Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.     

Structure-from-motion photogrammetry analysis of historical aerial photography: Determining beach volumetric change over decadal scales

Historical aerial photographs are an invaluable tool in shoreline mapping and change detection in coastal landscapes. We evaluate the extent to which structure-from-motion (SfM) photogrammetric methods can be applied to quantify volumetric changes along sandy beaches, using archival imagery. We demonstrate the application of SfM-derived digital surface models (DSMs) at East Beach and Lady Bay in southwest Victoria, Australia, using photographic datasets taken in 1969, 1977 and 1986, and compare them to LiDAR-derived DSMs acquired at both sites in 2007. The SfM approaches resulted in two entire and two partial suitable DSMs out of six datasets. Good-quality DSMs were spatially continuous with a good spread of ground control points (GCPs) near the beach at Lady Bay, whereas unsuitable DSMs were mostly restricted by poor distribution and number of GCPs in spatially segmented areas of East Beach, due to limited overlapping of images, possible poor quality of GCPs and also the propagation of errors in the derived point clouds. A volume of approximately 223 000 ± 72 000 m³ was deposited at Lady Bay between 1969 and 2007, despite minimal erosion observed near the breakwater. The partially suitable dataset of East Beach indicated that beach erosion of at least 39 m³ m⁻¹ occurred immediately to the east of the seawall after 1977. We also discuss the drawbacks and strengths of SfM approaches as a benchmark of historical erosion assessments along sandy beaches. © 2020 John Wiley & Sons, Ltd.     

High-latitude dust deposition in snow on the glaciers of James Ross Island,Antarctica

High-latitude dust (HLD) depositions on four glaciers of James Ross Island (the Ulu Peninsula) were analysed. The deposition rate on the selected glaciers varies from 11.8 to 64.0 g m⁻², which is one order of magnitude higher compared to the glaciers in Antarctica or elsewhere in the world. A strong negative relationship between the sediment amount and altitude of a sampling site was found. This is most likely caused by the higher availability of aeolian material in the atmospheric boundary layer. General southerly and south-westerly wind directions over the Ulu Peninsula – with exceptions based on local terrain configuration – help to explain the significantly lower level of sediment deposition on San Jose Glacier and the high level on Triangular Glacier. X-ray fluorescence (XRF) spectrophotometry was used to estimate the relative proportions of the main and trace (lithophile) elements in the sediment samples. Both the sediment amount and the XRF results are analysed in a depth profile at each locality and compared among the glaciers, suggesting long-range transport of fine mineral material from outside James Ross Island. The distribution of aeolian sediment among the glaciers corresponds well with the prevailing wind direction on the Ulu Peninsula. © 2020 John Wiley & Sons, Ltd.     

Field Demonstration of the Horizontal Treatment Well (HRX Well®) for Passive In Situ Remediation

The horizontal reactive media treatment well (HRX Well®) uses directionally drilled horizontal wells filled with a treatment media to induce flow-focusing behavior created by the well-to-aquifer permeability contrast to passively capture proportionally large volumes of groundwater. Groundwater is treated in situ as it flows through the HRX Well and downgradient portions of the aquifer are cleaned via elution as these zones are flushed with clean water discharging from the HRX Well. The HRX Well concept is particularly well suited for sites where long-term mass discharge control is a primary performance objective. This concept is appropriate for recalcitrant and difficult-to-treat constituents, including chlorinated solvents, per- and polyfluoroalkyl substances (PFAS), 1,4-dioxane, and metals. A full-scale HRX Well was installed and operated to treat trichloroethene (TCE) with zero valent iron (ZVI). The model-predicted enhanced flow through the HRX Well (compared to the flow in and equivalent cross-sectional area orthogonal to flow in the natural formation before HRX Well installation) and treatment zone width was consistent with flows and widths estimated independently by point velocity probe (PVP) testing, HRX Well tracer testing, and observed treatment in downgradient monitoring wells. The actual average capture zone width was estimated to be between 45 and 69 feet. Total TCE mass discharge reduction was maintained through the duration of the performance monitoring period and exceeded 99.99% (%). Decreases in TCE concentrations were observed at all four downgradient monitoring wells within the treatment zone (ranging from 50 to 74% at day 436), and the first arrival of treated water was consistent with model predictions. The field demonstration confirmed the HRX Well technology is best suited for long-term mass discharge control, can be installed under active infrastructure, requires limited ongoing operation and maintenance, and has low life cycle energy and water requirements.     

Inversion-based deblending using migration operators

In this paper, we compare the denoising- and inversion-based deblending methods using Stolt migration operators. We use Stolt operator as a kernel to efficiently compute apex-shifted hyperbolic Radon transform. Sparsity promoting transforms, such as Radon transform, can focus seismic data into a sparse model to separate signals, remove noise or interpolate missing traces. Therefore, Radon transforms are a suitable tool for either the denoising- or the inversion-based deblending methods. The denoising-based deblending treats blending interferences as random noise by sorting the data into new gathers, such as common receiver gather. In these gathers, blending interferences exhibit random structures due to the randomization of the source firing times. Alternatively, the inversion-based deblending treats blending interferences as a signal, and the transform models this signal by incorporating the blending operator to formulate an inversion problem. We compare both methods using a robust inversion algorithm with sparse regularization. Results of synthetic and field data examples show that the inversion-based deblending can produce more accurate signal separation for highly blended data.     

Morphology and dynamics of the intertidal floodplain along the Amazon tidal river

Depositional environments along the tidal river downstream of Óbidos have been proposed as important sinks for up to one third of the sediment discharge from the Amazon River. However, the morphology of the intertidal floodplain and the dynamics of sediment exchange along this reach have yet to be described. River-bank surveys in five regions along the Amazon tidal river reveal a distinct transition in bank morphology between the upper, central and lower reaches of the tidal river. The upper tidal-river floodplain is defined by prominent natural levees that control the transfer of water and sediment between the mainstem Amazon River and its floodplain. Greater tidal influence in the central tidal river suppresses levee development, and tidal currents increase sediment transport into the distal parts of the floodplain. In the lower tidal river, the floodplain morphology closely resembles marine intertidal environments (e.g. mud flats, salt marshes), with dendritic tidal channels incising elevated vegetated flats. Theory, morphology and geochronology suggest that the dynamics of sediment delivery to the intertidal floodplain of the Amazon tidal river vary along its length due to the relative influence and coupling of fluvial and tidal dynamics. © 2018 John Wiley & Sons, Ltd.     

Geochemical Atlas of the Slovak Republic at a scale of 1:1,000,000

The Geochemical Atlas of Slovak Republic (49,036 km²) at a scale of 1 : 1,000,000 was compiled during 1991–1995 together with maps of associated geochemical and ecological features at a scale of 1 :200,000. Investigations were aimed at the evaluation of concentrations and distributions of Al, As, Ba, Be, Ca, Ce, Co, Cd, Cs, Cr, Cu, Fe, Ga, Hg, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, U, V, W, Y, Zn, Zr in groundwater (16,359 samples), stream sediments (24,422 samples), rocks (3839 samples), soils (9892 samples from 4946 profiles; A and C horizons of each profile were sampled) and forest biomass (the foliage of the forest tree species from 3063 plots was sampled). In groundwater field measurements of temperature, pH, conductivity, dissolved O₂, acidity, alkalinity were done. The evaluation was oriented to the natural radioactivity of the Slovak territory as follows: rocks (K, U, Th, U_tot and dose rate, 15,573 reference spectrometric points), radon risk and water (U_nat, ²²⁶Ra, ²²²Rn; 5271 samples). The main objective of the Geochemical Atlas was to construct single-component maps showing concentrations of chemical elements, compounds and measured parameters in the researched media of Slovakia at a scale of 1 : 1,000.000 and to create interactive databases of chemical composition and/or measured parameters of groundwater, biomass, rocks, soils, stream sediments and natural radioactivity, for the entire territory of the Slovak Republic. The single-component maps are not constructed in the part ‘Rocks’, where all the main rocks types of Slovakia are presented in the ‘Map of lithogeochemical rock types of Slovakia at a scale of 1: 500,000’. The edition of six atlases has been planned. In 1997 the first three atlases will appear (Groundwater, Biomass, Natural Radioactivity). Publishing of last three atlases (Rocks, Soils, Stream Sediments) is planned for 1998. Since the analytical works on stream sediments were finished during 1997, it was not possible to present here the results of that part of the Geochemical Atlas.     

Colloid particle sizes in the Mississippi River and some of its tributaries,from Minneapolis to below New Orleans

An on-board technique was developed that combined discharge-weighted pumping to a high-speed continuous-flow centrifuge for isolation of the particulate-sized material with ultrafiltration for isolation of colloid-sized material. In order to address whether these processes changed the particle sizes during isolation, samples of particles in suspension were collected at various steps in the isolation process to evaluate changes in particle size. Particle sizes were determined using laser light-scattering photon correlation spectroscopy and indicated no change in size during the colloid isolation process. Mississippi River colloid particle sizes from twelve sites from Minneapolis to below New Orleans were compared with sizes from four tributaries and three seasons, and from predominantly autochthonous sources upstream to more allochthonous sources downstream. © 1998 John Wiley & Sons, Ltd.     

Interpretation of shear strength uncertainty and reliability analyses of slopes

The variance of the friction angle or friction coefficient (tan ?) is often considered in geotechnical reliability analyses, which implies that the variance of the shear strength as defined by a Mohr-Coulomb envelope increases as the normal stress on the shearing surface increases. However, shear strength data sometimes has approximately constant variance, and most simple regression techniques assume constant variance. Four effective stress shear strength data sets are evaluated using both the constant variance (homoscedastic) and constant coefficient of variation (heteroscedastic) interpretations. The impact of the variance interpretation on slope stability is evaluated using infinite slope, homogeneous dam, and zoned dam examples. For relatively shallow infinite slope surfaces, the reliability index for the heteroscedastic interpretation of shear strength variance was about twice the reliability index obtained using the homoscedastic approach. In the dam examples, the difference in the reliability indices resulting from the heteroscedastic and homoscedastic interpretations was about one, indicating a tenfold increase in the probability of failure. The typical assumption of constant coefficient of variation of shear strength may result in unconservative estimates of the reliability of shallow failure surfaces and overly conservative results for deeper failure surfaces.     

Sedimentary roles on hyporheic exchange in karst conduits at low Reynolds numbers by laboratory experiments

Hydrogeology Journal - The relative roles of the sediment grain size/permeability, conduit flow rate and conduit geometry/angle on the hyporheic exchange between a karst conduit and its underlying...