Ecological quality assessment of small estuaries from the Portuguese coast based on benthic macroinvertebrate assemblages indices

Benthic macroinvertebrates communities are the most consistently emphasized biotic component of aquatic ecosystems and are one of the biological indicators required for assessment by the European Water Framework Directive. In this context, several indices based on these communities have been developed in order to assess ecological quality of estuarine systems. In the present work we used AMBI, M-AMBI, BENTIX and BAT to distinguish ecological status of five small estuarine systems of the Portuguese south and southwest coasts. Although indices outputs did not differ between systems and sampling seasons, results indicated that the metrics in which these indices are based could differentiate community structures as a result of two main gradients that force these communities: the natural variability, and the anthropogenic impact.     

Biogeochemical and hydrographic controls on chromophoric dissolved organic matter distribution in the Pacific Ocean

Recent in situ observations of chromophoric dissolved organic material (CDOM) in the Pacific Ocean reveal the biogeochemical controls on CDOM and indicate predictive potential for open-ocean CDOM in diagnosing particulate organic matter (POM) remineralization rates within ocean basins. Relationships between CDOM and concentrations of dissolved oxygen, nutrients and inorganic carbon in the subthermocline waters of the Pacific reflect the relative influences of water mass ventilation and water-column oxidative remineralization. Apparent in situ oxygen utilization (AOU) accounts for 86% and 61% of variance in CDOM abundance, respectively, in Antarctic Intermediate Water and North Pacific Intermediate Water. In the deep waters of the Pacific below the zone of remineralization, AOU explains 26% of CDOM variability. The AOU–CDOM relationship results from competing biogeochemical and advective processes within the ocean interior. Dissolved organic carbon (DOC) is not statistically linked to the CDOM or AOU distributions, indicating that the majority of CDOM production occurs during the remineralization of sinking POM and thus potentially provides key information about carbon export. Once formed in the ocean interior, CDOM is relatively stable until it reaches the surface ocean where it is destroyed by solar bleaching. Susceptibility to bleaching confers an additional tracer-like quality for CDOM in water masses with active convection, such as mode waters that appear as subsurface CDOM minima. In the surface ocean, atypically low CDOM abundance highlights a region of unusually extreme oligotrophy: the subtropical South Pacific gyre. For these hyper-oligotrophic waters, the present CDOM observations are consistent with analysis of in situ radiometric observations of light attenuation and reflectance, demonstrating the accuracy of the CDOM spectrophotometric observations. Overall, we illustrate how CDOM abundance in the ocean interior can potentially diagnose rates of thermohaline overturning as they affect regional biogeochemistry and export. We further show how relative surface ocean CDOM abundances are driven in large part by processes occurring in the deep layers of the ocean. This is particularly significant for the interpretation of the global surface distribution of CDOM using satellite remote sensing.     

An investigation of the Eigenvalue Calibration Method (ECM) using GASP for non-imaging and imaging detectors

Polarised light from astronomical targets can yield a wealth of information about their source radiation mechanisms, and about the geometry of the scattered light regions. Optical observations, of both the linear and circular polarisation components, have been impeded due to non-optimised instrumentation. The need for suitable observing conditions and the availability of luminous targets are also limiting factors. The science motivation of any instrument adds constraints to its operation such as high signal-to-noise (SNR) and detector readout speeds. These factors in particular lead to a wide range of sources that have yet to be observed. The Galway Astronomical Stokes Polarimeter (GASP) has been specifically designed to make observations of these sources. GASP uses division of amplitude polarimeter (DOAP) (Compain and Drevillon Appl. Opt. 37, 5938–5944, 1998) to measure the four components of the Stokes vector (I, Q, U and V) simultaneously, which eliminates the constraints placed upon the need for moving parts during observation, and offers a real-time complete measurement of polarisation. Results from the GASP calibration are presented in this work for both a 1D detector system, and a pixel-by-pixel analysis on a 2D detector system. Following Compain et al. (Appl. Opt. 38, 3490–3502 1999) we use the Eigenvalue Calibration Method (ECM) to measure the polarimetric limitations of the instrument for each of the two systems. Consequently, the ECM is able to compensate for systematic errors introduced by the calibration optics, and it also accounts for all optical elements of the polarimeter in the output. Initial laboratory results of the ECM are presented, using APD detectors, where errors of 0.2 % and 0.1° were measured for the degree of linear polarisation (DOLP) and polarisation angle (PA) respectively. Channel-to-channel image registration is an important aspect of 2-D polarimetry. We present our calibration results of the measured Mueller matrix of each sample, used by the ECM, when 2 Andor iXon Ultra 897 detectors were loaned to the project. A set of Zenith flat-field images were recorded during an observing campaign at the Palomar 200 inch telescope in November 2012. From these we show the polarimetric errors from the spatial polarimetry indicating both the stability and absolute accuracy of GASP.     

Chemical and isotopic investigation of warm springs associated with normal faults in Utah

Thermal springs associated with normal faults in Utah have been analyzed for major cations and anions, and oxygen and hydrogen isotopes. Springs with measured temperatures averaging greater than 40°C are characterized by Na + K- and SO₄ + Cl-rich waters containing 10³ to 10⁴ mg/l of dissolved solids. Lower temperature springs, averaging less than 40°C, are more enriched in Ca + Mg relative to Na + K. Chemical variations monitored through time in selected thermal springs are probably produced by mixing with non-thermal waters. During the summer months at times of maximum flow, selected hot springs exhibit their highest temperatures and maximum enrichments in most chemical constituents.Cation ratios and silica concentrations remain relatively constant through time for selected Utah thermal springs assuring the applicability of the geothermometer calculations regardless of the time of year. Geothermometer calculations utilizing either the quartz (no steam loss), chalcedony or Mg-corrected Na/K/Ca methods indicate that most thermal springs in Utah associated with normal faults have subsurface temperatures in the range of 25 to less than 120°C. This temperature range suggests fluid circulation is restricted to depths less than about three kilometers assuming an average thermal gradient of about 40°C/km.Thermodynamic calculations suggest that most thermal springs are oversaturated with respect to calcite, quartz, pyrophyllite, (Fe, Mg)-montmorillonite, microcline and hematite, and undersaturated with respect to anhydrite, gypsum, fluorite and anorthite. Chalcedony and cristobalite appear to be the only phases consistently at or near saturation in most waters. Theoretical evaluation of mixing on mineral saturation trends indicates that anhydrite and calcite become increasingly more undersaturated as cold, dilute groundwater mixes with a hot (150°C), NaCl-rich fluid. The evolution of these thermal waters issuing from faults appears to be one involving the dissolution of silicates such as feldspars and micas by CO₂-enriched groundwaters that become more reactive with increasing temperature and/or time. Solution compositions plotted on mineral equilibrium diagrams trend from product phases such as kaolinite or montmorillonite toward reactant phases dominated by alkali feldspars.Isotopic compositions indicate that these springs are of local surface origin, either meteoric (low TDS, < 5000 mg/l) or connate ground water (high TDS, > 5000 mg/l). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence times of selected thermal spring systems (Red Hill, Thermo) have been evaluated through the use of a σ D-contour map of central and western Utah. Ages for waters in these areas range from about 13 years to over 500 years. These estimates are comparable to those made for low-temperature hydrothermal systems in Iceland.     

The relationship between dissolved hydrogen and nitrogen fixation in ocean waters

Fixed nitrogen is a key nutrient involved in regulating global marine productivity and hence the global oceanic carbon cycle. Oceanic nitrogen (N₂) fixation is estimated to supply 8×10¹² moles N y^?1 to the ocean, approximately equal to current riverine and the atmospheric inputs of fixed N, and between 50 and 100% of current estimates of oceanic denitrification. However, the spatial and temporal variability of N₂ fixation remains uncertain, mostly because of the normal low resolution sampling for diazotroph distribution and fixation rates. It is well established that N₂ fixation, mediated by the enzyme nitrogenase, is a source of hydrogen (H₂), but the extent to which it leads to supersaturation of H₂ in oceanic waters is unresolved. Here, we present simultaneous measurements of upper ocean dissolved H₂ concentration (nmol L^?1), and rates of N₂ fixation (μmol N m^?3 d^?1), determined using ¹⁵N₂ tracer techniques (at 7 or 15 m), on a transect from Fiji to Hawaii. We find a significant correlation (r=0.98) between dissolved H₂ and rates of N₂ fixation, with the greatest supersaturation of H₂ and highest rates of N₂ fixation being observed in the subtropical gyres at the southern (～18°S) and northern (18°N) reaches of the transect. The lowest H₂ saturation and N₂ fixation were observed in the equatorial region between 8°S and 14°N. We propose that an empirical relationship between H₂ supersaturations and N₂ fixation measurements could be used to guide sampling for ¹⁵N fixation measurements or to aid the spatial interpolation of such measurements.     

Fish Remains from Homestead Cave and Lake Levels of the Past 13,000 Years in the Bonneville Basin

A late Quaternary ichthyofauna from Homestead Cave, Utah, provides a new source of information on lake history in the Bonneville basin. The fish, represented by 11 freshwater species, were accumulated between 11,200 and 1000 ¹⁴C yr B.P. by scavenging owls. The ⁸⁷Sr/⁸⁶Sr ratio of Lake Bonneville varied with its elevation; ⁸⁷Sr/⁸⁶Sr values of fish from the lowest stratum of the cave suggest they grew in a lake near the terminal Pleistocene Gilbert shoreline. In the lowest deposits, a decrease in fish size and an increase in species tolerant of higher salinities or temperatures suggest multiple die-offs associated with declining lake levels. An initial, catastrophic, post-Provo die-off occurred at 11,300–11,200 ¹⁴C yr B.P. and was followed by at least one rebound or recolonization of fish populations, but fish were gone from Lake Bonneville sometime before 10,400 ¹⁴C yr B.P. This evidence is inconsistent with previous inferences of a near desiccation of Lake Bonneville between 13,000 and 12,000 ¹⁴C yr B.P. Peaks in Gila atraria frequencies in the upper strata suggest the Great Salt Lake had highstands at 3400 and 1000 ¹⁴C yr B.P.     

The Landscape of Diversity in U.S. Higher Education Geography

Palynological analyses were completed for the A and B horizons of a forested Mollic Hapludalf to determine type, amount, and distribution of pollen and spores within the soil solum. Hypotheses regarding the origin of pollen and the mechanisms of its movement within soil bodies are also advanced. Pollen downwash within the mineral soil seems to be very slow and confined to the uppermost porous and most homogenized part of the solum. The predominance of non-arboreal pollen at depth was believed to be a result of deposition with the loess parent material. High arboreal pollen frequencies in the upper horizons coupled with increases in non-arboreal types at depth indicate gradual ongoing mixing from the present vegetation into the soil.     

A multi-domain decomposition-based Fourier finite element method for the simulation of 3D marine CSEM measurements

We introduce a multi-domain decomposition Fourier finite element (MDDFFE) method for the simulation of three-dimensional (3D) marine controlled source electromagnetic measurement (CSEM). The method combines a 2D finite element (FE) method in two spatial dimensions with a hybrid discretization based on a Fourier FE method along the third dimension. The method employs a secondary field formulation rather than the total field formulation. We apply the MDDFFE method to several synthetic marine CSEM examples exhibiting bathymetry and/or multiple 3D subdomains. Numerical results show that the use of the MDDFFE method reduces the problem size by as much as 87 % in terms of the number of unknowns, without any sacrifice in accuracy.     

ISA accelerometer onboard the Mercury Planetary Orbiter: error budget

We have estimated a preliminary error budget for the Italian Spring Accelerometer (ISA) that will be allocated onboard the Mercury Planetary Orbiter (MPO) of the European Space Agency (ESA) space mission to Mercury named BepiColombo. The role of the accelerometer is to remove from the list of unknowns the non-gravitational accelerations that perturb the gravitational trajectory followed by the MPO in the strong radiation environment that characterises the orbit of Mercury around the Sun. Such a role is of fundamental importance in the context of the very ambitious goals of the Radio Science Experiments (RSE) of the BepiColombo mission. We have subdivided the errors on the accelerometer measurements into two main families: (i) the pseudo-sinusoidal errors and (ii) the random errors. The former are characterised by a periodic behaviour with the frequency of the satellite mean anomaly and its higher order harmonic components, i.e., they are deterministic errors. The latter are characterised by an unknown frequency distribution and we assumed for them a noise-like spectrum, i.e., they are stochastic errors. Among the pseudo-sinusoidal errors, the main contribution is due to the effects of the gravity gradients and the inertial forces, while among the random-like errors the main disturbing effect is due to the MPO centre-of-mass displacements produced by the onboard High Gain Antenna (HGA) movements and by the fuel consumption and sloshing. Very subtle to be considered are also the random errors produced by the MPO attitude corrections necessary to guarantee the nadir pointing of the spacecraft. We have therefore formulated the ISA error budget and the requirements for the satellite in order to guarantee an orbit reconstruction for the MPO spacecraft with an along-track accuracy of about 1 m over the orbital period of the satellite around Mercury in such a way to satisfy the RSE requirements.