Eclogite-facies fluid infiltration: constraints from δ18O zoning in garnet

In situ analysis reveals that eclogite-facies garnets are zoned in δ¹⁸O with lower values in the core and rims that are ~1.5 to 2.5 ‰ higher. This pattern is present in 9 out of 12 garnets analyzed by SIMS from four orogenic eclogite terranes, and correlates with an increase in the mole fraction of pyrope and Mg/Fe ratio from core to rim, indicating prograde garnet growth. At the maximum temperatures and the time-scales experienced by these garnets, calculated intragranular diffusion distances for oxygen are small (<5 μm), indicating that δ¹⁸O records primary growth zoning and not diffusive exchange. The oxygen isotope gradients are larger than could form due to temperature changes during closed-system mineral growth. Thus, gradients reflect the compositions of fluids infiltrating during prograde metamorphism. Values of δ¹⁸O in garnet cores range from ?1 to 15 ‰, likely preserving the composition of the eclogite protoliths. Two garnet cores from the Almenningen eclogite in the Western Gneiss Region, Norway, have δ¹⁸O ~?1 ‰ and are the first negative δ¹⁸O eclogites identified in the region. In contrast with orogenic eclogites, seven high δ¹⁸O garnets (>5 ‰) from two kimberlites are homogeneous in δ¹⁸O, possibly due to diffusive exchange, which is possible for prolonged periods at higher mantle temperatures. Homogeneity of δ¹⁸O in garnets outside the normal mantle range (5–6 ‰) may be common in kimberlitic samples.     

Apports des analyses chimiques et isotopiques à la connaissance du fonctionnement des aquifères plio-quaternaire et turonien de la zone synclinale d''Essaouira, Maroc occidental

The Essaouira synclinal zone is one of the Moroccan semi-arid zones with annual rainfalls not exceeding 300 mm yr⁻¹ and very high potential evapo-transpiration of about 920 mm yr⁻¹. This syncline with a Senonian axial zone is bordered by two diapiric structures of Triassic deposits: the Tidzi Diapir that outcrops in the east and south, and the hidden Essaouira diapir in the west, which was found by geophysics. This syncline contains two main superimposed aquifers. (i) The Plio-Quaternary aquifer consists of sands, sandstone and conglomerates and provides the main part of the water supply. This free-water table flows out towards the northwest and its surface is affected by significant piezometric variations. (ii) The calcareous dolomitic Turonian is a confined aquifer under the Senonian marls in the and in direct contact with the Plio-Quaternary. For a few years, the drinking water supply to the town of Essaouira has come from deep drillings.These two aquifers were sampled in June 1995 and in Januray 1996 after exceptional rainfalls. All waters have the same geochemical profile. The interpretation of the total dissolved solids and chloride content of Plio-Quaternary aquifers makes it possible to specify their origins. It emphasises, in particular, the source from the Ksob Wadi in the northeast and the role of the hidden Essaouira diapir. Nitrate levels were raised excessively, increasing at the same time as chloride concentrations during the rains of the winter of 1996, and underline the wells vulnerability to pastoral and domestic activities.The interpretation of O- and H-isotopes distinguishes two contrasting Plio-Quaternary and Turonian aquifers with an Atlantic origin for the rain recharge. A specific campaign was varried out in November 1996 to date water from the Turonian aquifer by ¹⁴C. Two boreholes draw water of several thousands years old.     

Petrology and geochemistry of the Huerto Andesite,San Juan volcanic field,Colorado

The Huerto Andesite is the largest of several andesite sequences interlayered with the large-volume ash-flow tuffs of the San Juan volcanic field, Colorado. Stratigraphically this andesite is between the region's largest tuff (the 27.8 Ma, 3,000 km³ Fish Canyon Tuff) and the evolved product of the Fish Canyon Tuff (the 27.4 Ma, 1,000 km³ Carpenter Ridge Tuff), and eruption was from vents located approximately 20–30 km southwest and southeast of calderas associated with these ashflow tuffs. Olivine phenocrysts are present in the more mafic, SiO₂-poor samples of andesite, hence the parent magma was most likely a mantle-derived basaltic magma. The bulk compositions of the olivine-bearing andesites compared to those containing orthopyroxene phenocrysts suggest the phenocryst assemblage equilibrated at 2–5 kbar. Two-pyroxene geothermometry yields equilibrium temperatures consistent with near-peritectic magmas at 2–5 kbar. Fractionation of phenocryst phases (olivine or orthopyroxene + clinopyroxene + plagioclase + Ti-magnetite + apatite) can explain most major and trace element variations of the andesites, although assimilation of some crustal material may explain abundances of some highly incompatible trace elements (Rb, Ba, Nb, Ta, Zr, Hf) in the most evolved lavas. Despite the great distance of the San Juan volcanic field from the inferred Oligocene destructive margin, the Huerto Andesite is similar to typical plate-margin andesites: both have relatively low abundances of Nb and Ta and similar values for trace-element ratios such as La/Yb and La/Nb.Deriving the Fish Canyon and Carpenter Ridge Tuffs by crystal fractionation from the Huerto Andesite cannot be dismissed by major-element models, although limited trace-element data indicate the tuffs may not have been derived by such direct evolution. Alternatively, heat of crystallization released as basaltic magmas evolved to andesitic compositions may have caused melting of crust to produce the felsic-ash flows. Mafic magmas may have been gravitationally trapped below lighter felsic magmas; mafic magmas which ascended to the surface probably migrated upwards around the margins of silicic chambers, as suggested by the present-day outcrops of andesitic units around the margins of recognized ash-flow calderas.     

New marine reptile fossils from the Late Jurassic of Poland with implications for vertebrate faunas palaeobiogeography

A new marine vertebrate assemblage from the Late Jurassic (late Kimmeridgian) at Krzy?anowice near I??a in the NE margin of the Holy Cross Mountains in Poland is described. This new locality is rich in fossils of coastal and pelagic reptiles. The most frequent fossils are plesiochelyid turtle shell fragments and pliosaurid skull bones and teeth. The Krzy?anowice vertebrate assemblage is similar to the Late Jurassic Boreal/Sub-Boreal localities of the Kimmeridge Clay in Great Britain and Svalbard Archipelago in the Arctic, in the presence of pliosaurids and long-necked plesiosaurids. However, plesiochelyid turtles and crocodylomorphs are similar to those from the Mediterranean/Sub-Mediterranean sites of the northern border of the Tethys Ocean, as, for example, in the Swiss Jura Mountains and Southern Germany. This unique composition of the Krzy?anowice vertebrate fauna demonstrates that, during the Late Jurassic this new locality was located in the transitional palaeobiogeographic line referred to in this paper as the “Matyja-Wierzbowski Line”. The new palaeobiogeographical reconstructions of Late Jurassic of Europe are based on the composition of the Krzy?anowice locality and other sites with similar turtle-pliosaurid faunas which formed a long-term, stable ecological sympatry in marine ecosystems of the European Archipelago.     

Environmental controls on the development of Mississippian microbial carbonate mounds and platform limestones in southern Montagne Noire (France)

Late Mississippian carbonates in southern Montagne Noire are dominantly domical to laterally‐accreted microbial mounds in some formations, as well as stratiform microbial limestones occurring in hundreds of olistoliths within a flysch basin, constituting pieces of a giant puzzle that are used to help reconstruct a platform in a region that is no longer preserved. Petrographic data of limestone samples from 14 continuous long sections of olistoliths have been analyzed statistically, using multivariate clustering (Q‐mode) of the components/matrix/cement and canonical correspondence analysis that allow the reconstruction of the environmental parameters of carbonate microbial communities in space and time. Clustering analysis separated microbial and non‐microbial facies. The calculation of indices along the various axes from canonical correspondence analysis allows recognition of the controlling factors of the mounds and microbial growth as being turbidity, light penetration, bathymetry and storms. Turbidity and light penetration are the primary factors controlling the morphology of the microbial limestones. Representation of the light penetration and bathymetry indices on the stratigraphical sections defines two vertical environmental gradients. Light penetration can be subdivided into euphotic, euphotic–dysphotic and dysphotic‐aphotic conditions. The representation of the bathymetry allows the subdivision of samples into a deeper outer ramp, external mid‐ramp and internal mid‐ramp. The curve distance from the section base = f (index) suggests a cyclicity for the platform that cannot be compared with the onlap curve defined from other cratonic areas (Moscow Basin), and thus the cyclic succession of the Montagne Noire is interpreted to have been mostly tectonically‐controlled. Integration of the data allowed the reconstruction of the original Mississippian carbonate platform, where, up to the Mikhailovian, it appears to correspond to a platform morphology, with narrow shallow water facies and wide turbiditic systems, whereas the width of shallow‐water settings expanded during the Venevian to the Protvian, forming a ramp or distally‐steepened ramp with widespread microbial limestones.     

Stratigraphy and Mesozoic–Cenozoic tectonic history of northern Sierra Los Ajos and adjacent areas,Sonora, Mexico

Geologic mapping in the northern Sierra Los Ajos reveals new stratigraphic and structural data relevant to deciphering the Mesozoic–Cenozoic tectonic evolution of the range. The northern Sierra Los Ajos is cored by Proterozoic, Cambrian, Devonian, Mississippian, and Pennsylvanian strata, equivalent respectively to the Pinal Schist, Bolsa Quartzite and Abrigo Limestone, Martin Formation, Escabrosa Limestone, and Horquilla Limestone. The Proterozoic–Paleozoic sequence is mantled by Upper Cretaceous rocks partly equivalent to the Fort Crittenden and Salero Formations in Arizona, and the Cabullona Group in Sonora, Mexico.Absence of the Upper Jurassic–Lower Cretaceous Bisbee Group below the Upper Cretaceous rocks and above the Proterozoic–Paleozoic rocks indicates that the Sierra Los Ajos was part of the Cananea high, a topographic highland during the Late Jurassic and Early Cretaceous. Deposition of Upper Cretaceous rocks directly on Paleozoic and Proterozoic rocks indicates that the Sierra Los Ajos area had subsided as part of the Laramide Cabullona basin during Late Cretaceous time. Basal beds of the Upper Cretaceous sequence are clast-supported conglomerate composed locally of basement (Paleozoic) clasts. The conglomerate represents erosion of Paleozoic basement in the Sierra Los Ajos area coincident with development of the Cabullona basin.The present-day Sierra Los Ajos reaches elevations of greater than 2600 m, and was uplifted during Tertiary basin-and-range extension. Upper Cretaceous rocks are exposed at higher elevations in the northern Sierra Los Ajos and represent an uplifted part of the inverted Cabullona basin. Tertiary uplift of the Sierra Los Ajos was largely accommodated by vertical movement along the north-to-northwest-striking Sierra Los Ajos fault zone flanking the west side of the range. This fault zone structurally controls the configuration of the headwaters of the San Pedro River basin, an important bi-national water resource in the US-Mexico border region.     

Effect of the soil–pile–structure interaction in seismic analysis: case of liquefiable soils

The design of earthquake-resistant structures depends greatly on the soil–foundation–structure interaction. This interaction is more complex in the presence of liquefiable soils. Pile and rigid inclusion systems represent a useful practice to support structures in the presence of liquefiable soils in seismic zones. Both systems increase the bearing capacity of soil and allow reducing the settlements in the structure. Numerical models with a 3-storey reinforced concrete frame founded on inclusions systems (soil–inclusion–platform–structure) and pile systems (soil–pile–structure) were analyzed. Finite difference numerical models were developed using Flac 3D. Two different soil profiles were considered. A simple constitutive model for liquefaction analysis that relates the volumetric strain increment to the cyclic shear strain amplitude was utilized to represent the behavior of the sand, and the linear elastic perfectly plastic constitutive model with a Mohr–Coulomb failure criterion was used to represent the behavior of the earth platform. Two earthquakes were used to study the influence of the different frequency of excitation in the systems. The results were presented in terms of maximum shear forces distribution in the superstructure and spectrum response of each system. The efforts and displacements in the rigid elements (piles or rigid inclusions) were compared for the different systems. The bending and buckling failure modes of the pile were examined. The results show that the pile system, the soil profile and the frequency of excitation have a great influence on the magnitude and location of efforts and displacements in the rigid elements.