Geochemical characteristics of sphagnum brown coal — A possible oil-generating precursor

A preliminary study of newly discovered sphagnum brown coal from the Jingsuo Basin, Yunnan Province, China, which is quite rich in montan wax, indicates the predominance of highern-alkane homologues and aromatized triterpenoid components. Aromatic hydrocarbons are composed mainly of pentacyclic and tetracyclic di-, tri- and tetra-aromatic components, which are obviously diagenetically related to higher plant-derived triterpenoids naturally occurring in the biosphere. Because the sphagnum brown coal still remains in the highly immature stage, it seems that the progressive diagenetic aromatization of the higher plant-derived triterpenoids may start at a very early stage.     

Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise)

In western Vanoise (French Alps), karstic pockets of Triassic‐to‐Jurassic metabauxites embedded in carbonate rocks and containing several generations of metamorphic veins were studied. During blueschist facies metamorphism, a cumulative amount of ～13 vol% of water is inferred to have been produced locally by successive dehydration reactions, and part of this fluid remained in the bauxitic lenses during most of the metamorphic cycle. Field and geochemical evidence show that these rocks have been isolated from large‐scale fluid flow (closed‐system behaviour). It is proposed that the internally derived fluid has promoted the opening of fluid‐filled open spaces (as attested by the euhedral habits of vein minerals) and served as medium for mass transfer from rock to vein. Indeed, the vein infill is obviously the result of chemical interactions, at the millimetre‐to‐centimetre scale, between the rock minerals and the locally produced aqueous fluid. Two vein types can be distinguished based on mineralogical and textural features: (i) some veins are filled with newly formed products of either prograde (chloritoid) or retrograde (chlorite) metamorphic reactions; in this case, fluid‐filled open spaces seem to offer energetically favourable nucleation/growth sites; (ii) the second vein type is infilled with cookeite or pyrophyllite, that were present in the host rock prior to the vein formation. In this closed chemical system, the components for the vein infill minerals have been transferred from rock to vein through the fluid, in a dissolution–transport–precipitation process, possibly stress‐assisted. These different vein generations all contain Al‐rich mineral infills, suggesting that Al was a mobile element (cm scale) during metamorphism. In these HP rocks, fluid flow may have been restricted, and if so mass transfer occurred by diffusion in an almost stagnant fluid. Metamorphic veins can be seen as witnesses of fluid and mass redistribution that partly accommodate the rock deformation (lateral segregation).     

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Estimating climate changes in the northern hemisphere in the 21st century under alternative scenarios of anthropogenic forcing

Possible changes in the climate characteristics of the Northern Hemisphere in the 21st century are estimated using a climate model (developed at the Obukhov Institute of Atmospheric Physics (OIAP), Russian Academy of Sciences) under different scenarios of variations in the atmospheric contents of greenhouse gases and aerosols, including those formed at the OIAP on the basis of SRES emission scenarios (group I) and scenarios (group II) developed at the Moscow Power Engineering Institute (MPEI). Over the 21st century, the global annual mean warming at the surface amounts to 1.2?C2.6°C under scenarios I and 0.9?C1.2°C under scenarios II. For all scenarios II, starting from the 2060s, a decrease is observed in the rate of increase in the global mean annual near-surface air temperature. The spatial structures of variations in the mean annual near-surface air temperature in the 21st century, which have been obtained for both groups of scenarios (with smaller absolute values for scenarios II), are similar. Under scenarios I, within the extratropical latitudes, the mean annual surface air temperature increases by 3?C7°C in North America and by 3?C5°C in Eurasia in the 21st century. Under scenarios II, the near-surface air temperature increases by 2?C4°C in North America and by 2?C3°C in Eurasia. An increase in the total amount of precipitation by the end of the 21st century is noted for both groups of scenarios; the most significant increase in the precipitation rate is noted for the land of the Northern Hemisphere. By the late 21st century, the total area of the near-surface permafrost soils of the land of the Northern Hemisphere decreases to 3.9?C9.5 10⁶ km² for scenarios I and 9.7?C11.0 × 10⁶ km² for scenarios II. The decrease in the area of near-surface permafrost soils by 2091?C2100 (as compared to 2001?C2010) amounts to approximately 65% for scenarios I and 40% for scenarios II. By the end of the 21st century, in regions of eastern Siberia, in which near-surface permafrost soils are preserved, the characteristic depths of seasonal thawing amount to 0.5?C2.5 m for scenarios I and 1?C2 m for scenarios II. In western Siberia, the depth of seasonal thawing amounts to 1?C2 m under both scenarios I and II.     

Sea surface wind and Sea ice in the Barents Sea using microwave sensing data from Meteor-M N1 and GCOM-W1 satellites in January–March 2013

Application of satellite passive microwave sensing for the retrieval of key climatic parameters in the Barents Sea is considered. Fields of surface wind, atmosphere water vapor content and cloud liquid water content were found from MTVZA-GY radiometer onboard the Meteor-M N1 satellite and AMSR2 onboard the GCOM-W1 satellite with the use of original algorithms. The fields are in a good agreement with the ancillary remote and in situ measurements, which follows from the analysis of the evolution of the extra tropical and polar cyclones and cold air outbreaks with storm winds leading to intense air-sea interaction, and the formation and drift of sea ice.     

Land-derived pollutant hydrocarbons

Evidence is given for the derivation of oil pollution from on-shore sources and for a possible relation between its concentration in estuarine sediment and in the lipids of the sediment biomass.     

Petrological and geochemical characteristics of Plio-Pleistocene Volcanics from Ponza Island (Tyrrhenian Sea, Italy)

Summary Volcanic rocks on Ponza Island (Tyrrhenian Sea, central Italy) consist of Pliocene submarine rhyolites and Pleistocene subaerial trachyte and comendite lavas. Chemical variations and the homogeneous Sr and Nd isotopic signatures within the analyzed Pliocene rocks are ascribed to crystal fractionation. The absolute isotopic values, however, indicate the important role of a crustal component in the origin of these magmas. The very high-silica rocks were probably derived from a superimposed mechanism which may have been connected to the ascent of hydrothermal magmatic fluids. Compositional and ⁸⁷Sr/⁸⁶Sr variations at constant ¹⁴³Nd/¹⁴⁴Nd values in the Pleistocene rocks are likely due to fractionation of the observed phenocryst assemblage, possibly coupled with minor crustal interaction. These processes, however, cannot account for the extreme enrichment of many incompatible trace elements in the comendites. Some evidence suggests the influence of a halogen- and/or CO₂-rich volatile phase. Received February 17, 2000; revised version accepted November 29, 2000     

Magnetization properties of intrusive/extrusive rocks from East Maio (Republic of Cape Verde) and their geological implications

Summary. The remanent magnetization of intrusive/extrusive rocks of the 'basement' complex of East Maio constitutes four components that define two different axes of magnetization, at around dec. 328, inc. 12 and dec. 007, inc. 14 respectively. In general, two or more components co-exist in separate specimens or sites but both axes are present most frequently in the normal sense. The NNW-striking axis, the B-axis, fits very well with the Upper Cretaceous polar wander path for Africa. It is consequently inferred that the major phase of sheet intrusions in Maio dates from this time, probably from the interval 90–70 Myr bp. Comparisons of the directional dispersions in the folded and unfolded states suggest that this injection phase post-dates the uplift of the Central Igneous Complex of the island. The second axis of magnetization, the A -axis, agrees very well with late Teritary—Quaternary palaeomagnetic data for Africa and the Canary Islands. The A -axis is therefore regarded as of secondary origin, being the consequence of a thermal/ chemical overprint during the Miocene—Pliocene volcanism on the island. The occurrence of a 50–70 Myr long period of volcanic quiescence and erosion, between the termination of the early igneous activity (Upper Cretaceous) and the rejuvenated magmatism in Miocene/Pliocene time, is compatible with similar observations in the Canary Islands. In contrast to the palaeomagnetic conclusions, the K/Ar data only give ages around 10 Myr. The unusually young isotope dates are regarded as being due to an almost complete age resetting and are seen in conjuction with the overprinted magnetization. This explanation is further supported by the fact that K/Ar results of pillow lavas underlying Upper Jurassic limestones only give Tertiary ages.     

Effects of nonlinear model response on allocation of streamflow depletion: exemplified by the case of Beaver Creek,USA

Anomalies found when apportioning responsibility for streamflow depletion are examined. The anomalies arise when responsibility is assigned to the two states that contribute to depletion of Beaver Creek in the Republican River Basin in the United States. The apportioning procedure for this basin presumes that the sum of streamflow depletions, computed by comparing simulation model runs with and without groundwater pumping from individual states, approximates the streamflow depletion when both states are pumping. In the case study presented here, this presumed superposition fails dramatically. The stream drying and aquifer-storage depletion, as represented in the simulation model used for allocation, are examined in detail to understand the hydrologic and numerical basis for the severe nonlinear response. Users of apportioning procedures that rely on superposition should be aware of the presence and likely magnitude of nonlinear responses in modeling tools.     

Chromospheric evolution and the flare activity of super-active region NOAA 6555

Super-active region NOAA 6555 was highly flare productive during the period March 21st–27th, 1991 of its disk passage. We have st udied its chromospheric activity using high spatial resolution Hα filtergrams taken at Udaipur along with MSFC vector magnetograms. A possible relationship of flare productivity and the variation in shear has been explored. Flares were generally seen in those subareas of the active region which possessed closed magnetic field configuration, whereas only minor flares and/or surges occurred in subareas showing open magnetic field configuration. Physical mechanisms responsible for the observed surges are also discussed.