Rb/Sr dating of the Upper Proterozoic basement of Zambesia,Mozambique

The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.

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Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.

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Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.

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Velocity fields associated with the magnetic component of solar faculae

The StokesV asymmetries observed in solar faculae can be interpreted by invoking the presence of magnetic and velocity fields variations along the line-of-sight. By means of a perturbative approach, we develop the theoretical dependence on magnetic and velocity fields of the StokesV profile around its zero-crossing point. We find that the empirical curves of growth for theV zero-crossing point and the slope, as well as the curve of growth for the integral (previously derived by Sánchez Almeidaet al., 1989, through the same approach), are reproduced quite well with a single atmosphere which assumes such simultaneous variations.The depth dependence of the fields that give the best fit in our model presents several striking properties which cannot be released without totally compromising the goodness of the fit. Namely, the magnetic field strength increases towards the observer while the downflowing velocity field decreases. Both variations must occur co-spatially, in the same atmospheric layers. This fact seems to contradict theoretical models for the fanning out parts of magnetic concentrations which foresee a sharp separation between a static magnetic layer and a deep zone with velocity fields. We discuss a possible solution of such contradiction in terms of a finite optical thickness of the boundary layer between zones with and without magnetic field in faculae.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

A new model for X-ray emission from NGC 4151

We present an analysis of the reported spectral features of NGC 4151 in X-rays. It is shown that the origin of X-rays from the source is inconsistent with a single production mechanism. We suggest a new two-component model in which soft X-rays arise from the black-body emission of a tiny hot nucleus withT2×10⁷ K and the hard X-ray photons are generated in an extended region by inverse Compton scattering of electrons with the infrared photons.     

The chemistry of orthophosphate uptake from seawater on to calcite and aragonite

The chemistry of orthophosphate uptake from synthetic seawater onto the surfaces of synthetic calcite, aragonite and low-magnesium biogenic calcite has been studied, in order to elucidate the kinetics of the process (generally believed to be the major control of dissolved reactive phosphate in carbonate-rich marine sediments). Our results differ from those obtained by others, who have studied orthophosphate uptake in low ionic strength solutions and at much higher supersaturations relative to apatite.In both ‘free drift’ and chemostat experiments, Mg and F have only a minor effect on the reaction rate. Even at constant solution composition the rate of orthophosphate uptake was found to decrease by 10⁶ over a two week period. The data from the ‘free drift’ experiments can be fitted to the Elovich equation. This indicates that the kinetics observed for this reaction can be explained by an exponential decrease in available surface reaction sites and/or a linear increase in the activation energy associated with chemisorption as the reaction proceeds.     

The appearance of Mars from 1907 to 1971: Graphic synthesis of photographs from the I.A.U. center at Meudon

Using selected high quality plates collected at the I.A.U. Planetary Data Center in Meudon (Paris), the author has drawn 32 Mercator charts of the planet Mars for every opposition from 1907 to 1971. This graphic synthesis of albedo distribution may be used in the study of major surface changes over the years.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

Comparative study of sampling methods and in situ and laboratory analysis for shallow-water submarine hydrothermal systems

A primary aim for sampling of submarine hydrothermal vents is to minimize inclusion of ambient seawater. Here, we compare the results of three different sampling methods (air displacement, two-valve bottle, and syringes) for shallow submarine systems. Mixing of hydrothermal fluid with seawater is unavoidable; however, calculations based on linear mixing models allow estimation of the hydrothermal fluid end-member composition. The results show that sampling with a two-valve bottle and syringes are the best options because they allow collection of samples with a large proportion of hydrothermal fluid. Additionally, we compare the results of in situ and laboratory analyses of the fluid samples, and demonstrate that determination of chemical composition in situ is the best option for some components, as re-equilibration affects some component concentrations (i.e. bicarbonate). Conversely, silica determination in situ usually underestimates the concentration in the fluid, as it does not account for polymeric silica. Other components can be measured either in the field or in the laboratory.     

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.