Vermiculite bio-barriers for Cu and Zn remediation: an eco-friendly approach for freshwater and sediments protection

The increase in heavy metal contamination in freshwater systems causes serious environmental problems in most industrialized countries, and the effort to find eco-friendly techniques for reducing water and sediment contamination is fundamental for environmental protection. Permeable barriers made of natural clays can be used as low-cost and eco-friendly materials for adsorbing heavy metals from water solution and thus reducing the sediment contamination. This study discusses the application of permeable barriers made of vermiculite clay for heavy metals remediation at the interface between water and sediments and investigates the possibility to increase their efficiency by loading the vermiculite surface with a microbial biofilm of Pseudomonas putida, which is well known to be a heavy metal accumulator. Some batch assays were performed to verify the uptake capacity of two systems and their adsorption kinetics, and the results indicated that the vermiculite bio-barrier system had a higher removal capacity than the vermiculite barrier (+34.4 and 22.8 % for Cu and Zn, respectively). Moreover, the presence of P. putida biofilm strongly contributed to fasten the kinetics of metals adsorption onto vermiculite sheets. In open-system conditions, the presence of a vermiculite barrier at the interface between water and sediment could reduce the sediment contamination up to 20 and 23 % for Cu and Zn, respectively, highlighting the efficiency of these eco-friendly materials for environmental applications. Nevertheless, the contribution of microbial biofilm in open-system setup should be optimized, and some important considerations about biofilm attachment in a continuous-flow system have been discussed.     

Computing derivative information of sequentially coupled subsurface models

A generic framework for the computation of derivative information required for gradient-based optimization using sequentially coupled subsurface simulation models is presented. The proposed approach allows for the computation of any derivative information with no modification of the mathematical framework. It only requires the forward model Jacobians and the objective function to be appropriately defined. The flexibility of the framework is demonstrated by its application in different reservoir management studies. The performance of the gradient computation strategy is demonstrated in a synthetic water-flooding model, where the forward model is constructed based on a sequentially coupled flow-transport system. The methodology is illustrated for a synthetic model, with different types of applications of data assimilation and life-cycle optimization. Results are compared with the classical fully coupled (FIM) forward simulation. Based on the presented numerical examples, it is demonstrated how, without any modifications of the basic framework, the solution of gradient-based optimization models can be obtained for any given set of coupled equations. The sequential derivative computation methods deliver similar results compared to FIM methods, while being computationally more efficient.     

Multiple timescale constraints for high-flux magma chamber assembly prior to the Late Bronze Age eruption of Santorini (Greece)

The rhyodacitic magma discharged during the 30–80 km³ DRE (dense rock equivalent) Late Bronze Age (LBA; also called ‘Minoan’) eruption of Santorini caldera is known from previous studies to have had a complex history of polybaric ascent and storage prior to eruption. We refine the timescales of these processes by modelling Mg–Fe diffusion profiles in orthopyroxene and clinopyroxene crystals. The data are integrated with previously published information on the LBA eruption (phase equilibria studies, melt inclusion volatile barometry, Mg-in-plagioclase diffusion chronometry), as well as new plagioclase crystal size distributions and the established pre-LBA history of the volcano, to reconstruct the events that led up to the assembly and discharge of the LBA magma chamber. Orthopyroxene, clinopyroxene and plagioclase crystals in the rhyodacite have compositionally distinct rims, overgrowing relict, probably source-derived, more magnesian (or calcic) cores, and record one or more crystallization (plag???opx?>?cpx) events during the few centuries to years prior to eruption. The crystallization event(s) can be explained by the rapid transfer of rhyodacitic melt from a dioritic/gabbroic region of the subcaldera pluton (mostly in the 8–12 km depth range), followed by injection, cooling and mixing in a large melt lens at 4–6 km depth (the pre-eruptive magma chamber). Since crystals from all eruptive phases yield similar timescales, the melt transfer event(s), the last of which took place less than 2 years before the eruption, must have involved most of the magma that subsequently erupted. The data are consistent with a model in which prolonged generation, storage and segregation of silicic melts were followed by gravitational instability in the subcaldera pluton, causing the rapid interconnection and amalgamation of melt-rich domains. The melts then drained to the top of the pluton, at fluxes of up to 0.1–1 km³ year^??1, where steep vertical gradients of density and rheology probably caused them to inject laterally, forming a short-lived holding chamber prior to eruption. This interpretation is consistent with growing evidence that some large silicic magma chambers are transient features on geological timescales. A similar process preceded at least one earlier caldera-forming eruption on Santorini, suggesting that it may be a general feature of this rift-hosted magmatic system.     

An ecosystem-based composite spatial model for floodplain vulnerability assessment: a case study of Artigas,Uruguay

Floods are natural processes that constitute a hazard to society when associated to improper land use. Anthropic activities in floodplains are a factor of vulnerability that converts a natural hazard into a threat factor, eventually leading to disaster. Nowadays, natural and social complex processes demand integrated assessments in order to improve their understanding, helping decision making over sustainable use of territory, as well as integrating society’s activity in ecosystems and potentials, restrictions and benefits that society obtain from them. In this context, the objective of this work was to build a composite vulnerability model for a floodplain under urban influence, using an integrated assessment approach. This model was based on three dimensions; threat, fragility and an ecosystem services provision. These dimensions were calculated using both primary and secondary information, and weights by specialists. Main results show that the area presents high vulnerability with an increasing gradient towards high and urbanized areas, associated with an important number and relevant ecosystem services. Also, a spatial heterogeneity of the three dimensions emerged, making evident this area’s complexity and the need of integrated assessments to approach it. The composite vulnerability model proposed presents an elevated potential for natural and social processes analysis in floodplains, which is crucial for these territory management. Moreover, these integrated dimensions could contribute to decision making in different levels, as well as generating important supplies for environmental management and land planning.

     

The P-y Response of Laterally Loaded Flexible Piles in Residual Soil

This paper describes the main features related to lateral displacements with depth after successive lateral loading–unloading cycles applied to the top of reinforced-concrete flexible bored piles embedded in naturally bonded residual soil. The bored piles under study have a cylindrical shape, with 0.40-m in diameter and 8.0-m in length. Both bored piles types (P1 and P2) include an embedded steel pipe section in their center as longitudinal steel reinforcements: pile type P1 has another 16 steel rods as steel reinforcement to concrete while pile type P2 has no further steel reinforcement. Pile type P1 has three times as much stiffness (EI) and four and a half times the plastic moment (M_y) than pile type P2. A similar load–displacement performance was observed at initial loads as for small displacements of both piles. At this initial loading stage, the response of the reinforced concrete piles is a function of the soil characteristics and of a linear elastic pile deformation. During this stage, piles can even be understood as probes for evaluating soil reactions. For larger horizontal displacements, after the concrete section starts undergoing large deformations, approaching the ultimate bending moment, pile behavior and consequently the load–displacement relation starts to diverge for both piles. For pile P1 the values of relevant lateral displacements are extended to about 2.5-m in depth, while for pile P2 lateral displacements are mostly constrained to about 2.0-m in depth. Measurements of horizontal displacements of pile P1 against depth recorded with a slope indicator show that, after unloading, lateral loads at distinct stages (small and near failure loads), exhibits a much higher elastic phase of the system response. An analytical fitting model of soil reaction is proposed based on the measured displacements from slope indicator. The integration of a continuous model proposed for the soil reaction agrees fairly well with the measured displacements up to moments close to plastic limit. Results of load–displacement show that the stiffer pile (P1) was able to mobilize twice as much lateral load compared to pile P2 for a service limit displacement of about 20 mm. The paper shows results that enable the isolation of the structural variable through real scale pile load tests, thus granting understanding of its importance and enabling its quantitative visualization in examples of piles embedded in residual soil sites.

     

Predicting the impact of management and climate scenarios on groundwater nitrate concentration trends in southern Portugal

Hydrogeology Journal - The dynamics related to evolution of nitrate-contaminated groundwater are analyzed with focus on the impact of intrinsic aquifer properties, agricultural activities and...     

Long-term monitoring of the behavior of a talus-colluvium deposit

Landslides - This article describes the behavior of a talus-colluvium deposit up to 70-m thick located in the Serra dos Orgaos, Rio de Janeiro/RJ, Brazil. The monitoring dataset of 13 years...     

Long‐term temporal and spatial patterns in bioeroding sponge distribution at the Abrolhos Bank,Brazil, Southwestern Atlantic

Bioeroding sponges belong to the most dominant bioeroders, significantly contributing to the erosion of coral reefs. Some species are tolerant or even benefit from environmental conditions such as ocean warming, acidification, and eutrophication. In consequence, increases in sponge bioerosion have been observed on some coral reefs over the last decades. The Abrolhos Bank is the largest coral reef system in the South Atlantic. It has been affected by sedimentation, eutrophication, overfishing, and climate change, mainly affecting coastal reefs, and at lesser intensity outer ones as well. This study aimed to describe spatial and temporal patterns in bioeroding sponge distribution in carbonate substrates in the Abrolhos Bank. Photo‐quadrats were used to compare bioeroding sponge abundance between two shallow reefs: a coastal, Pedra de Leste (PL), and an outer reef, Parcel dos Abrolhos (PAB). Each individual was delimitated over the substrate by determining the sponge surface through a line connecting the outermost papillae. The study was conducted over 6 years in 2008–2009 and 2013–2016. Four species of bioeroding sponges were identified: Cliona carteri Ridley, 1881, C. delitrix Pang, 1973, C. cf. schmidtii Ridley, 1881, and Siphonodictyon coralliphagum Rützler, 1971. The distribution and abundance of species varied between the inner and outer reefs and across the years, and displayed certain selectivity for the calcareous substrates recorded. Crustose coralline algae (CCA) were the main substrate excavated by the most abundant bioeroding species, C. carteri, and represented 70% of the substrate types occupied by this sponge (CCA, coral overgrown by CCA and plain coral). The highest abundance of bioeroding sponges observed in photo‐quadrats was 21.3 individuals/m² at the outer reefs (PAB) in 2014. The abundances or areal extents of bioeroding sponges were up to 10 times greater on the outer reefs than on the coastal ones, where sedimentation is higher and more strongly influenced by siliciclastic material. Moreover, a higher herbivorous fish biomass has been reported on outer reefs which could also influence the higher abundance of bioeroding sponges in outer reefs. During the study period of 6 years, an increase in bioeroding sponge abundance was observed at the outer reefs (PAB), with the sea surface temperature increase. As CCA have an important role in reefal cementation and carbonate production in the Abrolhos reefs, a bioerosion impact might be expected, in particular, on the outer reefs.     

The Cabo Frio upwelling overrides geographical patterns in the population dynamics of the shrimp Artemesia longinaris Spence Bate, 1888 (Decapoda: Penaeidae)

Upwelling areas are among the most productive ecosystems on the planet, influencing the biology of marine organisms. This study investigated the population dynamics of the shrimp Artemesia longinaris in two regions in southeastern Brazil, one inside (Macaé—Rio de Janeiro State) and one outside (Ubatuba—State of São Paulo) the Cabo Frio upwelling area. The aim was to verify the influence of the upwelling phenomenon on the abundance, growth, longevity, size of sexual maturity, and reproductive period of the species. In total, 188,902 individuals were captured at Macaé and 3,461 at Ubatuba. Individuals captured at Macaé showed larger maximum size, higher longevity, and slower growth rate, besides reaching sexual maturity at larger sizes than at Ubatuba. Continuous reproduction was observed in both regions, with juvenile recruitment peaks in spring and summer. Local conditions observed at Macaé were influenced by the Cabo Frio upwelling zone, characterized by productive and cooler waters that are around 20°C during most of the year. The upwelling phenomenon is probably the main factor influencing the population parameters studied here, changing the geographic patterns previously observed for the variation of these parameters in A. longinaris.