No evidence for thermogenic methane release in coal from the Karoo-Ferrar large igneous province

The Early Jurassic Toarcian oceanic anoxic event (T-OAE) and concurrent negative carbon-isotope (δ¹³C) excursion have recently been attributed to either the release of methane (CH₄) clathrates or thermogenic CH₄ gas associated with the Karoo-Ferrar large igneous province (LIP) into coals and organic-rich shales. ¹²C-enriched thermogenic CH₄ production associated with the Karoo-Ferrar would result in residual material being ¹²C-depleted nearer the intrusions. In this study, geochemical analyses (carbon isotopes, volatile matter (VM), vitrinite reflectance (R_o)) are reported for two coal transects associated with dykes intruding the No. 4L coal in the Highveld Coalfield, Karoo Basin, South Africa. VM decreases from over 35% to around 15% in one transect, and the second transect shows a less pronounced decrease (from > 25% to ~ 16%). Accompanying the decrease in VM content is an increase in R_o from background levels of around 0.7% to over 4% adjacent to the dyke; used as a palaeo-geothermometer, R_o values indicate background temperatures of ~ 100 °C increasing to > 300 °C close to the contact. Despite changes in VM and R_o, there are no significant changes in δ¹³C, certainly not of the magnitude that would be expected associated with large-scale thermogenic CH₄ generation. These and other Gondwanan coals have low vitrinite and liptinite contents (components more prone to CH₄ generation), in part explaining the modest decreases in VM adjacent to the dykes. This, combined with the relatively narrow metamorphic aureole surrounding the intrusions and the likelihood that at least some of the volatiles generated by the intrusion were trapped as coalbed CH₄ or condensed as pyrolytic carbon, suggests only limited CH₄ release. In addition, based on original estimates of moisture contents in these coals and the depth at time of intrusion (1,000–2,000 m) the dykes would have lost most of their energy heating and evaporating water, thus having very little remaining energy to generate thermogenic CH₄.     

Dryland salinity processes within the discharge zone of a local groundwater system,southeastern Australia

Detailed study of a localised saline discharge zone in southeastern Australia shows that the salinisation is mostly due to the shallow water table (<1–2 m from the surface). Direct evaporation, particularly in summer, leads to extremely high soil–water salinities at the surface, even though the underlying groundwater is moderately fresh. Groundwater discharge is localised at a break of slope, where the water table intersects the surface, and where the transition from permeable sands to clay-rich sediments inhibits lateral groundwater flow. Higher salt concentrations build up in the clays because of the long residence times during which soil-waters are exposed to evapotranspiration and the reduced potential for salts to be flushed from the sediments. As a result the saline discharge area does not correspond to the part of the site with the largest salt store. Results of the study demonstrate that for dryland salinisation to occur, the groundwater beneath the discharge zone need not be saline, and the presence of a large salt store does not necessarily lead to problems of dryland salinisation if, as in the clay-rich sediments at the site, the salt lies below the pasture root zone. Furthermore, mobilisation of salt stores within low permeability sediments by rising groundwater may be minor.

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Résumé L’étude détaillée d’une zone localisée d’émergence salée au sud-est de l’Australie montre que la salinisation est surtout due à la nappe phréatique (<1–2 m sous la surface). L’évaporation directe, particulièrement durant l’été, conduit à des salinités de l’eau du sol extrêmement élevées à la surface, même si l’eau souterraine sous-jacente est modérément douce. L’émergence de l’eau souterraine est localisée à la rupture de pente, là où la nappe phréatique rencontre la surface du sol et où la transition entre sables perméables et sédiments riches en argiles inhibe les écoulements d’eau souterraine latéraux. Les plus fortes concentrations en sel s’accumulent dans les argiles du fait de temps de résidence élevés, durant lesquels les eaux du sol sont exposées à l’évapotranspiration et à un lessivage réduit des sédiments. Il en résulte que l’aire d’émergence des eaux salées ne correspond pas à la partie du site rencontrant la réserve de sel la plus importante. Les résultats de l’étude démontrent que pour que la salinisation d’une zone aride devienne effective, l’eau souterraine sous la zone ne doit pas être forcément salée, et la présence d’une zone étendue de réserve de sel ne conduit pas forcément à des problèmes de salinisation de zones arides si, comme dans les sédiments argileux du site, le sel ne repose pas sous la zone de pature. De plus, la mobilisation des réserves de sel dans les sédiments peu perméables par la montée du niveau de l’eau souterraine devrait être mineure.

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Resumen El estudio detallado de una zona local de descarga salina en el sudeste de Australia, muestra que la salinización es principalmente debido a un nivel freático poco profundo (<1–2 m de la superficie). La evaporación Directa, particularmente en verano, conlleva a salinidades de suelo-agua sumamente altas en la superficie, aunque el agua subterránea subyacente es moderadamente dulce. La descarga de Agua subterránea se localiza en una interrupción de la ladera, dónde el nivel freático intercepta la superficie, y donde la transición de las arenas permeables a los sedimentos ricos en arcilla inhibe el flujo lateral del agua subterránea. Las concentraciones de sal más altas se forman en las arcillas debido a los tiempos de residencia largos durante los cuales se exponen el conjunto suelo-agua a la evapotranspiración y también por el potencial reducido para las sales de ser expulsadas de los sedimentos. Como resultado el área de la descarga salina no corresponde a la parte del sitio con el contenido de sal más grande. Los resultados del estudio demuestran que para que ocurra la salinización en terrenos secos, el agua subterránea bajo la de zona de descarga no necesita ser salina, y que la presencia de un almacenamiento de sal grande, no necesariamente lleva a los problemas de salinización en terrenos secos si, como en los sedimentos ricos en arcilla del sitio, la sal yace debajo de la zona de raíz de la pastura. Además, la movilidad de depósitos de sal dentro de los sedimentos de permeabilidad baja pueden ser menores, por causa del agua subterránea ascendente.

     

Experimental studies of sodic microperthites from the Loch Ailsh syenite

Solvus curves under both ‘dry’ and ‘hydrothermal’ (P_H2O = 1 kbar) conditions have been determined for two microperthitic alkali feldspar starting materials from the Loch Ailsh syenite complex, Assynt, Scotland. One sample (Ab₇₄ Or₂₄ An₂) possessed a K-phase showing dominant monoclinic symmetry to both powder and single-crystal X-ray methods, the other (Ab₈₈Or₃₀An₂) had maximum microcline as K-phase. These materials gave essentially identical solvi for both types of experiment, interpreted as indicating similar degrees of local order in the K-phase, but with differing domain size, leading to the different X-ray properties. The ‘dry’ solvus curves confirm the determination of the microcline-low albite solvus of Bachinski & Müller. The hydrothermal curves are used to estimate P_H1O <3.5 kbars, T > 755 °C for emplacement of the Loch Ailsh syenites.     

The 2dF Galaxy Redshift Survey: galaxy luminosity functions per spectral type

We calculate the optical b _J luminosity function (LF) of the 2dF Galaxy Redshift Survey (2dFGRS) for different subsets defined by their spectral properties. These spectrally selected subsets are defined using a new parameter, η , which is a linear combination of the first two projections derived from a Principal Component Analysis. This parameter η identifies the average emission- and absorption-line strength in the galaxy rest frame spectrum, and hence is a useful indicator of the present star formation. We use a total of 75 000 galaxies in our calculations, chosen from a sample of high signal-to-noise ratio, low-redshift galaxies observed before 2001 January. We find that there is a systematic steepening of the faint-end slope ( α ) as one moves from passive  ( α =-0.54)  to active  ( α =-1.50)  star-forming galaxies, and that there is also a corresponding faintening of the rest frame characteristic magnitude   M *-5 log₁₀( h )  (from −19.6 to −19.2). We also show that the Schechter function provides a poor fit to the quiescent (Type 1) LF for very faint galaxies  [ M _{b J}-5 log₁₀( h )  fainter than −16.0], perhaps suggesting the presence of a significant dwarf population. The LFs presented here give a precise confirmation of the trends seen previously in a much smaller preliminary 2dFGRS sample, and in other surveys. We also present a new procedure for determining self-consistent k -corrections, and investigate possible fibre-aperture biases.     

Land change attribution based on Landsat time series and integration of ancillary disturbance data in the Athabasca oil sands region of Canada

The Alberta Oil Sands (AOS) is a unique area in Canada undergoing significant disturbance and recovery due to a variety of anthropogenic and natural factors. Accurately quantifying these changes in space and time is important for assessing ecosystem status and trends. In this research, we implemented an approach to combine Landsat time series for the period 1984–2012 with ancillary change datasets to derive detailed change attribution in the AOS. Detected changes were attributed to causes including fire, forest harvest, surface mining, insect damage, flooding, regeneration, and several generic change classes (abrupt/gradual, with/without regeneration) with accuracies ranging from 74% to 100% for classes that occurred frequently. Lower accuracies were found for the generic gradual change classes which accounted for less than 3% of the affected area. Timing of abrupt change events were generally well captured to within ±1 year. For gradual changes timing was less accurate and variable by change type. A land-cover time series was also created to provide information on “from-to” change. A basic accuracy assessment of the land cover showed it to be of moderate accuracy, approximately 69%. Results show that fire was the major cause of change in the region. As expected, surface mine development and related activities have increased since 2000. Insect damage has become a more significant agent of change in the region. Further investigation is required to determine if insect damage is greater than past historical events and to determine if industrial development is linked to the increasing trend observed.