甲醛还原Pt/TiO2催化剂用于温和条件下高效催化氧化甲醛（英文）

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.     

REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.     

采用泵喷补偿技术的近底拖体水压场数值模拟研究

采用标准 k-ε 模型,结合 Fluent 软件,对采用泵喷补偿技术的拖体水下被拖行运动所产生的压力场变化进行了数值模拟实验。结果表明：采用泵喷补偿技术对拖体水压场的“马鞍形”分布特性影响较小, 但随着喷水速度的增加,拖体首端压力负值略有增加,而中段的负峰幅值显著增加,当喷水速度达到一定值后,拖体的压力特性曲线已经较为接近期望值,证明泵喷补偿技术具有一定的可行性。     

可解释性长短期记忆模型用于预测湖泊总磷浓度变化

对湖泊总磷的变化预测和来源识别对水资源调度和流域生态治理有着重要的意义,然而复杂的生化反应和水动力条件导致的非平稳性给湖泊总磷浓度的准确预测带来极大的困难。为克服这一挑战,本文引入了基于加权回归的季节趋势分解(seasonal and trend decomposition using Loess,STL)技术和夏普利加法(SHapley additive exPlanations,SHAP)结合长短期记忆网络(long short-term memory neural network,LSTM)和门控循环单元(gated recurrent unit,GRU)构建了一个可解释的预测框架,以增强对湖泊总磷浓度演变的预测并提高其可解释性。研究表明:(1)在骆马湖总磷浓度的预测中,该框架拥有较好的预报精度(R²=0.878),优于LSTM和卷积长短期记忆模型(convolutional neural networks and long short term memory network,CNN-LSTM)。当预测时间步长增加到8 h时,该框架有效提高了总磷浓度的预测精度,平均相对误差和均方根误差分别降低了47.1%和33.3%。从预测趋势来看,骆马湖在汛期的总磷平均浓度为0.158 mg/L,相较于非汛期的平均浓度,增加了202.1%。(2)运河来水是骆马湖总磷浓度最重要的影响因素,贡献权重为60.0%,并且不同断面(三湾、三场)的污染源受水动力、气象等因素的影响存在显著的时空差异。本文凸显了神经网络模型在预警水体污染方面的可实施性,并且为提高传统神经网络的学习能力和可解释性的开发与验证提供了重要方向。     

葛洲坝至胭脂坝长江干流段江豚活动规律

长江江豚是我国一级保护野生动物,也是长江生态系统的指示性物种,其种群数量恢复情况及活动规律一直备受关注。本文选择长江宜昌段江豚活动频繁的葛洲坝下游至胭脂坝江段为研究区域,于2021年6月-2022年5月采用定点目测、水上流动监测与无人机监测相结合的方法分区监测长江江豚的游泳行为,分析长江江豚的活动规律,构建了长江江豚出水头次的零膨胀泊松回归模型,识别影响长江江豚出水头次的关键因素,建立长江江豚出水头次与各因素间的相关关系。结果表明:(1)葛洲坝至胭脂坝长江干流段监测到最大江豚出水头次为19头次,长江江豚集群规模以2~3头最为常见,占比达58.1%;长江江豚主要表现出4种行为特征,各行为占比从大到小依次为:玩耍＞休息＞摄食＞抚幼。(2)长江江豚在葛洲坝下游近坝区(A区,葛洲坝至至喜长江大桥)出水头次最多,且在秋冬季节累计出水头次多于春夏季节,冬季累计出水头次最高,达252头次。(3)长江江豚出水头次与电站下泄流量呈显著负相关;浊度增大,长江江豚出水的概率减小。本文研究结果对长江江豚生态保护策略及长江十年禁渔效果评估具有重要参考价值。     

Seasonal change of ice algal and phytoplankton assemblages in the Nella Fjord near Zhongshan Station, East Antarctica

The ice algal and phytoplankton assemblages were studied from Nella Fjord near Zhongshan Station, East Antarctica from April 12 to December 30, 1992. Algal blooms occurred about 3 cm thick on the bottom of sea ice in late April and mid November to early December respectively, and a phytoplankton bloom appeared in the underlying surface water in mid December following the spring ice algal bloom. The biomass in ice bottom was 1 to 3 orders of magnitude higher than that of surface water. Amphiprora kjellmanii, Berkeleya sp., Navicula glaciei, Nitzschia barkelyi, N. cylindrus /N. curta, N. lecointei and Nitzschia sp. were common in the sea ice temporarily or throughout the study period. The biomass in a certain ice segment was decreased gradually and the dominant species were usually succeeded as the season went on. Nitzschia sublineata and Dactyliosolen antarctica were two seasonal dominant species only observed in underlying water column. The assemblages between bottom of ice and underlying surface water were different except when spring ice algae bloomed. The evidence shows that the ice algal blooms occurred mainly by in situ growth of ice algae, and the phytoplankton bloom was mostly caused by the release of ice algae.     

Softs of Fildes Peninsula, King George Island, the maritime Antarctic: Part I. Formation processes and pedogenetic particularities

Based on the data obtained from tens of the investigated soil profiles scattered over the Fildes Peninsula, King George Island, the maritime Antarctic, the soil-forming processes were discussed. It was concluded that on the weathering crusts resulted from various physical courses, the strong freeze-thaw action within regolith, significant organic matter accumulation, evident leaching and illuviation, as well as initial argillification dominated the formation and development of the soils on the Fildes Peninsula. Furthermore, this study indicated that the juvenility of genesis, poor profile-expression, variation in column thickness, etc. characterized the pedogenetic features of the soils of the Fildes Peninsula.     

Reconstruction of palaeosalinity using carbon isotopes and benthic associations: a comparison

Carbon and oxygen isotopes were determined on 40 recrystallized shells of Late Jurassic bivalves from the Lusitanian Basin of Portugal. In contrast with the oxygen isotopes, which exhibited considerable diagenetic distortion, the carbon isotopes are thought to preserve a record of the salinity of the Jurassic marginal marine seas in which these bivalves lived. The reconstructed palaeosalinities range from 35%o (euhaline) to 5% (oligohaline). Comparing these values with the palaeosalinity reconstructed from a palaeoecological analysis of 17 stratigraphic levels within the basin, the independently derived values agree in most cases. Strongly differing values are explained as being due to biotic factors and to diagenetic distortion of the isotopic signal; they are less likely to be due to smallscale time-averaging or insufficient microstratigraphic sampling. On the whole, the carbon isotope analyses are thought to produce reasonable palaeosalinity values, although data from infaunal, originally aragonitic bivalves appear to be less reliable than those from epifaunal bivalves with a predominantly or exclusively calcitic shell. As diagenetic alteration of the carbon isotope signal is, however, unpredictable and biotic effects on the isotopic composition are insufficiently known, palaeosalinity reconstructions based on stable isotope data should be supported by palaeoecological data.     

Analysis of mutations in the p53 tumor suppressor gene and Ki- and Ha-ras proto-oncogenes in hepatic tumors of European flounder (Platichthys flesus).

DNA from five tumors, three other-injured livers and two normal liver tissue samples from the European flounder were analyzed for mutations in exons 5-8 of the tumor suppressor gene p53 and at codons 12, 13 and 61 of Ha- and Ki-ras proto-oncogenes. No tumor-specific mutations were identified by direct sequencing and single-strand conformation polymorphism of these genes. A number of silent polymorphisms were noted in p53. In addition to a need for more extensive analyses of flounder liver tumor samples for ras or p53 mutations, other cancer-related genes should be investigated.