Renovation of a failed constructed wetland treating acid mine drainage

 Acid mine drainage (AMD) from abandoned underground mines significantly impairs water quality in the Jones Branch watershed in McCreary Co., Kentucky, USA. A 1022-m² surface-flow wetland was constructed in 1989 to reduce the AMD effects, however, the system failed after six months due to insufficient utilization of the treatment area, inadequate alkalinity production and metal overloading. In an attempt to improve treatment efficiencies, a renovation project was designed incorporating two anoxic limestone drains (ALDs) and a series of anaerobic subsurface drains that promote vertical flow of mine water through a successive alkalinity producing system (SAPS) of limestone beds overlain by organic compost. Analytical results from the 19-month post-renovation period are very encouraging. Mean iron concentrations have decreased from 787 to 39 mg l^–1, pH increased from 3.38 to 6.46 and acidity has been reduced from 2244 to 199 mg l^–1 (CaCO₃ equivalent). Mass removal rates averaged 98% for Al, 95% for Fe, 94% for acidity, 55% for sulfate and 49% for Mn during the study period. The results indicate that increased alkalinity production from limestone dissolution and longer residence time have contributed to sufficient buffering and metal retention. The combination of ALDs and SAPS technologies used in the renovation and the sequence in which they were implemented within the wetland system proved to be an adequate and very promising design for the treatment of this and other sources of high metal load AMD. Received: 29 June 1998 · Accepted: 15 September 1998     

Propagation of MHD body and surface waves in magnetically structured regions of the solar atmosphere

The fact that magnetically structured regions exist in the solar atmosphere has been known for a number of years. It has been suggested that different kinds of magnetohydrodynamic (MHD) waves can be efficiently damped in these regions and that the dissipated wave energy may be responsible for the observed enhancement in radiative losses. From a theoretical point of view, an important task would be to investigate the propagation and dissipation of MHD waves in these highly structured regions of the solar atmosphere. In this paper, we study the behavior of MHD body and surface waves in a medium with either a single or double (slab) magnetic interface by use of a nonlinear, two-dimensional, time-dependent, ideal MHD numerical model constructed on the basis of a Lagrangean grid and semi-implicit scheme. The processes of wave confinement and wave energy leakage are discussed in detail. It is shown that the obtained results depend strongly on the type of perturbations imposed on the interface or slab and on the plasma parameter, . The relevance of the obtained results to the heating problem of the upper parts of the solar atmosphere is also discussed.     

Gyldén Model: The Slowly Changing Equivalent Gravitational Parameter

In the Gyldén problem, the case of slowly changing equivalent gravitational parameter (e.g.p.) is studied. Assuming the following law for the variation of the e.g.p.: μ (t) = μ₀+ εμ (εt), ε< μ₀, we obtained a) a O(ε⁴ T⁴)-approximation of the solution, on a shortened time scale (0,T), with T of order o(ε^-1),for the general case (i.e. the support function μ is O(1)-valued and admits an expansion in power series of its argument), and b) a O(ε²)-approximation of the solution, on a natural timescale of order O(1/ε), for the case of a bounded variation rate (i.e. the support function μ and its derivative are both O(1)-valued). For the study of the first problem we introduced a type of Lissajous variables and used the Lie-Hori normalization scheme; for the second problem we used the Delaunay variables and applied the von Zeipel method for approximate integration. The physical interpretation of the results is in both cases the same: within the corresponding limits of approximation, the variation of e.g.p. (i) has no effect on the size of the osculating ellipse, (ii) it sets the pericenter in slow rotation and (iii) it introduces a secular variation in the longitudes. This revised version was published online in July 2006 with corrections to the Cover Date.     

The coalescence of invariant manifolds and the spiral structure of barred galaxies

In a previous paper (Voglis et al., Paper I), we demonstrated that, in a rotating galaxy with a strong bar, the unstable asymptotic manifolds of the short-period family of unstable periodic orbits around the Lagrangian points L ₁ or L ₂ create correlations among the apocentric positions of many chaotic orbits, thus supporting a spiral structure beyond the bar. In this paper, we present evidence that the unstable manifolds of all the families of unstable periodic orbits near and beyond corotation contribute to the same phenomenon. Our results refer to a N -body simulation, a number of drawbacks of which, as well as the reasons why these do not significantly affect the main results, are discussed. We explain the dynamical importance of the invariant manifolds as due to the fact that they produce a phenomenon of 'stickiness' slowing down the rate of chaotic escape in an otherwise non-compact region of the phase space. We find a stickiness time of the order of 100 dynamical periods, which is sufficient to support a long-living spiral structure. Manifolds of different families become important at different ranges of values of the Jacobi constant. The projections of the manifolds of all the different families in the configuration space produce a pattern due to the 'coalescence' of the invariant manifolds. This follows closely the maxima of the observed   m = 2  component near and beyond corotation. Thus, the manifolds support both the outer edge of the bar and the spiral arms.     

Disc–Planet Interactions: Migration and Resonances in Extrasolar Planetary Systems

We consider orbital resonances in multiplanet systems. These are expected to arise during or just after formation in a gaseous disc. Disc–planet interaction naturally produces orbital migration and circularization through the action of tidal torques which in turn may lead to an orbital resonance. The mass and angular momentum content of the disc is likely to be comparable to that in the planets so that it is essential to fully incorporate the disc in the analysis.We study the orbital evolution of two planets locked in 2:1 commensurability through migration tidally induced by the disc using both analytic methods and numerical hydrodynamic simulations. The planets are assumed to orbit in an inner cavity containing at most only a small amount of disc material. Results are found to be sensitive to initial surface density profile, planet masses and disc parameters. The evolution may range between attaining and subsequently maintaining a resonance lock with two angles librating to divergent migration with no commensurability formed. In the former case eccentricities increase monotonically with time while the system undergoes inward migration. If the migration is halted by loss of the disc leaving the planets in a final configuration, there is likely to be a low probability of seeing resonant planets at small radii as well as a sensitive dependence on past history.We have also considered a multiplanet system in secular apsidal resonance. We consider the system as being in just one secular normal mode and include the effects of a gaseous disc. It is suggested that a normal mode may be selected by adding in some weak dissipative process in the disc and that it may remain, involving only the planets, when the disc is slowly removed.     

Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. II. Rate constants,effective surface area,and the hydrolysis of feldspar

Analysis of experimental data reported by Lagache (1965, 1976), Evans (1965), Busenberg (1975), Busenberg and Clemency (1976), Holdren and Berner (1979), Siegel and Pfannkuch (1984), and Chou and Wollast (1984) with the aid of irreversible thermodynamics and transition state theory (Aagaard and Helgeson, 1977, 1982) suggests that at temperatures at least up to 650°C, the rate of both congruent and incongruent feldspar hydrolysis in aqueous solutions far from equilibrium at pH ? 10.6 ? (2300/T), where T stands for temperature in kelvins, is a function solely of effective surface area and pH at constant pressure and temperature. At higher pH, the rate is apparently pH-independent up to ~pH 8 at 25°C, where it again becomes pH-dependent at higher pH. Observations of scanning electron micrographs indicate that the cross-sectional area of etch pits on hydrolyzed feldspar grains is of the order of 10^?9 to 10^?8 cm² and that the ratio of the effective to total surface area (which may or may not change with reaction progress) ranges from <0.01 to 1, depending on the grain size, dislocation density, and the extent of comminution damage on the surfaces of the grains. Apparent rate constants retrieved from experimental data reported in the literature for feldspar hydrolysis in the lower pH-dependent range extend from ~10^?13 to ~10^?7 moles cm^?2 sec^?1 at temperatures from 25° to 200°C, which is consistent with activation enthalpies for albite and adularia of the order of 20 kcal mole^?1. In contrast, the apparent rate constants for the pH-independent rate law range from ~10^?16 to ~10^?11 moles cm^?2 sec^?1 at temperatures from 25° to 650°C, which requires an activation enthalpy for adularia of ~ 9 kcal mole^?1. These observations are consistent with surface control of reaction rates among minerals and aqueous solutions. The rate-limiting step in the pH-dependent case apparently corresponds at the lower end of the pH scale to breakdown of a protonated configuration of atoms on the surface of the reactant feldspar, but at higher pH the rate is limited by decomposition of an activated surface complex corresponding in stoichiometry to hydrous feldspar. In highly alkaline solutions, an activated complex containing hydroxyl ions apparently controls the rate of feldspar hydrolysis. Nevertheless, near equilibrium, regardless of pH the rate is proportional to the chemical affinity of the overall hydrolysis reaction.     

The new hominid skeleton from Sterkfontein,South Africa: age and preliminary assessment

A new hominid skeleton from Sterkfontein Member 2 attaches to foot bones recovered from loose blocks during the 1980s and first described in 1995. Several flowstone horizons are present above and below the skeleton and have given clear palaeomagnetic signatures. Five changes in magnetic polarity have been identified; when constrained by the available biostratigraphy, this sequence can be placed confidently between 3.22 and 3.58 Ma. Interpolation of sedimentation rates over the small intervals between reversals allows this range to be reduced to 3.30–3.33 Ma. The skeleton is thus the oldest yet discovered and is considered to belong to a species of Australopithecus other than africanus. Copyright © 1999 John Wiley & Sons, Ltd.