Evaluation of heavy metal bio-availability from Almagrera pyrite-rich tailings dam (Iberian Pyrite Belt,SW Spain) based on a sequential extraction procedure

The beginning of polymetallic sulphide ore exploitation at Almagrera, Iberian Pyrite Belt, SW Spain, has been dated back to pre-Roman times; mining activity lasted until 2001 when it was definitely halted. The Almagrera sulphide tailings dam was built at the Sotiel–Coronada mine, where Cu, Zn and Pb concentrates were obtained by flotation processes, and sulphide (mainly pyrite) wastes formed. The dam was built as a water-reservoir, on a tectonic fault; its hazard is currently documented by the released wastes after a strong storm in the region, then, its stability is not monitored by the owner.     

Astronomical frequencies for climate research at the decadal to century time scale

Short-term variations of the elements representing the Earth's motion around the Sun and its rotation have been analyzed over the last 6000 years using 1-year steps. Their low-frequency part is compared first to the values obtained from a secular theory of the planetary long-term motion showing that they can be considered reliable enough to represent adequately the motion of the Earth over the last 5000 years. Spectral analysis of these values shows that the main periodicities are 2.67, 3.98, 5.26, 5.93, 7.9, 9.8, 11.9, 14.7, 15.8, 29, 42, 61, 122, 165 and 250 years for the eccentricity as well as for the climatic precession, with an additional component at around 930 years for the eccentricity and around 840 years for the climatic precession. Periodicities at 2.67, 3.8, 5.9, 8.0, 9.3, 11.9, 14.7, 18.6, 29, 135, 250 and 840 yr are also shown for the obliquity. Spectral analyses of the daily July mid-month insolation at 65°N show essentially the same periodicities as the climatic precession and the obliquity, i.e. 2.67, 3.98, 5.92, 8.1, 11.9, 15.7, 18.6, 29, 40, 61 and around 900 years. Finally a wider analysis of the insolation pattern was performed related to the large periodicity band of the insolation time series for the solstices and the equinoxes for 7 different latitudes. In equatorial latitudes the insolation variance is largely explained by precession. But precession dominates everywhere with the obliquity signal being stronger at polar latitudes at the solstices. The amplitudes of the insolation change at these frequencies is of the order of 0.2 Wm^–2 at the maximum. Offprint requests to: A Berger     

Stress fields in the Iberian-Maghrebi region

This study concerns the present stressfield between the Eurasian and Africanplates in the Iberian-Maghrebi region(Portugal, Spain, Morocco, Algeria andTunisia). In addition to an up-to-datecatalogue of earthquakes in this area, acatalogue of the focal mechanisms composedof 486 solutions of fault planes,standardized in terms of notation andinformation type, was used. These data wereused applying the right-dihedron method ofAngelier and Mechler (1977), to obtaindifferent zones with homogeneous stress.The results obtained for shallowearthquakes (h < 30 km) coincide, in themajority of cases, with the general stressfields proposed by numerous authors forthis region, according to which there isNW-SE compression. However, the stressorientation appears to vary in certainareas, perhaps perturbed by the opening ofthe Atlantic Ocean, the approach of Iberiaand Africa, or the extension of the AlboranSea.For the intermediate earthquakes (30 < h< 150 km) no general pattern was found,and the P and T axes seem to be randomlyoriented for the depth intervalsconsidered. For the very deep earthquakes(h > 600 km), however, the P axis lies ina NNW-SSE direction, dipping towards theSSE, while the T axis is subhorizontal in aNE-SW direction.The determinations from the focalmechanisms highlight the existence of aregional stress field with a subhorizontalcompression axis trending NW-SE. Superimposed are others that specificallyaffect particular sectors; these arerelated to the opening of the AtlanticOcean, the extension of the BeticCordillera and the Alboran Sea, and eventhe present compression between the Iberianand European plates.     

Potassium Doppler-resonance lidar for the study of the mesosphere and lower thermosphere at the Arecibo Observatory

We have developed a lidar to study the temperature structure of the nighttime mesopause region over the Arecibo Observatory (18.35°N, 66.75°W) by measuring the lineshape of the fluorescence spectrum of atomic potassium that is deposited in the mesosphere and lower thermosphere (MLT) by meteors. To demonstrate how the potassium lidar can enhance MLT studies at Arecibo, we show recent results for: (1) comparisons with airglow temperature measurements; (2) simultaneous operations with stratospheric and mesospheric temperature profiling by Rayleigh lidar; (3) simultaneous observations of K, Ca⁺, and E-region electron density profiles; and (4) occurrences of sporadic K layers, and relationships to sporadic E layers.     

Large-Scale Temperature Changes across the Southern Andes: 20th-Century Variations in the Context of the Past 400 Years

Long-term trends of temperature variations across the southern Andes (37–55° S) are examined using a combination of instrumental and tree-ring records. A critical appraisal of surface air temperature from station records is presented for southern South America during the 20th century. For the interval 1930–1990, three major patterns in temperature trends are identified. Stations along the Pacific coast between 37 and 43° S are characterized by negative trends in mean annual temperature with a marked cooling period from 1950 to the mid-1970s. A clear warming trend is observed in the southern stations (south of 46°S), which intensifies at higher latitudes. No temperature trends are detected for the stations on the Atlantic coast north of 45° S. In contrast to higher latitudes in the Northern Hemisphere where annual changes in temperature are dominated by winter trends, both positive and negative trends in southern South America are due to mostly changes in summer (December to February) temperatures. Changes in the Pacific Decadal Oscillation (PDO) around 1976 are felt in summer temperatures at most stations in the Pacific domain, starting a period with increased temperature across the southern Andes and at higher latitudes.Tree-ring records from upper-treeline were used to reconstruct past temperature fluctuations for the two dominant patterns over the southern Andes. These reconstructions extend back to 1640 and are based on composite tree-ring chronologies that were processed to retain as much low-frequency variance as possible. The resulting reconstructions for the northern and southern sectors of the southern Andes explain 55% and 45% ofthe temperature variance over the interval 1930–1989, respectively. Cross-spectral analysis of actual and reconstructed temperatures over the common interval 1930–1989, indicates that most of the explained varianceis at periods >10 years in length. At periods >15 years, the squaredcoherency between actual and reconstructed temperatures ranges between 0.6 and 0.95 for both reconstructions. Consequently, these reconstructions are especially useful for studying multi-decennial temperature variations in the South American sector of the Southern Hemisphere over the past 360 years. As a result, it is possible to show that the temperatures during the 20thcentury have been anomalously warm across the southern Andes. The mean annual temperatures for the northern and southern sectors during the interval 1900–1990 are 0.53 °C and 0.86 °C above the1640–1899 means, respectively. These findings placed the current warming in a longer historical perspective, and add new support for the existence of unprecedented 20th century warming over much of the globe. The rate of temperature increase from 1850 to 1920 was the highest over the past 360 years, a common feature observed in several proxy records from higher latitudes in the Northern Hemisphere.Local temperature regimes are affected by changes in planetary circulation, with in turn are linked to global sea surface temperature (SST) anomalies. Therefore, we explored how temperature variations in the southern Andes since 1856 are related to large-scale SSTs on the South Pacific and South Atlantic Oceans. Spatial correlation patterns between the reconstructions and SSTs show that temperature variations in the northern sector of the southern Andes are strongly connected with SST anomalies in the tropical and subtropical Pacific. This spatial correlation pattern resembles the spatial signature of the PDO mode of SST variability over the South Pacific and is connected with the Pacific-South American (PSA) atmospheric pattern in the Southern Hemisphere. In contrast, temperature variations in the southern sector of the southern Andes are significantly correlated with SST anomalies over most of the South Atlantic, and in less degree, over the subtropical Pacific. This spatial correlation field regressed against SST resembles the `Global Warming' mode of SST variability, which in turn, is linked to the leading mode of circulation in the Southern Hemisphere. Certainly, part of the temperature signal present in the reconstructions can be expressed as a linear combination of four orthogonal modes of SST variability. Rotated empirical orthogonal function analysis, performed on SST across the South Pacific and South Atlantic Oceans, indicate that four discrete modes of SST variability explain a third, approximately, of total variance in temperature fluctuations across the southern Andes.     

A New Methodology for Decreasing Uncertainties in the Seismic Hazard Assessment Results by Using Sensitivity Analysis. An Application to Sites in Eastern Spain

v--vIn this study a sensitivity analysis has been carried out by means of the seismic hazard results obtained using the non-zoning methodology (Epstein and Lomnitz, 1966) and the extreme value distribution functions proposed by Gumbel (1958), via a logic tree procedure. The aim of the sensitivity analysis is to identify the input parameters that have the largest impact on assessed hazard and its uncertainty. The research findings from the study of these parameters can serve as a useful guide to facilitate further research studies on seismic hazard evaluations because it allows us to identify parameters that have little or no effect on the seismic hazard results as well as parameters that have great effects on them. In this way, using the obtained results, we have proposed objective criteria in assigning probabilities to the different logic tree branches in a more objective way. It should be noted that, although the sensitivity of the logic tree branches depends on the site, it does not always do so in the same way. Finally, re-evaluation of seismic hazard using the proposed methodology applied to eastern Spain leads to a reduction of uncertainty from 52% to 27% of the expected acceleration with 10% probability of exceedence, at the site with the highest value of seismic hazard (Site 1: Torrevieja).     

Oxygen and Hydrogen Isotopic Signatures of Large Atmospheric Ice Conglomerations

Specific studies about the stable isotope composition (¹⁸O/¹⁶O and D/H) of atmospheric icy conglomerations are still scarce. The present work offers, for the first time, a very detailed analysis of oxygen and hydrogen isotopic signatures of unusually large ice conglomerations, or “megacryometeors”, that fell to the ground in Spain during January 2000. The hydrochemical analysis is based on the bulk isotopic composition and systematic selective sampling (deuterium isotopic mapping) of eleven selected specimens. δ¹⁸O and δD (V-SMOW) of all samples fall into the Meteoric Water Line matching well with typical tropospheric values. The distribution of the samples on Craig's line suggests either a variation in condensation temperature and/or different residual fractions of water vapour (Rayleigh processes). Three of the largest megacryometeors exhibited unequivocally distinctive negative values (δ¹⁸O = −17.2%₀ and δD = −127 %₀ V-SMOW), (δ¹⁸O = −15.6%₀ and δD = −112%₀ V-SMOW) and (δ¹⁸O = −14.4%₀ and δD = −100%₀ V-SMOW), suggesting an atmospheric origin typical of the upper troposphere. Theoretical calculations indicate that the vertical trajectory of growth was lower than 3.2 km. During the period in which the fall of megacryometeors occurred, anomalous atmospheric conditions were observed to exist: a substantial lowering of the tropopause with a deep layer of saturated air below, ozone depression and strong wind shear. Moreover, these large ice conglomerations occurred during non-thunderstorm conditions, suggesting an alternative process of ice growth was responsible for their formation.     

Geochemical assessment of the contaminant potential of granite fines produced during sawing and related processes associated to the dimension stone industry

Granite fines are inorganic wastes produced in the elaboration of dimension stone. Because of the increasing development of that industry in NW Spain, some concerns related to their classification as type of waste and their environmental impact have been raised. We have performed a detailed physicochemical, mineralogical and geomechanical characterization of the fines and the results make up the basis of several modeling exercises addressed to give answers to particular topics: the impact of high pH waters on the environment and the mobility of some toxic metals. Based on our analyses, we conclude that granite fines do not constitute a significant hazard to the quality of natural waters.     

Preconsolidation stress in the Vega Baja and Media areas of the River Segura (SE Spain): Causes and relationship with piezometric level changes

Preconsolidation stress (σ′_p) is the maximum effective stress that a soil has suffered throughout its life. From a geotechnical point of view, preconsolidation stress has a great importance because it separates elastic and reversible deformations from inelastic and only partially irreversible deformations and marks the starting point of high compressibility. This study calculates the preconsolidation stress for 139 undisturbed soil samples from the Vega Baja and Media of the Segura river (SE Spain), using the uniaxial consolidation test and applying the method proposed by Casagrande while using a novel analytical procedure proposed by Gregory et al. [Gregory, A.S., Whalley, W.R., Watts, C.W., Bird, N.R.A., Hallet, P.D., Whitmore, A.P., 2006. Calculation of the compression index and precompression stress from soil compression test data. Soil and Till. Res., 89, 45–57] to avoid subjective interpretations of maximum curvature point. The results show overconsolidation ratio (OCR — the ratio of preconsolidation stress to current natural overburden stress) values for the 10–15 m depth of soil varying from 2 to 14 and maximum preconsolidation stresses above 800 kPa. The main causes of calculated preconsolidation identified are desiccation due to seasonal drying and wetting cycles that have induced additional stresses always lower than 42 kPa for the more superficial samples. Water level decline due to the reduction of recharge suffered by the aquifer system during periods of drought and the uncontrolled withdrawal of water is considered to be the second cause of anomalous OCR values. This second cause induces low stresses to the more superficial layers (lower than 41 kPa) that can reach values higher than 150 kPa for the deeper layers for known water level decreases. In consequence, the soils of the Vega Baja and Media of the Segura river are highly overconsolidated for the first 5 m, decreasing gradually with depth to 10–15 m deep. For samples located deeper than 15 m the soils seem to be underconsolidated, probably due to the existence of confined aquifers that cause deviations from a hydrostatic and linear pore pressure model. This fact has a huge practical significance which implies that deformations affecting superficial layers are lower than those expected for deeper layers for the same load.