Internally consistent gahnitic spinel-cordierite-garnet equilibria in the FMASHZn system: geothermobarometry and applications

The equilibrium (Mg, Fe, Zn)₃Al₂Si₃O₁₂+2Al₂SiO₅=3(Mg, Fe, Zn)Al₂O₄+5SiO₂ garnet + sillimanite/kyanitc = spinel + quartz was calibrated in the piston-cylinder apparatus between 11 and 30 kbar, and over the temperature range of 950 to 1200°C. Three experimental mixes of Mg no. [100^*MgO/(MgO+FeO)] 40, 47 and 60, in the FeO –MgO–Al₂O₃–SiO₂–ZnO (FMASZn) system were used under low oxygen fugacities and anhydrous conditions. We derive a ternary Fe–Mg–Zn symmetric mixing model for aluminous spinels in equilibrium with garnet, to quantify the increase in gahnitic end-member of spinel with increasing pressure and descreasing temperature. Further experiments in the spinel-cordieritequartz-sillimanite field were combined with garnet-cordierite data from the literature to produce a consistent set of equations describing the exchange reactions in FMASHZn relevant to quartz-sillimanite bearing rocks at granulite facies conditions. As spinel is an important mineral participating in many rocks of aluminous composition at granulite-facies conditions, and as zinc contributes to an enlargement of spinel's stability field towards higher pressures and lower temperatures, the thermobarometric calibrations presented here will be most significant in delineating the prograde and retrograde trajectory of P-T paths.     

On the causes of landslides: Human activities,perception, and natural processes

Conceptual equations are presented for the net benefits, total risk, and total vulnerability associated with hazard zone occupation. It is shown that, as they are polycausal phenomena, landslides require a more sophisticated approach to this form of analysis than that employed for most other forms of hazard.Three examples of landsliding are examined. At Cuyocuyo, in the Peruvian Cordillera Oriental, slope instability is virtually inevitable, but human intervention may be disturbing some very fragile natural equilibria. At Calciano, in southern Italy, deforestation has resulted in a mudflow disaster, although man-made factors are not the only causes at work. Finally, in the Valle dell'Orco (also in southern Italy) demographic and agrarian change have aided the partial metamorphosis of the catchment into a large-scale mudflow complex (although the longer-term causes are natural, tectonic ones). These examples illustrate parts of the continuum that extends from dominant natural to dominant anthropogenic causes.Human intervention has played a key role in stimulating the natural antecedents of landslides occurring in the study areas. It is concluded that risk perception has not been wide enough to promote adequate risk mitigation, in part because of a failure properly to conceive of landslides as polycausal phenomena, in which man-made causes effectively cannot—and should not—be separated from natural ones.     

An estimate of late Pleistocene geomagnetic intensity variation from Sulu Sea sediments

Sediments from Site 769 of the Ocean Drilling Program's Leg 124 provide a record of geomagnetic intensity variation over the past 110 ky. Using continous shipboard measurements exclusively, I estimate the variation in the geomagnetic field strength by employing low-field magnetic susceptibility as a normalization parameter for the measured remanence intensity. By calibrating the resultant relative paleointensity record against previously available Holocene age estimates of absolute paleointensity, I derive an estimate of virtual dipole moment since 110 ka. The record obtained from these Sulu Sea sediments is strikingly like that previously obtained from sediments of a similar age in the Mediterranean Basin with distinct intervals of low intensity near 15, 20, 40 and 65–70 ka. The Sulu sediments also indicate a low-intensity feature near 108 ka. Important differences in paleointensity estimates obtained from these different regions for the interval between 30 and 20 ka suggest that a relatively large non-dipolar component of the geomagnetic field might have been present at that time.     

An assessment of the effect of chemical scavenging within submarine hydrothermal plumes upon ocean geochemistry

Profiles of ²¹⁰Pb over the Endeavour and North Cleft Segments of the Juan de Fuca Ridge are used to model a time scale for the scavenging, by hydrothermal plumes, of reactive elements in seawater. The hydrothermal plumes above these ridge segments are sites of intense scavenging removal of ²¹⁰Pb. At Endeavour, the total ²¹⁰Pb activities within the plume are as low as 8 dpm/100 l and dissolved activities are as low as 3 dpm/100 l. At the North Cleft, which is characterized by higher particulate Fe concentrations, the total ²¹⁰Pb activities are 4.5 dpm/100 l, the dissolved activities are 1–2 dpm/100 l and the ²¹⁰Pb activities are deficient with respect to the activity of the ²¹⁰Po daughter. These are perhaps the lowest ²¹⁰Pb activities ever measured in the deep sea. The large gradient of ²¹⁰Pb between the plume and surrounding deep water suggests that scavenging is focused into the plumes through horizontal transport. The implication, therefore, is that this process might impact the ocean on a scale larger than that local to the ridge crest. By coupling published measurements of particle flux from Endeavour with ²¹⁰Pb activities on particles trapped at that site, the total volume of seawater stripped of ²¹⁰Pb per year for that site was calculated to be 7.4 × 10¹² l/y. Globally, the extrapolated volume flux of seawater stripped of reactive constituents is 5.7 × 10¹⁵ l/y, such that the entire ocean is processed in this manner in 2.4×10⁵ y. The geochemical cycle of elements with ocean residence times much shorter than this (e.g., Pb and Th) will not be greatly affected by hydrothermal scavenging. On the other hand, this process holds significance for the geochemistry of other elements scavenged by hydrothermal plumes, such as P and V, whose ocean residence times are > 10⁴ y.