Determination of Antibiotic Residues in Manure,Soil, and Surface Waters

In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil.     

Neotectonics and extension direction of the Southern Kenya Rift, Lake Magadi area

The Magadi area, located in the southern part of the Kenya Rift, is a seismically active region where rifting is still in progress. The recent tectonic activity has been investigated through a seismological survey and the study of neotectonic joints found in Lake Magadi sediments, which were deposited some 5000 years ago. The structural analysis of these open fractures was combined with a quantitative analysis of the orientation and size characteristics of imagery faults. The gathered data demonstrate (1) that the majority of the systematic joints have straight and parallel trajectories with a common en echelon mode of propagation displayed through a rich variety of patterns, and (2) that there is a self-similarity in fault and joint principal directions recognised at the different telescopic scales. SPOT image (1:125,000), aerial photos (1:76,000), and outcrop fieldwork reveal two important structural orientations which are N015°E and N015°W. The N015°E regional direction is consistent with the orientation of the southern segment of the Kenya Rift. Structural analysis is supported by results of a joint microseismic investigation in the Lake Magadi area. Obtained focal mechanism solutions indicate an E–W to ESE–WNW normal faulting extension direction.     

Diffusion and mobility of electrically conducting defects in olivine

 Electrical conductivity of lherzolite (65% olivine), measured as a function of time after changes in the oxygen fugacity (f _o2) of the surrounding CO₂/CO atmosphere, is used to infer the diffusivity of the point defects responsible for conduction in olivine. A total of 63 equilibration runs at temperatures of 900, 1000, 1100, and 1200 ^∘C were fit using nonlinear parameter estimation to recover time constants (directly related to diffusivity) and conductivity steps. An observed f _o2 dependence in the time constants associated with re-equilibration implies two defect species of fixed diffusivity but with f _o2-dependent concentrations. Although the rate-limiting step may not necessarily be associated with a conducting defect, when time constants are converted to diffusivities, the magnitudes and activation energies agree extremely well with the model for magnesium vacancies (the slower species) and small polarons (holes localized on Fe³⁺) derived by Constable and Roberts (1997). This earlier study used an independent method of simultaneous modeling of thermopower and electrical conductivity as a function of f _o2 and temperature, on data from a different type of sample (a dunite). We observe that at high f _o2 where polarons dominate over magnesium vacancies in the defect population, re-equilibration is dominated by magnesium vacancy diffusion, and vice versa (at low f _o2 magnesium vacancies dominate and re-equilibration proceeds at the faster rate associated with polaron mobility). We interpret this to suggest association between the cation vacancies and polarons, as has been suggested by Tsai and Dieckmann (1997), making the concentration of the minority defect the rate-limiting step in the oxidation/reduction reactions. Received: 18 October 2000 / Accepted: 7 May 2002     

A wind-driven model of the ocean surface layer with wave radiation physics

Ocean Dynamics - Surface windstress transfers energy to the surface mixed layer of the ocean, and this energy partly radiates as internal gravity waves with near-inertial frequencies into the...     

On the role of diffractions in velocity model building: a full-waveform inversion example

Studia Geophysica et Geodaetica - Imaging of small-scale heterogeneities is important for the geological exploration in complex environments. It requires a processing sequence tuned to...     

Decadal morphological evolution of the mouth zone of the Yangtze Estuary in response to human interventions

The morphology of the Yangtze Estuary has changed substantially at decadal time scales in response to natural processes, local human interference and reduced sediment supply. Due to its high sediment load, the morphodynamic response time of the estuary is short, providing a valuable semi-natural system to evaluate large-scale estuarine morphodynamic responses to interference. Previous studies primarily addressed local morphologic changes within the estuary, but since an overall sediment balance is missing, it remains unclear whether the estuary as a whole has shifted from sedimentation to erosion in response to reduced riverine sediment supply (e.g. resulting from construction of the Three Gorges Dam). In this paper we examine the morphological changes of two large shoals in the mouth zone (i.e. the Hengsha flat and the Jiuduan shoal) using bathymetric data collected between 1953 and 2016 and a series of satellite images. We observe that the two shoals accreted at different rates before 2010 but reverted to erosion thereafter. Human activities such as dredging and dumping contribute to erosion, masking the impacts of sediment source reduction. The effects of local human intervention (such as the construction of a navigation channel) are instantaneous and are likely to have already resulted in new dynamic equilibrium conditions. The morphodynamic response time of the mouth zone to riverine sediment decrease is further suggested to be >30 years (starting from the mid-1980s). Accounting for the different adaptation time scales of various human activities is essential when interpreting morphodynamic changes in large-scale estuaries and deltas. © 2019 John Wiley & Sons, Ltd.     

Localizing and quantifying groundwater-surface water interactions at different scales: A tracer approach at the River Moselle,Germany

Groundwater-surface water interactions (GSI) connect rivers and streams with riparian areas and the adjacent aquifer. Although these interactions exert a substantial control of quantity and quality of both groundwater and surface water, knowledge on GSI along rivers at the regional scale, particularly for inland waterways, is still limited. We investigated GSI along the river Moselle, an important federal inland waterway in Germany, by using radon and tritium to identify gaining (water flux from the aquifer to the surface water) and losing (water flux from the surface water to the aquifer) stream conditions, respectively. Gaining stream conditions were identified by continuously measuring radon along the river during boat surveys with a high spatial resolution (every 2 km) during intermediate (October 2020) and near low flow conditions (August/September 2021). The tritium concentrations in surface water and groundwater and the resulting tritium inventories were used to characterize losing stream conditions Monthly tritium inventories from 2017 to 2022 revealed a mean loss for the whole period of 20.3 % and a mean gain of 21.8%. Both were probably triggered by a combination of losing stream conditions and flood-induced mass transfer of water from the aquifer back into the river as well as discharge fluctuations. At the investigated site Lehmen there were direct indications of an influence of surface water due to elevated tritium concentrations in the groundwater (up to 13.3 Bq L⁻¹). Using radon mass balance modelling, good agreements of simulated versus measured radon data with respect to two groundwater end-member scenarios were obtained during intermediate flow (Spearman's ρ: 0.97 and 0.99; MAE: 10.1 and 3.4 Bq L⁻¹) and near low flow (Spearman's ρ: 0.97 and 0.99; MAE: 11 and 6.5 Bq L⁻¹). Considerable groundwater inflow was limited to the meander of Detzem, where cumulated groundwater inflow of about 19 m³ s⁻¹ (9.5% of total discharge) and 4.2 m³ s⁻¹ (3.8% of total discharge) was simulated during intermediate and near low flow, respectively. However, the groundwater inflow was relatively low compared to alpine streams, for example. The study will help to better identify and quantify GSI at the regional scale and provide methodological guidance for future studies focusing on inland waterways.     

Analytical 3D views and virtual globes — scientific results in a familiar spatial context

In this paper we introduce analytical three-dimensional (3D) views as a means for effective and comprehensible information delivery, using virtual globes and the third dimension as an additional information carrier. Four case studies are presented, in which information extraction results from very high spatial resolution (VHSR) satellite images were conditioned and aggregated or disaggregated to regular spatial units. The case studies were embedded in the context of: (1) urban life quality assessment (Salzburg/Austria); (2) post-disaster assessment (Harare/Zimbabwe); (3) emergency response (Lukole/Tanzania); and (4) contingency planning (faked crisis scenario/Germany). The results are made available in different virtual globe environments, using the implemented contextual data (such as satellite imagery, aerial photographs, and auxiliary geodata) as valuable additional context information. Both day-to-day users and high-level decision makers are addressees of this tailored information product. The degree of abstraction required for understanding a complex analytical content is balanced with the ease and appeal by which the context is conveyed.     

Asteroid impact in the Black Sea. Death by drowning or asphyxiation?

Normally the consequences of an impact of an asteroid in a water body are discussed in terms of the beach run up of impact-generated waves. If even a small asteroid would hit the Black Sea, however, the potential emissions of toxic and flammable gases could be more disastrous to the region (comprised of Romania, Ukraine, Russia, Georgia, Turkey and Bulgaria) than the tsunami caused by the impact.     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: I. An introduction to the project

We investigated paleolimnological records from a series of river deltas around the northeastern rim of Lake Tanganyika, East Africa (Tanzania and Burundi) in order to understand the history of anthropogenic activity in the lakes catchment over the last several centuries, and to determine the impact of these activities on the biodiversity of littoral and sublittoral lake communities. Sediment pollution caused by increased rates of soil erosion in deforested watersheds has caused significant changes in aquatic communities along much of the lakes shoreline. We analyzed the effects of sediment discharge on biodiversity around six deltas or delta complexes on the east coast of Lake Tanganyika: the Lubulungu River delta, Kabesi River delta, Nyasanga/Kahama River deltas, and Mwamgongo River delta in Tanzania; and the Nyamuseni River delta and Karonge/Kirasa River deltas in Burundi. Collectively, these deltas and their associated rivers were chosen to represent a spectrum of drainage-basin sizes and disturbance levels. By comparing deltas that are similar in watershed attributes (other than disturbance levels), our goal was to explore a series of historical experiments at the watershed scale, with which we could more clearly evaluate hypotheses of land use or other effects on nearshore ecosystems. Here we discuss these deltas, their geologic and physiographic characteristics, and the field procedures used for coring and sampling the deltas, and various indicators of anthropogenic impact.