Tracing sediment movement in interrill overland flow on a semi-arid grassland hillslope using magnetic susceptibility

Experiments were undertaken to determine the feasibility of tracing sediment movement in interrill overland flow. Crushed magnetite was introduced as a source-line 10 cm wide by 8 m long on a runoff plot 18 m wide by 29 m long located in southern Arizona. Initial magnetic susceptibilities along this source line, and along three transects located 0·25, 2·95 and 5 m downslope of the source-line, were measured. Movement of the magnetite in response to three rainfall simulation experiments was monitored. During the first two experiments, overland flow discharge was sampled at miniature flumes located along two cross sections on the plot downslope of the source-line, and at a supercritical flume at the plot outlet. Magnetic susceptibilities along the source-line and transects were measured after all three experiments. Results show that the magnetite moves very early in the experiments and that it reaches one of the flumes 2 m downslope of the source-line in 3 min. Most of the tracer moves a very short distance: 29·7 per cent is deposited within 25 cm of the source-line and only 2·2 per cent is deposited 2·95 m away. The deposition rate appears to decrease exponentially away from the source-line. Very little magnetite is recorded in the flow through the miniature flumes: in general it makes up less than 1 per cent of the total sediment load. No temporal pattern in these percentages is observed. Magnetite appears to be an effective tracer of sediment movement in interrill overland flow, though its higher density than natural soil may affect its detachment and transport.     

Assessing the natural recovery of a lake contaminated with Hg using estimated recovery rates determined by sediment chronologies

Deer Lake is an impoundment located near Ishpeming, Michigan, USA. Iron mining assay laboratories located in Ishpeming disposed of Hg salts to the city sewer whose outfall was located along an inlet to Deer Lake. An effort to remediate the system in the mid 1980s which consisted of drawing down water in the impoundment in order to volatize Hg from the sediments did not result in recovery of the system. Since the mid 1990s, the remediation strategy has been to allow the continual burial of the contaminated sediments, i.e., natural recovery. The goal of this study was to assess the effectiveness of this strategy. This was accomplished by investigating the state of the system in terms of its recovery and estimating the time frame for recovery. Sediment cores were collected in 2000 to determine historical trends in accumulation rates and concentrations of Hg and other metals. Sedimentation rates and sediment ages were estimated using ²¹⁰Pb. Event-based dating (e.g., peak of ¹³⁷Cs in 1963) was used to supplement ²¹⁰Pb data due to non-monotonic features in the ²¹⁰Pb profile and activities that were not at supported levels at the base of the core. Selected results are that: (1) drawdown significantly influenced sedimentation patterns causing slopes for ²¹⁰Pb profiles that reflected the influx of older sediment, (2) periods of Fe production correlate to Hg loading indicating the point source for contamination, a relationship not previously identified, (3) Hg:Al ratios indicate a recent change to a watershed pathway for Hg loading and (4) Hg concentrations had decreased from their peak, remain elevated, and were increasing after 1997. The cause of the recent Hg concentrations may be related to influx of contaminated watershed soils or sediments. Estimating the time frame for recovery is challenging in this system because the process of natural recovery seems to have been arrested and deeper, uncontaminated sediments, were not recovered as a basis for reference. However, a recovery to background conditions is likely not achievable since rates of Hg loading to nearby lakes and the current rate of atmospheric deposition are greater than an estimate of background conditions for Deer Lake. Assuming recovery continued after 2000, estimates of the time required for recovery varied based on the system state used to define it (e.g., recent rates of wet Hg deposition or Hg surface concentrations/fluxes from similar systems), but were less than 12 a. However, the recent increasing values of recovery indicators (e.g., Hg concentrations) suggests that these estimates are conservative and will be longer if recovery remains arrested, which may in part be due to the legacy of Hg contamination on the landscape. This study shows that estimates of recovery of highly disturbed lake systems can be made in the absence of within lake reference conditions by using comparisons to reference systems and challenges of estimating ages from atypical ²¹⁰Pb activity profiles can be overcome in part using event-based dating techniques.     

Northern opportunities: A strategic review of Canada's Arctic icebreaking services

Climate change presages increasingly ice-free waters in the Canadian Arctic and fundamental reconfiguration of Asia–Europe and Asia–US East Coast marine transportation networks via the Northwest Passage (NWP). Retreating sea ice will impact the annual re-supply of goods to northern communities, natural resource development, cruise ship and adventure tourism activity, and the fishing industry. Reviews of infrastructure to support increased shipping activity and support future developments highlight an ageing Canadian Coast Guard (CCG) icebreaker fleet. This paper aims to debate the need for, and provision, ownership and management of Arctic icebreaking services required to serve a NWP. It reports perceptions by 110 experts of future marine activity in the Canadian Arctic and CCG services, principally Arctic icebreaking, in terms of their effectiveness and efficiency. The extent of possible private involvement is identified and evaluated. The requirements needed to ensure timely and uninterrupted marine transportation from vessels operating in these waters are highlighted.     

An isobaric–isenthalpic magma mixing model for the Hasan Dagi volcano,Central Anatolia,Turkey

Calc-alkaline rocks of the Hasan Dagi volcano (Central Anatolia, Turkey) are products of arc volcanism triggered by continental collision. Volcanic rocks of the Hasan Dagi range in composition from basalt to rhyolite but are dominated by andesite and dacite. Considering only the mass transfer part of the process leads to an incomplete picture of magma chamber processes. The exclusion of simultaneous calculations of heat and mass transfer between mixing magmas, however, has prevented petrologists from gaining new insights into the magma mixing process. Thus, we report our experimental results in conjunction with modeling with MELTS to test the ideas concerning the petrogenesis of Hasan Dagi volcanic rocks and quantitatively model the relevant petrogenetic processes. Our results demonstrate that the chemical diversity of Hasan Dagi volcano is inconsistent with the closed-system crystallization and differentiation. Thus, (1) our experimental modeling, (2) the agreement between the liquid line of descent defined by the natural rock data and the MELTS calculations, and (3) the agreement between the mineralogy of the rocks and calculated mineralogy corroborate the conclusion that the isobaric–isenthalpic magma mixing of basalt and rhyolite is the major controlling process in the petrogenesis of the Hasan Dagi magmas.     

Exsolution and coarsening mechanisms and kinetics in an ordered cryptoperthite series

Cryptoperthites from the Klokken layered syenite intrusion were examined by TEM to determine the role of exsolution, ordering and twinning in the development of the coherent microtextures during slow cooling, the stratigraphic position of the samples in the layered series giving an independent variable in determining their evolution. Both periodicity (primary and secondary) and morphology change with distance from the top of the series. Most samples contain low microcline in the diagonal association.Partial ordering occurred before exsolution, which was followed by Albite-twin formation in the albite lamellae. The twin periodicity depends on the average lamellar thickness (or on the primary lamellar periodicity, ₁) and no longer changes during subsequent morphological evolution. In the Or-rich lamellae long-period Albite twins develop before waves form in the lamellar interface. The interfaces rotate with increasing order to give parallel-sided zig-zag lamellae of low microcline with Albite twinned lamellae of low albite, which may pinch and swell. Where the albite lamellae are discontinuous, adjacent microcline lamellae coalesce giving oblique lamellae and Pericline or M-type twins. Thickening of some oblique lamellae gives a distinct secondary periodicity, ₂, which outlines lozenge-shaped areas with relics of the primary periodicity and, if coarse enough, is responsible for optically-visible braid microperthite. Coherency, demonstrated by high resolution images, is maintained through all stages of the coarsening.A time-temperature-transformation diagram for continuous cooling is presented and can be used to interpret the kinetics and morphological evolution of cryptoperthites from rocks with very different cooling rates (dykes and lavas to very large plutons), which have, however, similar primary lamellar periodicities. The finest periodicities are only slightly larger than the supposed initial periodicities ( _o) for spinodal decomposition and little coarsening can have occurred. Coarsening at cooling rates slow enough to produce significant ordering may be much slower than coarsening in disordered feldspars. Primary coarsening may be stopped by the development of Albite twins in the Abrich phase, which will require reversal of the order-antiorder sense of parts of the framework. Coarsening may also be slowed if the phases at intermediate temperatures order at different rates or have different equilibrium degrees of Al-Si order. Secondary coarsening can develop at much lower temperatures (<400° C) on the formation of low microcline, when both phases have the same framework order.     

The Reykjanes Ridge: structure and tectonics of a hot-spot-influenced, slow-spreading ridge, from multibeam bathymetry, gravity and magnetic investigations

We report a comprehensive morphological, gravity and magnetic survey of the oblique- and slow-spreading Reykjanes Ridge near the Iceland mantle plume. The survey extends from 57.9°N to 62.1°N and from the spreading axis to between 30 km (3 Ma) and 100 km (10 Ma) off-axis; it includes 100 km of one arm of a diachronous ‘V-shaped' or ‘chevron' ridge. Observed isochrons are extremely linear and 28° oblique to the spreading normal with no significant offsets. Along-axis there are ubiquitous, en-echelon axial volcanic ridges (AVRs), sub-normal to the spreading direction, with average spacing of 14 km and overlap of about one third of their lengths. Relict AVRs occur off-axis, but are most obvious where there has been least axial faulting, suggesting that elsewhere they are rapidly eroded tectonically. AVRs maintain similar plan views but have reduced heights nearer Iceland. They are flanked by normal faults sub-parallel to the ridge axis, the innermost of which occur slightly closer to the axis towards Iceland, suggesting a gradual reduction of the effective lithospheric thickness there. Generally, the amplitude of faulting decreases towards Iceland. We interpret this pattern of AVRs and faults as the response of the lithosphere to oblique spreading, as suggested by theory and physical modelling. An axial, 10–15 km wide zone of high acoustic backscatter marks the most recent volcanic activity. The zone's width is independent of the presence of a median valley, so axial volcanism is not primarily delimited by median valley walls, but is probably controlled by the lateral distance that the oblique AVRs can propagate into off-axis lithosphere. The mantle Bouguer anomaly (MBA) exhibits little mid- to short-wavelength variation above a few milliGals, and along-axis variations are small compared with other parts of the Mid-Atlantic Ridge. Nevertheless, there are small axial deeps and MBA highs spaced some 130 km along-axis that may represent subdued third-order segment boundaries. They lack coherent off-axis traces and cannot be linked to Oligocene fracture zones on the ridge flanks. The surveyed chevron ridge is morphologically discontinuous, comprising several parallel bands of closely spaced, elevated blocks. These reflect the surrounding tectonic fabric but have higher fault scarps. There is no evidence for off-axis volcanism or greater abundance of seamounts on the chevron. Free-air gravity over it is greater than expected from the observed bathymetry, suggesting compensation via regional rather than pointwise isostasy. Most of the observed variation along the ridge can be ascribed to varying distance from the mantle plume, reflecting changes in mantle temperature and consequently in crustal thickness and lithospheric strength. However, a second-order variation is superimposed. In particular, between 59°30′N and 61°30′N there is a minimum of large-scale faulting and crustal magnetisation, maximum density of seamounts, and maximum axial free-air gravity high. To the north the scale of faulting increases slightly, seamounts are less common, and there is a relative axial free-air low. We interpret the 59°30′N to 61°30′N region as where the latest chevron ridge intersects the Reykjanes Ridge axis, and suggest that the morphological changes that culminate there reflect a local temperature high associated with a transient pulse of high plume output at its apex.