Morphological evolution of a complex drift-aligned prograded barrier

Prograded barriers are coastal landforms with a worldwide distribution that provide a paleoenvironmental record within a sequence of successive ridges and intervening swales. Most barriers with variable terrestrial morphologies, also known as complex barriers, have been poorly studied. At the main entrance of Western Port, a bay in southeastern Australia, a morphologically complex barrier was formed as a function of its somewhat sheltered position and orientation in relation to sporadic swells and tidal circulation. LiDAR-derived topography shows highly truncated and asymmetrical ridges both across and along the Somers–Sandy Point barrier plain. These uncommon morphologies are associated with an intricate hydrodynamic circulation subject to sporadic storms approaching at a sharp angle to the shoreline that eliminate a significant part of the sedimentary record but also redistribute vast quantities of sand to the downdrift shoreline, and a large and variable sandy bank that undergoes intense sediment movement. Optically stimulated luminescence (OSL) dating within a limited area on the western side revealed an age of ~2600 years for the innermost dated ridge, located about halfway across the plain. Significant erosion of the ridges' record occurred on the western side of the barrier between 2600 and 700 years ago and between 600 and 240 years ago, whereas undated ridges on the eastern side were preserved. This creates an opportunity for future research on past erosional events that would be of great value for coastal management and adaptation. Textural and elemental (XRF) sediment characteristics suggest that the type of material provided for barrier accretion remained the same throughout the late Holocene. Given the sustained growth of the barrier and other sandy parts of the bay, a net supply of marine sand from Bass Strait must have occurred. The proposed evolutionary model contributes to the understanding of the sediment budget for the bay as a whole.     

Stability of Al- and F-rich titanite in metacarbonate: petrologic and isotopic constraints from a polymetamorphic eclogitic marble of the internal Sesia Zone (Western Alps)

Al- and F-rich titanite (3.862O₃ <9.33 wt%, 0.931(F, OH)₁Ti_-1O_-1 substitution within single crystals, particularly at grain boundaries with omphacite and/or phengite. In-situ ion microprobe U-Pb analysis of titanite domains that have various Al and F contents yielded apparent ²⁰⁶Pb/²³⁸U ages scattering between 283 and 153 Ma. Chemical and petrological data are indispensable to interpret this complex age distribution, and the good correlation between ²⁰⁶Pb/²³⁸U ratios and Al content indicates that the Al- and F-rich titanite was formed during pre-Alpine metamorphism (𔕑ᆟ Ma). Progressively younger ages are obtained in domains with decreasing Al and F content, suggesting that partial chemical re-equilibration was responsible for the incomplete isotopic resetting during Alpine metamorphism. Petrological and U-Pb data show that Al- and F-rich titanite should be used with caution to infer high-pressure conditions in polymetamorphic carbonate systems.     

Susceptibility to oxidative stress of mussels (Mytilus galloprovincialis) in the Venice Lagoon (Italy)

The aim of this study was to evaluate the susceptibility to pollutant mediated oxidative stress of the Mediterranean mussel Mytilus galloprovincialis in the Venice lagoon (Italy).

In June 2003, mussels from a farm were transplanted to eight sites in the lagoon for five weeks. Oxidative stress responses were measured by: (i) total oxyradical scavenging capacity (TOSC) assay, for an overall evaluation of the oxidative stress response capability; (ii) catalase (CAT), as a key enzyme involved in the antioxidant defence system; (iii) malondialdehyde (MDA), as an indicator of lipid peroxidation, to evaluate an oxidative damage; (iv) metallothioneins (MTs), as they play a role in the antioxidant defence.

The TOSC analysis revealed a reduced capability to eliminate: (i) peroxyl radical in mussels transplanted at Palude della Rosa, Valle Millecampi and Chioggia; (ii) hydroxyl radical at Campalto and Valle Millecampi; (iii) peroxynitrite at Valle Millecampi.

Inhibition in CAT activity, observed in all the monitored sites, confirms the presence of an oxidative pressure in transplanted mussels.

In addition, Pearson correlation analysis was performed in order to observe possible links between the various parameters. The PCA was a powerful tool to discriminate impacted sites, suggesting that the mussels transplanted throughout the Venice lagoon were subjected to different levels of oxidative pressure. Furthermore, it provided an easy and useful tool to summarize the obtained results.     

An estimation of the probable maximum precipitation for river basins in the Czech Republic

The hydro-meteorological evaluation of a flood event in July 1997 (the Odra flood in Central Europe) demonstrated that new procedures to estimate design floods for the reservoir outflow structures in the Czech Republic (CR) were needed. Therefore, the techniques of the estimation of Probable Maximum Precipitation (PMP) were developed in a national research project (1998–2000), and the activity focused on the improvement of the area related PMP estimates was going on within a present national project. In the frame of the evaluation of the next extreme precipitation event in August 2002 (the Labe flood in the CR and Germany), we compared the catchments related precipitation with the PMP estimates. In this paper, an outline of the PMP estimation techniques is given and the use of data from the Czech gauges is described, the aim being the statistical derivation of the point and area PMP estimates for precipitation duration of 1 to 5 days. The use of radar data in assessing the maximized area reduction factor is discussed and the relationship resulting from the radar measurements over the CR territory is presented. An evaluation of the radar-based area rainfall enabled us to transform the point PMP to the area PMP estimate designed for the river basins in CR. In the last part of the paper, the results obtained by comparing the rainfalls in 1997 and 2002 flood events with the PMP estimates are presented. The comparison showed that the maximum area rainfalls over small Czech catchments (the 3rd order river basins) did not exceed 63% of the corresponding PMP values.     

A new versatile constitutive law for modelling the monotonic response of soft rocks and structured fine-grained soils

This paper deals with a new critical state–based constitutive model for soft rocks and fine-grained soils. The model, formulated in the single-surface plasticity framework, is characterised by the following main features: (i) a generalised three-invariant yield surface capable of reproducing a wide set of well-known criteria, (ii) the dependency of the elastic stiffness on the current stress state by means of a hyperelastic formulation, (iii) the ability of simulating the plastic strain–driven structure degradation processes by a set of appropriate isotropic hardening laws, and (iv) a nonassociate flow rule in the meridian plane. The adopted formulation is hierarchical, such that the various features of the model can be activated or excluded depending on the specific kind of geomaterial to be modelled and on the quality and quantity of the related available experimental results. The constitutive model was implemented in a commercial finite element code by means of an explicit modified Euler scheme with automatic substepping and error control. The procedure does not require any form of stress correction to prevent drift from the yield surface. The performance of the model is first analysed by means of a wide set of parametric analyses, in order to highlight the main features and to evaluate the sensitivity of the formulation with reference to the input parameters. The model is then adopted to simulate the experimental response observed on three different geomaterials, ranging from soft clays to soft rocks.     

Radial distribution of lead and lead isotopes in stem wood of Norway spruce: A reliable archive of pollution trends in Central Europe

Annual growth rings of a common hardwood species, Picea abies L., were investigated as a potential archive of past atmospheric Pb pollution. Wide distribution of trees in terrestrial settings and straightforward chronology are two advantages of this potential geochemical archive, but several processes described in the literature may obscure the trends in past Pb deposition. These confounding factors include, e.g., radial post-depositional mobility of Pb in xylem, and ecosystem acidification leading to higher bioavailability of Pb. One- to five-year annual wood increments were analyzed for Pb concentrations and ²⁰⁶Pb/²⁰⁷Pb ratios at Jezeri (JEZ), Uhlirska (UHL) and Na Lizu (LIZ), three sites in the Czech Republic, differing in atmospheric Pb loads. Three to four trees per site were included in the study. Distinct Pb concentration maxima between 1960 and 1990 at the two heavily polluted sites (JEZ and UHL) coincided with historical Pb emissions known from inventories of industrial production. No Pb concentration maxima were found at one site, LIZ, situated in a national park 150 km from major pollution sources. Spruce tree rings from JEZ, located just 5 km from coal-burning power stations, contained a large proportion of coal-derived Pb (a high-²⁰⁶Pb/²⁰⁷Pb ratio of 1.19). A coal-related maximum in ²⁰⁶Pb/²⁰⁷Pb in JEZ tree rings was found using two different analytical techniques, laser-ablation multi-collector ICP MS, and single-collector sector-field ICP MS. In a three-isotope graph (²⁰⁶Pb/²⁰⁷Pb vs. ²⁰⁸Pb/²⁰⁷Pb), tree-ring data plotted into the field of ombrotrophic (i.e., rain-fed) peat bogs, suggesting negligible contribution of bedrock-derived Pb in the xylem. We concluded that none of the potential confounding factors played a major role at our sites. Annual growth rings of P. abies in Central Europe faithfully recorded historical changes in atmospheric Pb depositions.     

Pre‐Variscan metagabbro from NW Sardinia,Italy: evidence of an enriched asthenospheric mantle source for continental alkali basalts

Small metagabbro bodies are enclosed in the metasedimentary sequence of NW Sardinia. The metagabbros represent the last magmatic episode before the continent–continent collision that built up the Variscan chain of north Sardinia. The metagabbros are composed of variable proportions of plagioclase and pyroxene igneous relics and metamorphic minerals. Major and trace element data, specifically high TiO₂ and P₂O₅ and low K and Rb contents, as well as light rare‐earth elements, Nb and Ta enrichment, suggest an alkaline affinity for the gabbro and emplacement in a within‐plate tectonic setting. The gabbro was derived from an ocean island alkali basalt‐like asthenospheric mantle source enriched with incompatible elements and uncontaminated by crustal or subducted materials. Non‐modal modelling indicates a 5–7% partial melting of the asthenospheric mantle. Copyright © 2003 John Wiley & Sons, Ltd.     

The investigation of potential earthquake sources in peninsular Italy: A review

We summarise and discuss almost a century of progress inthe understanding of the main characteristics of large Italian earthquakes.Topics of discussion include (1) the distribution of the largest earthquakesin relation with Late Pleistocene and Holocene faulting, (2) the geologicaland tectonic setting of the 1908 Messina Straits, 1915 Fucino Plain and1980 Irpinia earthquakes, (3) some of the geodynamic motivations for thecharacteristics of Italian seismicity, and (4) the resulting implications for theassessment of seismic hazard. In a subsequent section of the paper we present a summaryof recent achievements in the understanding and characterization of Italianseismicity, with special emphasis on the assignment of large historicalearthquakes to specific sources identified through geological observationsand on the evaluation of average recurrence intervals for individualearthquake sources. The final section describes some of the efforts being madefor matching the newly acquired geological evidence with instrumental andhistorical observations of Italian seismicity and the hypotheses than can bederived for anticipating the locus of large earthquakes of the future.