Mercury mobilization by oxidative dissolution of cinnabar (α-HgS) and metacinnabar (β-HgS)

Cinnabar (α-HgS) and metacinnabar (β-HgS) dissolved at environmentally significant rates in oxygenated slurry experiments simulating a low-flow fluvial system. Based on SO₄²⁻ production, cinnabar dissolution rates were 2.64 to 6.16 μmol (SO₄²⁻) m^− 2 day^− 1, and metacinnabar dissolution rates were 1.20 to 1.90 μmol (SO₄²⁻) m^− 2 day^− 1. Monodentate-bound thiosulfate (S₂O₃²⁻) was identified as an oxidation product on the HgS surface by ATR-IR spectroscopy based on strong infrared absorption bands in the 1140–1145 cm^− 1 and 1006–1014 cm^− 1 regions. The presence of sulfide oxidation intermediates on the HgS surface indicates that SO₄²⁻ concentration underestimates α-HgS and β-HgS dissolution in this setting. Mercury release rates during dissolution were more than two orders of magnitude less than SO₄²⁻ production, but were significant: 0.47 mg (Hg) m^− 2 y^− 1 from cinnabar [6.45 nmol (Hg) m^− 2 day^− 1], and 0.17 mg (Hg) m^− 2 y^− 1 from metacinnabar [2.29 nmol (Hg) m^− 2 day^− 1]. The Hg mobilized during α-HgS and β-HgS dissolution is sufficient to form natural Au–Hg amalgam in downstream placer settings. The proportion of mercury that is not remobilized during α-HgS and β-HgS dissolution likely adsorbs to the dissolving mercuric sulfide. Adsorption of Hg²⁺ to cinnabar was detected in situ by anodic stripping voltammetry using a cinnabar-modified carbon paste electrode following accumulation of Hg²⁺ on the electrode at open circuit potential.     

Karrat Fjord (Greenland) tsunamigenic landslide of 17 June 2017: initial 3D observations

On 17 June 2017, a landslide-generated tsunami reached the village of Nuugaatsiaq, Greenland, leaving four persons missing and presumed dead. Here, we present a preliminary high-resolution analysis of the tsunamigenic landslide scar based on three-dimensional (3D) reconstructions of oblique aerial photographs taken during a post-failure reconnaissance helicopter overflight. Through a 3D quantitative comparison with pre-failure topography, we estimate that approximately 58 million m³ of rock and colluvium (talus) was mobilized during the landslide, 45 million m³ of which reached the fjord, resulting in a destructive tsunami. We classify this event as a “tsunamigenic extremely rapid rock avalanche,” which likely released along a pre-existing metamorphic fabric, bounded laterally by slope-scale faults. Further analysis is required to properly characterize this landslide and adjacent unstable slopes, and to better understand the tsunami generation.     

Rapidly oscillating M giant stars?

The Hipparcos mission discovered a few dozen M giant stars with periods P shorter than 10 d. Similar stars may be found in other large data bases of new variables (e.g., OGLE). The three possible sources of the magnitude variations – pulsation, starspots and ellipsoidal deformation – are discussed in general terms. The parallaxes and V − I colour indices are used to calculate radii and temperatures for all M giant variables with P <100 d. Masses are estimated from the positions of the stars in a Hertzsprung–Russell (HR) diagram, using evolutionary tracks. Using these data, it is shown that starspots can be ruled out as a variability mechanism in almost all cases, and ellipsoidal variations in about half of the stars. Pulsation in very high-overtone modes appears to be the only viable explanation for the stars with P <10 d. Many of the stars may be multiperiodic. IRAS data are used to deduce information about reddening and circumstellar dust. The apparently low level of mass-loss, as well as the kinematics and the spatial distribution of the stars, indicates that they are from a relatively young (i.e., thin disc) giant star population.     

Enhancing the effectiveness of policy-relevant integrative research in rural areas

There has been much debate about the importance of policy-relevant research in geography over the last decade. There has also been an increasing recognition by policymakers of the importance of integrative (interdisciplinary and transdisciplinary) approaches to policy-relevant research. However, geographers have been more reluctant than their colleagues in other social and natural sciences to embrace integrative research collaborations. For integrative research to achieve its full potential and to encourage greater participation from the geographical research community, we need to increase our understanding of its potential value, but also some of the challenges that it poses, and how these can be overcome. In this paper, we consider the processes involved in conducting successful integrative research from the perspective of researchers involved in these projects. We base our analysis on the results of a questionnaire survey of international integrative research programmes on environmental issues in rural areas, combined with our own experiences of working in integrative research. We conclude that effective integrative research depends on the establishment of a clear conceptual framework, the use of appropriate temporal and spatial scales in the research, effective language and communication, time and commitment, and trust and respect. We also highlight the value of stakeholder involvement in integrative research to ensure the policy relevance of the work and provide a mechanism to assist with effective knowledge transfer of the results.     

Characteristics of intense rainfall over Gujarat State (India) based on percentile criteria

The study focuses on the spatial and temporal variations of intense/extreme rainfall events over Gujarat State (India) during the period 1970–2014. Average monsoon rainfall for the state shows a significant increasing trend, with an increase of 48 mm/decade. Some of the stations in the Saurashtra region show a statistically significant increasing trend but none of the stations in the state show a decreasing trend. The increasing trend in monsoon rainfall is very significant for the past three decades, with an increase of 167 mm/decade. Instead of fixed absolute threshold values, relative threshold values of rainfall corresponding to the 95th, 98th, 99th and 99.5th percentiles for each station have been proposed to represent heavy, very heavy, intense and extreme rainfall, which varied between 70–120, 105–160, 130–210 and 165–280 mm, respectively. Significant increasing trends are observed for the frequency of heavy and very heavy rainfall events over the state.     

Sandy beach ecosystems: key features, sampling issues, management challenges and climate change impacts

Escalating pressures caused by the combined effects of population growth, demographic shifts, economic development and global climate change pose unprecedented threats to sandy beach ecosystems worldwide. Conservation of beaches as functional ecosystems and protection of their unique biodiversity requires management interventions that not only mitigate threats to physical properties of sandy shores, but also include ecological dimensions. Yet, beach management remains overwhelmingly focused on engineering interventions. Here we summarise the key outcomes of several workshops, held during the 2006 Sandy Beach Ecology Symposium in Vigo, Spain, that addressed issues of climate change, beach management and sampling methodology. Because efficient communication between managers and ecologists is critical, we summarise the salient features of sandy beaches as functional ecosystems in 50 'key statements'; these provide a succinct synopsis of the main structural and functional characteristics of these highly dynamic systems. Key outcomes of the workshops include a set of recommendations on designs and methods for sampling the benthic infaunal communities of beaches, the identification of the main ecological effects caused by direct and indirect human interventions, the predicted consequence of climate change for beach ecosystems, and priority areas for future research.     

Fourier amplitude sensitivity test applied to dynamic combined finite-discrete element methods–based simulations

Fracture propagation plays a key role for a number of applications of interest to the scientific community, from dynamic fracture processes like spallation and fragmentation in metals to failure of ceramics, airplane wings, etc. Simulations of material deformation and fracture propagation rely on accurate knowledge of material characteristics such as material strength and the amount of energy being dissipated during the fracture process. Within the combined finite-discrete element method (FDEM) framework material fracture behavior is typically described through a parametrized softening curve, which defines a stress-strain relationship unique to each material. We apply the Fourier amplitude sensitivity test to explore how each of these parameters influences the simulated damage processes and to determine the key input parameters that have the most impact on the model response. We present several sensitivity numerical experiments for the simulation of a split Hopkinson pressure bar (SHPB) test for weathered granite samples using different combinations of model parameters. We validate the obtained results against SHPB experimental data. The experiments show that the model is mostly sensitive to parameters related to tensile and shear strengths, even in the presence of other parameter perturbations. The results suggest that the specification of tensile and shear strengths at the interfaces dominate the stress-time history of the FDEM simulation of SHPB test.     

Diverse forms of primordial organic matter identified in interplanetary dust particles

Abstract– Coordinated in situ transmission electron microscopy and isotopic measurements of carbonaceous phases in interplanetary dust particles were performed to determine their origins. Five different types of carbonaceous materials were identified based on their morphology and texture, observed by transmission electron microscopy: globular, vesicular, dirty, spongy, and smooth. Flash heating experiments were performed to explore whether some of these morphologies are the result of atmospheric entry processes. Each of these morphologies was found to have isotopically anomalous H and N. Rare C isotopic anomalies were also observed. The isotopic and morphological properties of several of these phases, particularly the organic globules, are remarkably similar to those observed in other extraterrestrial materials including carbonaceous chondrites, comet 81P/Wild 2 particles collected by the Stardust spacecraft, and Antarctic micrometeorites, indicating that they were widespread in the early solar system. The ubiquitous nature and the isotopic anomalies of the nanoglobules and some other morphologies strongly suggest that these are very primitive phases. Given that some of the isotopic anomalies (D and ¹⁵N excesses) are indicative of mass fractionation chemical reactions in a very cold environment, and some others (¹³C and ¹⁵N depletions) have other origins, these carbonaceous phases come from different reservoirs. Whatever their origins, these materials probably reflect the first stages of the evolution of solar system organic matter, having originated in the outermost regions of the protosolar disk and/or interstellar cold molecular clouds.     

Understanding the evolution of a disaster��a Framework for Assessing Crisis in a System Environment (FACSE)

To understand the evolution of a disaster, we propose a Framework for Assessing Crisis in a System Environment (FACSE). FACSE is set in a multi-system environment, containing the human system as well as the various natural and technological systems that interact with people. We take a lifecycle perspective, via which we quantify rhythms of life exhibited in multiple systems, across different scales, at different times. The lifecycle perspective also implies a relative approach in that rhythms of life during time t can be compared against those during t-1. We illustrate how rhythms of life in the human system can be measured at different scales. We propose a new concept??the degree of disaster, which is a composite score that encompasses the various measurements of rhythms of life from multiple systems, across different scales. We conclude the paper by discussing the potential offered by FACSE in disaster research as well as the limitations.