho-geochemistry of fine-grained terrigenous rocks (metapelites, shales, and mudstones) of sedimentary megasequences in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh indicates that Riphean sequences in these regions are dominated by chlorite-hydromica rocks, with montmorillonite and potassic feldspar possibly occurring only in some of the lithostratigraphic units. According to the values of their hydrolysate modulus, most clay rocks from the three Riphean metamorphosed sedimentary sequences are normal or supersialites, with hydrosialites and hydrolysates playing subordinate roles. The most lithochemicaly mature rocks are Riphean clays in the Yenisei Kryazh (Yenisei Range). The median value of their CIA is 72, whereas this index is 70 for fine-grained aluminosilicate rocks from the Uchur-Maya area and 66 for fine-grained terrigenous rocks of the Riphean stratotype. Hence, at ancient water provenance areas from which aluminosilicate clastic material was transported in sedimentation basins in the southwestern (in modern coordinates) periphery of the Siberian Platform, the climate throughout the whole Riphean was predominantly humid. At the same time, the climate at the eastern part of the East European Platform was semiarid-semihumid. The K₂O/Al₂O₃ ratio, which is employed as an indicator of the presence of petro-and lithogenic aluminosilicate clastic component in Riphean sedimentary megasequences, shows various tendencies. According to their Sc, Cr, Ni, Th, and La concentrations and the Th/Sc ratio, the overwhelming majority of Riphean shales and mudstones notably differ from the average Archean mudstone and approach the average values for post-Archean shales. This suggests that mafic Archean rock in the provenance areas did not play any significant role in the origin of Riphean sedimentary megasequences. The Co/Hf and Ce/Cr ratios of the terrigenous rocks of the three Riphean megaseqeunces and their (Gd/Yb) _N and Eu/Eu* ratios place these rocks among those containing little (if any) erosion products of primitive Archean rocks. According to various geochemical data, the source of the great majority of fine-grained aluminosilicate clastic rocks in Riphean sediment megasequences in our study areas should have been mature sialic (felsic), with much lower contents of mafic and intermediate rocks as a source of the clastic material. The REE patterns of the Riphean shales and metapelites in the Bashkir Meganticlinorium, Uchur-Maya area, and Yenisei Kryazh show some features that can be regarded as resulting from the presence of mafic material in the ancient provenance areas. This is most clearly seen in the sedimentary sequences of the Uchur-Maya area, where the decrease in the (La/Yb) _N ratio up the sequence of the fine-grained terrigenous rocks from 15–16.5 to 5.8–7.1 suggests that mantle mafic volcanics were brought to the upper crust in the earliest Late Riphean in relation to rifting. Analysis of the Sm-Nd systematics of the Riphean fine-grained rocks reveals the predominance of model age values in the range of 2.5–1.7 Ga, which can be interpreted as evidence that the rocks were formed of predominantly Early Proterozoic source material. At the same time, with regard for the significant role of recycling in the genesis of the upper continental crust, it seems to be quite possible that the ancient provenance areas contained Archean complexes strongly recycled in the Early Proterozoic and sediments formed of their material. An additional likely source of material in the Riphean was mafic rocks, whose variable contribution is reflected in a decrease in the model age values. Higher Th and U concentrations in the Riphean rocks of the Yenisei Kryazh compared to those in PAAS indicate that the sources of their material were notably more mature than the sources of fine-grained aluminosilicate clastic material for the sedimentary megaseqeunces in the Southern Urals and Uchur-Maya area.     

Petrogeochemical features of metaterrigenous rocks of the Kan Block of the Eastern Sayan: Reconstructions of provenances and sedimentation conditions

Chemical and isotopic compositions of Proterozoic metaterrigenous rocks of the Kan Block (Central and Idar terranes) of the Eastern Sayan are studied. The results of the reconstruction of their provenances and sedimentation conditions are presented. The rocks under investigation correspond by their petrogeochemical composition to graywackes of island arcs. The combination of geochemical and isotope data shows that sediments of the Central terrane had a local provenance represented by Early Proterozoic subduction magmatic complexes, whereas sediments of the Idar terrane formed probably as the result of mixing of terrigenous material related to the destruction of rocks of Meso-Neoproterozoic oceanic and more ancient continental crust.     

Effects of the Wind and Ice Conditions on the Upwelling along the Western Kamchatka Coast (Sea of Okhotsk) Based on the Satellite Data

The variability of the upwelling along the western coast of the Kamchatka Peninsula (northeastern part of the Sea of Okhotsk) has been studied based on an analysis of the multisensor satellite data. The intensity of upwelling is estimated on the basis of wind-forced offshore Ekman transport (upwelling index). The wind data for studying the seasonal variation of upwelling were collected in 1999–2009 using a Quik-SCAT/SeaWinds scatterometer. The upwelling events along the western Kamchatka coast were observed in December at the beginning of the winter monsoon period. During the period of strong winter monsoon northern winds from January to the middle of March, the drifting ice prevents the upwelling of the deep water at the western Kamchatka shelf edge under the mean conditions. The oceanographic data show that upwelling in the western coastal zone of Kamchatka was also observed during the transitional periods from winter to the summer monsoon (April). In summer, upwelling events are rarely observed in this region. The main cause of the summer upwelling is the propagation of the atmospheric cyclones over the Kamchatka Peninsula.     

Late Precambrian terrigenous rocks of the Anamakit–Muya zone of the Baikal–Muya belt: geochemistry and results of LA-ICP-MS dating of detrital zircons

A comparative geochemical characteristics of Late Precambrian sedimentary rocks (Ust’-Kelyana and Tuluya rock units) in the Anamakit–Muya zone of the Baikal–Muya belt is given, and the conditions of their sedimentation are considered. The first results of U–Pb (LA-ICP-MS) dating of detrital zircons and Sm–Nd isotope data on the Tuluya unit deposits are presented. Petrogeochemical study showed that the studied sediments are first-cycle rocks similar in composition to terrigenous island-arc sediments. The low contents of Th, Rb, Zr, Hf, and LREE and high contents of Co, Ni, Sc, V, Cr, and Fe₂O₃* in the sandstones of the Ust’-Kelyana unit evidence that these rocks are similar to oceanic-arc deposits. In contrast, the enrichment of the Tuluya unit rocks in Zr, LREE, Th, Rb, and Nb indicates their similarity to deposits of continental island arcs or active continental margin. Isotope-geochronological studies of the Tuluya rock unit showed the mixing of detrital material resulted from the erosion of Neoproterozoic island-arc igneous rock associations (625–700 Ma), like those in the Karalon–Mamakan zone (Yakor’ and Karalon Formations), and more ancient associations, like the Kelyana (812–824 Ma) and/or Dzhaltuk Groups. Judging from the minimum age of detrital zircon, the lower time bound of sedimentation corresponds to 0.6 Ga.     

Assessment of atmospheric emissions of pollutants and greenhouse gases from the civil aviation of Russia

Presented are the results of computation of emissions of pollutants and greenhouse gases from civil aircrafts in the first decade of the 21st century (from 2000 to 2012). It is revealed that in 2012 the emissions of pollutants to the atmospheric surface layer were reduced by 22.0–61.4% as compared with 2000, and those of greenhouse gases, by 30.6–62.3%. Environmental conditions in the area of large airports can remain rather strained. It is demonstrated that in 2012 the emissions of the majority of pollutants and greenhouse gases to the upper tropospheric layer increased by 41.9–48.5 and 43.7%, respectively, as compared with 2000. The inflow of gaseous compounds of different types of activity to the atmosphere can increase the total negative effect.