The chemistry of interstellar CH: The contribution of Bates and Spitzer (1951)

We review the present understanding of interstellar CH⁺. We show that the essential chemistry was correctly identified by Bates and Spitzer in 1951. More recent work has been concerned with defining appropriate venues within which this chemistry can function efficiently. This process had led to a much fuller understanding of the nature of the interstellar medium.     

Macroseepage of methane and light alkanes at the La Brea tar pits in Los Angeles

Geologic seepage of methane and light (C₂-C₅) alkanes was measured at the La Brea Tar Pits in Los Angeles. Samples were collected using flux chambers with stainless steel canisters and analyzed using gas chromatography. Average seepage rates from individual seepage sites were 970 ± 330 mg/h of methane, 14.0 ± 5.5 mg/h of ethane, 9.1 ± 3.7 mg/h of propane, 3.7 ± 1.6 mg/h of i-butane, 0.33 ± 0.16 mg/h of n-butane, 260 ± 120 μg/h of i-pentane, and 5.3 ± 1.9 μg/h of n-pentane, while maximum seepage rates exceeded 17 g/h of methane, 270 mg/h of ethane, 190 mg/h of propane, 95 mg/h of i-butane, 10 mg/h of n-butane, 7 mg/h of i-pentane, and 0.1 mg/h of n-pentane. These absolute fluxes have an additional unknown amount of error associated with them due to sampling methodology, and should be taken as the lower limit of emissions. Samples collected revealed generally dry gas, with high methane emissions relative to the light alkanes. Overall emissions from the tar pits were found to come not only from the active geologic seepage, but also from the outgassing of the standing asphalt at the site. Using the gas ratios, which are negligibly affected by errors introduced by sampling methodology, observed in this study, daily emissions of C₂ – C₅ alkanes from the La Brea area were estimated to be 4.7 ± 1.6 Mg, which represents 2–3 % of total emissions in the entire Los Angeles region.     

Sedimentary and faunal events revealed by a revised correlation of post‐glacial Hirnantian (Late Ordovician) strata in the Welsh Basin,UK

The discovery of a previously unrecognized unconformity and of new faunas in the type Llandovery area underpins a revised correlation of Hirnantian strata in mid Wales. This has revealed the sedimentary and faunal events which affected the Lower Palaeozoic Welsh Basin during the global rise in sea level that followed the end‐Ordovician glacial maximum and has allowed their interpretation in the context of local and global influences. In peri‐basinal shelfal settings the onset of post‐glacial deepening is recorded by an unfossiliferous, transgressive shoreface sequence (Cwm Clyd Sandstone and Garth House formations) which rests unconformably on Rawtheyan rocks, deformed during an episode of pre‐Hirnantian tectonism. In the deep water facies of the basin centre, this same sequence boundary is now recognized as the contact between fine‐grained, re‐sedimented mudstones and an underlying regressive sequence of turbidite sandstones and conglomerates; it is at a level lower than previously cited and calls into question the established lithostratigraphy. In younger Hirnantian strata, graptolites associated with the newly recognized Ystradwalter Member (Chwefri Formation) demonstrate that this distal shelf unit correlates with the persculptus graptolite‐bearing Mottled Mudstone Member of the basinal succession. Together these members record an important macrofaunal recolonization of the Welsh Basin and mark a key event in the post‐glacial transgression. Further deepening saw the establishment of a stratified water column and the imposition of anoxic bottom water conditions across the basin floor. These post‐glacial Hirnantian events are consistent with the re‐establishment of connections between a silled Welsh Basin and the open Iapetus Ocean. However, a comparison with other areas suggests that each event records a separate deepening episode within a pulsed glacio‐eustatic transgression, while also reflecting changes in post‐glacial climate and patterns of oceanic circulation and associated biotic flux. British Geological Survey © NERC 2009. All rights reserved.     

Micrometeorological Observations of a Microburst in Southern Finland

On the afternoon of 3 July 2004 in Hyytiälä (Juupajoki, Finland), convective cells produced a strong downburst causing forest damage. The SMEAR II field station, situated near the damage site, enabled a unique micrometeorological analysis of a microburst with differences above and inside the canopy. At the time of the event, a squall line associated with a cold front was crossing Hyytiälä with a reflectivity maximum in the middle of the squall line. A bow echo, rear-inflow notch, and probable mesovortex were observed in radar data. The bow echo moved west-north-west, and its apex travelled just north of Hyytiälä. The turbulence data were analysed at two locations above the forest canopy and at one location at sub-canopy. At 1412 EET (Eastern European Time, UTC+2), the horizontal and vertical wind speed increased and the wind veered, reflecting the arrival of a gust front. At the same time, the carbon dioxide concentration increased due to turbulent mixing, the temperature decreased due to cold air flow from aloft and aerosol particle concentration decreased due to rain scavenging. An increase in the number concentration of ultra-fine particles (< 10 nm) was detected, supporting the new particle formation either from cloud outflow or due to rain. Five minutes after the gust front (1417 EET), strong horizontal and downward vertical wind speed gusts occurred with maxima of 22 and 15 m s^?1, respectively, reflecting the microburst. The turbulence spectra before, during and after the event were consistent with traditional turbulence spectral theory.     

Timing and Extent of Late Quaternary Paleolakes in the Trans-Pecos Closed Basin, West Texas and South-Central New Mexico

The Trans-Pecos Closed Basin is a hydrographically closed region covering 20,000 km²centered on Salt Basin, 160 km east of El Paso, Texas. Geomorphic and limnetic evidence have been used to identify four major highstands for Lake King during the last glacial maximum (LGM). Additional geomorphic features from a second, recently identified, paleolake, Lake Sacramento, have been found in the Beargrass subbasin, a nested subbasin approximately 75 km northwest of Salt Basin. Radiocarbon ages of the organic material in Lake King sediments date four abrupt climate changes and rapid lacustrine transgressions during the LGM with a quasi-periodicity of 2000 yr. Geomorphic evidence in the Beargrass subbasin identifies lake cycles contemporaneous with those in Lake King. The dates for these transgressions correlate with the dates of freshening events identified by researchers in paleolake basins elsewhere in New Mexico. The quasi-periodicity of the events approximates that of Dansgaard–Oeschger events identified from Greenland ice cores. The contemporaneity of the Trans-Pecos transgressions with transgressive events in other basins in the region suggests that paleolakes in the region were in phase with respect to abrupt climate changes during the latter stages of the LGM.     

Local Agenda 21 and Barriers to Sustainability at the Local Government Level in Victoria,Australia

At the 1992 Rio 'Earth Summit', Australia joined other nations in committing to processes leading to the formulation of 'Local Agenda 21s' (LA21s) by 1996. Subsequently, in the latter year, Whittaker carried out a national survey of local government authorities to evaluate what progress had been made. Whittaker's conclusion was that progress in Australia had been slow, but ten 'leading-edge' Victorian councils were identified through a self-reporting process. In this paper we discuss the concept of LA21, analyse in closer detail the 'progress' that has been made in the ten Victorian councils, and discuss some of the broader forces that, we argue, have made LA21 formulation increasingly difficult, particularly in the state of Victoria in the recent past.     

A scenario of European climate change for the late twenty-first century: seasonal means and interannual variability

A scenario of European climate change for the late twenty-first century is described, using a high-resolution state-of-the-art model. A time-slice approach is used, whereby the atmospheric general circulation model, HadAM3P, was integrated for two periods, 1960–1990 and 2070–2100, using the SRES A2 scenario. For the first time an ensemble of such experiments was produced, along with appropriate statistical tests for assessing significance. The focus is on changes to the statistics of seasonal means, and includes analysis of both multi-year means and interannual variance. All four seasons are assessed, and anomalies are mapped for surface air temperature, precipitation and snow mass. Mechanisms are proposed where these are dominated by straightforward local processes. In winter, the largest warming occurs over eastern Europe, up to 7°C, mean snow mass is reduced by at least 80% except over Scandinavia, and precipitation increases over all but the southernmost parts of Europe. In summer, temperatures rise by 6–9°C south of about 50°N, and mean rainfall is substantially reduced over the same area. In spring and autumn, anomalies tend to be weaker, but often display patterns similar to the preceding season, reflecting the inertia of the land surface component of the climate system. Changes in interannual variance are substantial in the solsticial seasons for many regions (note that for precipitation, variance estimates are scaled by the square of the mean). In winter, interannual variability of near-surface air temperature is considerably reduced over much of Europe, and the relative variability of precipitation is reduced north of about 50°N. In summer, the (relative) interannual variance of both variables increases over much of the continent.     

Potential water sources for Late Quaternary Megalake Jilantai-Hetao,China, inferred from mollusk shell <Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr ratios

Lake Jilantai-Hetao, a megalake, was formed some time before 60–50 ka, along the Great North Bend of the Yellow River. The basin is now dry, with most of the area covered by aeolian sand. We are investigating this profound hydrologic change using a number of research approaches. Paleoshorelines of this megalake are best preserved in the Jilantai area in the southwestern portion of the megalake basin. We collected aquatic mollusk shells from littoral sediments at different altitudes around Jilantai and measured their strontium isotope compositions. ⁸⁷Sr/⁸⁶Sr ratios in shell carbonates are different between the high lake phase (~1,080–1,050 m altitude) and the low lake phase (~1,044–1,030 m altitude), with a small shift in average strontium ratios to more radiogenic values during the low lake phase. Based on regional hydrology and physical geography, we conclude that water from the Yellow River was the dominant water source supplying this megalake. ⁸⁷Sr/⁸⁶Sr ratios of modern water samples suggest the Yellow River was the dominant water source during the high lake phase, but that the relative contribution of Yellow River water to the megalake was reduced, and that the relative contributions of local precipitation and groundwater increased, during the low lake phase.