A Case Study of the Performance of Different Detrending Methods in Turbulent-Flux Estimation

Observations using a three-dimensional scanning coherent Doppler lidar in an urban area revealed the characteristics of streaky structures above a rough, inhomogeneous surface for a high-Reynolds-number flow. The study focused on two points: (1) the frequency of occurrence and conditions required for the presence of streaky structures, and (2) the universal scaling of the spacing of streaky structures (\(\lambda )\). The horizontal snapshots of the radial velocity were visually classified into six groups: Streak, Mixed, Fishnet, No streak, Front, and Others. The Streak category accounted for more than 50% of all possible flows and occurred when the horizontal wind speed was large and the atmospheric stratification was near-neutral. The spacing (\(\lambda )\) was estimated from the power spectral density of the streamwise velocity fluctuations along the spanwise direction. The spacing \(\lambda \) decreased with an increase in the local velocity gradient. Furthermore, it was revealed that the local velocity gradient normalized by the friction velocity and the boundary-layer height (\(z_i )\) comprehensively predicts \(\lambda /z_i \) under various experimental and environmental conditions, in terms of the scale of motion (i.e., indoor and outdoor scales), thermal stratification (i.e., from weakly unstable to stable stratification), and surface roughness (i.e., from flat to very rough surfaces).     

Time evolution of chemical exchanges during mixing of rhyolitic and basaltic melts

We present the first set of chaotic mixing experiments performed using natural basaltic and rhyolitic melts. The mixing process is triggered by a recently developed apparatus that generates chaotic streamlines in the melts, mimicking the development of magma mixing in nature. The study of the interplay of physical dynamics and chemical exchanges between melts is carried out performing time series mixing experiments under controlled chaotic dynamic conditions. The variation of major and trace elements is studied in detail by electron microprobe and Laser Ablation ICP-MS. The mobility of each element during mixing is estimated by calculating the decrease in the concentration variance in time. Both major and trace element variances decay exponentially, with the value of exponent of the exponential function quantifying the element mobility. Our results confirm and quantify how different chemical elements homogenize in the melt at differing rates. The differential mobility of elements in the mixing system is considered to be responsible for the highly variable degree of correlation (linear, nonlinear, or scattered) of chemical elements in many published inter-elemental plots. Elements with similar mobility tend to be linearly correlated, whereas, as the difference in mobility increases, the plots become progressively more nonlinear and/or scattered. The results from this study indicate that the decay of concentration variance is in fact a robust tool for obtaining new insights into chemical exchanges during mixing of silicate melts. Concentration variance is (in a single measure) an expression of the influence of all possible factors (e.g., viscosity, composition, and fluid dynamic regime) controlling the mobility of chemical elements and thus can be an additional petrologic tool to address the great complexity characterizing magma mixing processes.     

Rough evaluation of the water-inflow discharge in abandoned mining tunnels using a simplified water balance model: the case of the Cogne iron mine (Aosta Valley, NW Italy)

One of the most complex hydrogeological problems in the design and maintenance of drainage systems in abandoned mining sites is quantifying the maximum water infiltration and, therefore, the amount that is potentially drainable by the tunnels. This problem is compounded when water-inflow data are limited or lacking. The aim of the study was to present a single but reliable model for making this evaluation; this model was applied to the case history of the abandoned Cogne iron ore mining complex (Western Alps, Aosta Valley Region, NW Italy). The study focused on quantifying the amount of water infiltrating into the mine drifts, using a water balance model in a Geographic Information System (GIS) environment. In the model, five different infiltration scenarios were calculated, including a detailed analysis of rainfall data, snow density and thickness (Snow Water Equivalent calculation), and melting periods. The maximum water discharge that could affect the mine tunnels was, therefore, determined under several scenarios of normal precipitation conditions and during heavy rainfall, including the case of the Cogne valley flood in October 2000, used as a reference for the limit conditions. Taking into account the various approximations considered, the results can be considered a good indication of the magnitude of the total amount of water that should be drained out through abandoned mine drifts and in the drainage network during implementation of final closure of the mine.     

Metamorphic CO2 production from calc-silicate rocks via garnet-forming reactions in the CFAS–H2O–CO2 system

The type and kinetics of metamorphic CO₂-producing processes in metacarbonate rocks is of importance to understand the nature and magnitude of orogenic CO₂ cycle. This paper focuses on CO₂ production by garnet-forming reactions occurring in calc-silicate rocks. Phase equilibria in the CaO–FeO–Al₂O₃–SiO₂–CO₂–H₂O (CFAS–CO₂–H₂O) system are investigated using P–T phase diagrams at fixed fluid composition, isobaric T–X(CO₂) phase diagram sections and phase diagram projections in which fluid composition is unconstrained. The relevance of the CFAS–CO₂–H₂O garnet-bearing equilibria during metamorphic evolution of calc-silicate rocks is discussed in the light of the observed microstructures and measured mineral compositions in two representative samples of calc-silicate rocks from eastern Nepal Himalaya. The results of this study demonstrate that calc-silicate rocks may act as a significant CO₂ source during prograde heating and/or early decompression. However, if the system remains closed, fluid–rock interactions may induce hydration of the calc-silicate assemblages and the in situ precipitation of graphite. The interplay between these two contrasting processes (production of CO₂-rich fluids vs. carbon sequestration through graphite precipitation) must be considered when dealing with a global estimate of the role exerted by decarbonation processes on the orogenic CO₂ cycle.     

Directional response of a reconstituted fine‐grained soil—Part II: performance of different constitutive models

In this paper, the performance of different advanced constitutive models for soils is evaluated with respect to the experimentally observed behaviour of a soft reconstituted clay subject to a wide range of loading directions, see (presented in the companion paper). The models considered include a three‐surface kinematic hardening elastoplastic model; the CLoE hypoplastic model; a recently proposed K‐hypoplastic model for clays, and an enhanced version of the same model incorporating the concept of intergranular strain. A clear qualitative picture of the relative performance of the different models as a function of the loading direction is obtained by means of the incremental strain response envelopes. The definition of suitable error measures allows to obtain further quantitative information in this respect. For the particular initial conditions and loading programme considered in this study, the kinematic hardening and the enhanced K‐hypoplastic models appear to provide the best performance overall. Copyright © 2006 John Wiley & Sons, Ltd.     

Distribution of noble gases in Chinese tektites: Implication for neon solubility in natural glasses

Abstract— Five indochinites from Hainan Island and the Leizhou Peninsula, China were analyzed for noble gas abundances and isotopic ratios. These splash‐form tektites show vesiculation ranging from 0.4 vol% to 8 vol%, as determined by digital image analysis (software SXM®) on thin section photographs. To study the distribution of noble gases in vesicles and in glass, the gases were extracted by heating and by crushing, respectively, on 2 aliquots of the same sample. The results show that 5 to 53% of the total measured ²⁰Ne resides in vesicles. The calculated concentration of neon dissolved in the glass is higher (0.7‐1 times 10^?7 cm³STP/g) than that expected from solubility equilibrium (1 times 10^?8 cm³STP/g), assuming solubility data from MORB glasses. The neon concentration of splash‐form tektites, those analyzed in this work and those from other strewn‐fields worldwide, is correlated with the SiO₂ content of glass and with the nonbridging oxygen per tetrahedral cation in the melt (hereafter NBO/T ratio), the latter being an index of the free‐volume in the silica network where neon could be dissolved. These correlations suggest that the glass structure of tektite has a larger free‐volume available for dissolving noble gases than MORB glasses.     

4. Building of a Habitable Planet

Except the old Jack Hills zircon crystals, it does not exit direct record of the first 500 Ma of the Earth history. Consequently, the succession of events that took place during this period is only indirectly known through geochemistry, comparison with other telluric planets, and numerical modelling. Just after planetary accretion several episodes were necessary in order to make life apparition and development possible and to make the Earth surface habitable. Among these stages are: the core differentiation, the formation of a magma ocean, the apparition of the first atmosphere, oceans and continents as well as the development of magnetic field and of plate tectonics. In the same time, Earth has been subject to extraterrestrial events such as the Late Heavy Bombardment (LHB) between 3.95 and 3.8 Ga. Since 4.4–4.3 Ga, the conditions for pre-biotic chemistry and appearance of life were already met (liquid water, continental crust, no strong meteoritic bombardment, etc...). This does not mean that life existed as early, but this demonstrates that all necessary conditions assumed for life development were already present on Earth.     

Groundwater flow and residence time in a karst aquifer using ion and isotope characterization

In order to identify the origin of the main processes that affect the composition of groundwater in a karstic aquifer, a hydrogeochemical and isotopic study was carried out of water from numerous observation wells located in Sierra de Gador, a semiarid region in SE Spain. Several natural and anthropogenic tracers were used to calculate groundwater residence time within this complex aquifer system. Analysis of major ions enabled the principal geochemical processes occurring in the aquifer to be established, and the samples were classified into four distinctive solute groups according to this criterion. Dissolution of carbonate rocks determines the chemical composition of less mineralized water. In another group, the concurrent dissolution of dolomite and precipitation of calcite in gypsum-bearing carbonate aquifer, where the dissolution of relatively soluble gypsum controls the reaction, are the dominant processes. Marine intrusion results in highly mineralized waters and leads to base exchange reactions. The groundwater enrichment of minor and trace elements allowed classification of the samples into two classes that are linked to different flow patterns. One of these classes is influenced by a slow and/or deep regional flow, where the temperature is generally elevated. The influence of sulphate reduces by up to 40 % the barium concentration due to the barite precipitation. Isotope data (T, ¹⁴C) confirm the existence of recent local flows, and regional flow system, and ages of ground water may reach 8000 years. The importance of gypsum dissolution in this aquifer is proved by the δ³⁴S content.     

Identifying a low-frequency oscillation in Galileo IOV pseudorange rates

Galileo, the European global navigation satellite system, is in its in-orbit validation phase and the four satellites which have been available for some months now have allowed a preliminary analysis of the system performance. Previous studies have showed that Galileo will be able to provide pseudorange measurements more accurate than those provided by GPS. However, a similar improvement was not found for pseudorange rate observations in the velocity domain. This fact stimulated additional analysis of the velocity domain, and, in particular, an unintended oscillatory component was identified as the main error source in the velocity solution. The magnitude of such oscillation is less than 10 cm/s, and its period is in the order of few minutes. A methodology was developed to identify oscillatory components in the Galileo IOV pseudorange rate observables, and it was verified that the measurements from Galileo IOV PFM and Galileo IOV FM2 are affected by a small oscillatory disturbance. This disturbance stems from the architecture adopted for combining the frequency references provided by the two active clocks present in the Galileo satellites. The issue has been solved in Galileo IOV FM3 and Galileo IOV FM4, and the oscillatory component has been eliminated. We also propose a methodology for removing this unwanted component from the final velocity solution and for determining the performance that Galileo will be able to achieve. The analysis shows that Galileo velocity solution will provide a root-mean-square error of about 8 cm/s even in the limited geometry conditions achieved using only four satellites. This shows the potential of Galileo also in the determination of user velocity.