Sorption and desorption behavior of residual antidepressants and caffeine in freshwater sediment and sewage sludge

The use of antidepressants is widespread in modern times. Thus, they present a potential risk for ecosystems due to occurrence in domestic sewage containing unaltered metabolites and structures, even after the treatment plants have processed the sewage. The current research investigated the sorption and desorption of antidepressants(citalopram, venlafaxine, fluoxetine, sertraline, and amitriptyline) and caffeine from freshwater sediment and sewage sludge. The samples of freshwater sediment were ...     

Ideal width of transects for monitoring source-related categories of plastics on beaches

Although there is a consensus on the necessity of monitoring solid wastes pollution on beaches, the methods applied vary widely. Therefore, creating, testing and recommending a method that not only allows comparisons of places and periods, but also the detection of source signals, will be important to reach the objectives of the source-prevention principle. This will also allow the optimisation of time, resources, and processing of samples and data. A classification of the items found into specific categories was made according to their most probable source/use (fisheries, food packaging, hazardous, sewage/personal hygiene, beach user, general home). This study tested different widths of sampling transects to be used in the detection of plastics contamination on beaches, until all the categories were significantly represented. Each transect had its total width (50m) sub-divided into eight intervals of 0-2.5m; 2.5-5m; 5-10m; 10-15m; 15-20m; 20-30m; 30-40m; and 40-50m. The accumulated number of categories in the 50m (up to 2.5m; up to 5m and so on) was used to determine the minimal width necessary to qualitatively characterize the area regarding plastics contamination. The diversity of the categories was directly related to the area of the sampling transect. These results indicate that a significant increase in the number of categories in the first intervals tend to stabilize from 15-20m onwards.     

Sediment contamination in floodplains and alluvial terraces as an historical record of gold exploitation in the Carmo River basin,Southeast Quadrilátero Ferrífero,Minas Gerais,Brazil

This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na₂O, K₂O, SiO₂, CaO, MgO, Al₂O₃, Fe₂O₃, TiO₂, P₂O₅, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.     

Two Brazilian archaeological sites investigated by GPR: Serrano and Morro Grande

The application of the ground penetrating radar (GPR) at two archaeological sites, Serrano and Morro Grande, situated in Araruama County, Rio de Janeiro, Brazil, aids the study of a prehistoric indigenous culture, associated with the “Tupinambá” that inhabited the region during prehistoric times.The archaeological remains of the study area are mainly characterized by pottery artifacts for several uses, including funerary urns, which were buried within layers of sand and clay. Several profiles were acquired using a RAMAC system, with a 200 and 400 MHz frequency antennae. At the Serrano site, the profiles were acquired around some partially exposed pottery shards, due to sand exploitation. The resultant profiles provided a response model to guide the interpretation of new profiles acquired at other sites in the area, which present similar characteristics.The results showed the great importance of the dielectric permittivity contrast which exists between the targets and the host media, in order for possibly significant features to be identified in radar data.     

Investigating Ionospheric Scintillation Effects on Multifrequency GPS Signals

Surveys in Geophysics - Over the last 15 years, the satellite constellation of the global positioning system (GPS) has been modernized for more precise applications, with the introduction...     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.     

Seismic hazard analysis in zones of time and space interdependence: An application to São Miguel Island,Azores

The Azores Islands are located in the mid-Atlantic region near the triple junction where the Euro-Asiatic-African-American plates join together. Seismic activity in the area is very high, as can be observed either from historical events since the fifteenth century, from present day microseismicity, and from direct and indirect measurements of recent tectonic deformation. Volcanic activity is also present throughout the region. All available information, even data exhibiting low quality, was used to develop hazard models of São Miguel Island. Source zones were established based on both the global tectonic behaviour of the region and on the local active fault structures. Recurrence laws for São Miguel Island, for which historical information seemed quite incomplete, were obtained from the large events in the entire archipelago and from their remarkable pattern of time and space dependence, and complimented by information on long-term fault deformation (for the longer recurrence periods) and on high precision instrumental network (for the very short recurrence periods). Attenuation laws were derived from data on events felt and/or recorded in the Island. Hazard maps were obtained through a modified version of McGuire's algorithm for several geometries of source areas and results compared with the maximum observed intensity of historical events.     

The 18 June 1997 Companion supercells: Multiparametric Doppler radar analysis

Summary ?On 18 June 1997 two simultaneous supercells 50 km apart swept the Po valley W-NW to E-SE. An exceptional hailfall lasted for more than 3 hours over a strip 200 km wide. There are no records of companion supercells over northern Italy, a fact that attributes to the present observations a considerable meteorological interest. The forcing due to a baroclinic wave disturbance created the synoptic conditions favourable for storm development. A closer mesoscale analysis conducted using the Local Analysis and Prediction System (LAPS) indicates that the interaction of the storm systems with the low-level frontal high-humidity band is a key aspect of their evolution. The operational polarimetric Doppler weather radar of S. Pietro Capofiume was used for a volumetric analysis of the storm system focusing on the microphysical and dynamical structure, and wind patterns. Reflectivity and Doppler wind fields document the transition from multicell to supercell phase for one of the storms. Differential reflectivity (Z_DR) fields are examined. Positive Z_DR columns are detected in connection with the storms strong updraft. Flare echoes hint to the presence of substantial hailshafts. The spectrum width field is used to investigate internal motions. Limited dual Doppler analysis is carried out and results are discussed in terms of storm evolution properties. Received June 30, 1999/Revised February 3, 2000