<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural sinhalites

Natural sinhalites, MgAlBO_4, from the Ratnapura District, Sri Lanka, and from Bodnar Quarry near Hamburg, Sussex Co., New Jersey, USA, have been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine the oxidation state and site occupancy of iron in the sinhalite structure. The samples contain about 3.35 and 1.46 wt% of total iron oxide, respectively. The structure refinement is successful and reproduces the total iron content provided that the substitution of Mg²⁺ by Fe²⁺ on the M2 position only is assumed. The ⁵⁷Fe Mössbauer spectra at 77, 293, 573 and 773 K can be resolved into two doublets with hyperfine parameters common for octahedrally coordinated high-spin Fe²⁺. There is no evidence for iron in the tetrahedral site. Electronic structure calculations in local spin density approximation yield hyperfine parameters for Fe²⁺ on the M2-site at 0, 293, 573 and 773 K in quantitative agreement with experiments. Calculated spectroscopic properties for Fe²⁺ on the M1-site are at variance with the experimental data and, thus, indicate that substitution of Al³⁺ by Fe²⁺, if occurring at all, must be accompanied by considerable local expansion and distortion of the M1-octahedron.     

花岗岩型铀矿勘查中航放信息的提取与综合

采取线性与非线性的航放信息提取方法相结合的方式,对桃山地区的航空放射性测量数据进行了处理,在很大程度上有效地提取出与花岗岩型铀矿化密切相关的航放异常信息,建立了花岗岩型铀矿的航放找矿标志,并运用成矿有利度法完成了该区铀成矿潜力评价。已知铀矿含矿单元的正判率达86.4%,表明所建立的找矿标志及评价模型可靠,可用于未知区的铀成矿远景预测。     

A sedimentary facies model for glacial-age sediments in Baldwin Lake, Southern California

A combined sedimentological and high-resolution petrographic analysis was conducted on a glacial-age (20,000–65,000 cal yr BP) sediment core from Baldwin Lake, Southern California. The results of this research represent the most complete glacial-age, terrestrial climate record from Southern California to date. These results are used to characterize the different sediment types and to investigate the difference in depositional processes and environments between the core's three predominant sediment types: massive, semi-laminated, and laminated sediments. Massive sediments are commonly associated with a blocky texture and/or desiccation cracks, are organic-poor, have high magnetic susceptibility values, and are coarser-grained. Thin-sections from massive sediments reveal a homogenous sediment fabric. Sub-centimeter-scale laminated and centimeter-scale semi-laminated sediments are generally organic-rich, have low magnetic susceptibility values, and are finer grained. Thin-sections from laminated and semi-laminated sediments reveal diffuse sub-millimeter- to millimeter-scale laminae. This combination of sedimentological and high-resolution petrographic data enabled us to characterize four sediment facies, each related to specific depositional processes and environments: (1) a playa lake; (2) a perennial shallow lake; (3) an intermediate lake with variable lake level; and, (4) a perennial deep lake. At centennial-to millennial-timescales, lower lake levels are represented by deposition of massive to semi-laminated sediments in a playa to a perennial shallow lake environment. At similar timescales, higher lake levels are recorded by semi-laminated to laminated sediments deposited in an intermediate lake to a perennial deep lake environment. These results provide an additional sedimentological study for comparison to similar arid environment basins, and for comparison to existing regional paleoclimatic reconstructions.     

The influence of shallow landslides on sediment supply: A flume-based investigation using sandy soil

The impact of rainfall-induced shallow landslides on hillslope sediment discharge is not well understood. This paper reports experimental measurements of sediment discharge after water-induced shallow landslides are triggered on sandy soil in a flume under simulated rainfall. The principal aim of the research was to investigate how varying soil depth affects the location and occurrence of shallow slope failures, as well as how it affects sediment yields downslope. Four experiments were conducted using the same sandy soil and a 30° and 10° compound slope configuration under average rainfall intensity of 50 mm h^− 1 for up to 390 min. Soil depths were set to 200, 300, 400 and 500 mm. Engineering and geotechnical properties of the soil were examined. Sediment discharge and runoff were collected from the flume outlet at 15 minute intervals. Changes in the soil slope profiles after landslides and soil physical properties resulted from soil armouring, under continuous rainfall were also recorded. Results showed that sediment yields at the flume outlet, before landslides occurred, were very low and limited to the finer soil particles as would be expected for a sandy soil. However subsequent variations in sediment discharge were strongly related to failure events and their proximity to the outlet. Sediment yield was also affected by the original soil depth; the greater the depth, the higher the sediment yields. Post-failure reductions in sediment discharge were observed and attributed to post-failure slope stabilization under continuing rainfall and extensive soil armouring near the flume outlet. The results provide a clear linkage between landslides and sediment discharge due to hydrological processes occurring in the hillslope. This knowledge is being used to develop a model to predict sediment discharges from hillslopes following shallow landslide events.     

城市污水处理厂地下水环境影响评价技术方法

本次以池南区污水处理厂为研究对象,通过分析其水文地质条件,结合建立的水文地质概念模型和地下水流数值模型,运用MODFLOW对池南区污水处理厂地下水水流及水质的影响进行模拟预测,从而针对可能产生的不利影响提出保护措施。     

北海涠洲岛珊瑚多色性分布规律初步研究

正涠洲岛位于北部湾中部(中国新闻网,2015),属亚热带季风气候,远离大陆,海水清洁,广泛发育珊瑚礁群落(王欣等,2009)。涠洲岛具有丰富多彩的海蚀、海积与海滩地貌(北海涠洲岛网,2015)。作者于2018年3月1日～3月4日赴涠洲岛进行为期4天的调研工作,通过观察发现,海滩砂主要由珊瑚和贝壳碎屑构成,珊瑚碎块大量呈白色,但也见有少量的灰色、粉色等,本文探究不同颜色     

黄河冲积层静止土压力系数原位测定与分析

静止土压力系数K0与其他物理力学性质相互制约,变化特征复杂,加之试验条件、理论假设条件不同,表达形式多样,结果迥异。依托济南地铁工程勘察,采用原位土体水平压力测定仪（KSB）对济南西北部黄河厚冲积层现场测试,将测试结果与原位旁压试验、室内侧压力仪K0试验结果,以及考虑黏性土内摩擦角、塑性指数的K0计算公式进行对比,分析表明：KSB测试结果以指数形式插值推算原位静止土压力系数更优;20 m深度范围内黄河冲积层黏性土可近似为正常固结饱和状态,K0介于0.4～0.7之间并随埋深减小,而Jaky公式计算值偏高,室内土工试验K0值偏低;以固结快剪内摩擦角 或等效内摩擦角 修正Jaky公式的计算结果更接近KSB实测值。     

土体电阻率与导热系数的相关性实验研究

将南京下蜀土与中砂以不同比例混合,配制了四种土样,利用室内四极法分别测试了每种土样在不同含水率条件下 的电阻率,发现随含水率和黏土颗粒含量的增加,土体电阻率减小;同时,采用DRE导热系数测试仪测试了每个试样的导 热系数,发现随含水率和砂含量的增高,导热系数增大。已有研究表明,土的电阻率与导热系数均与土体饱和度及孔隙率 等物理性质有关。通过将土的电阻率与导热系数进行拟合,发现两者符合指数关系,并建立了表征电阻率与导热系数相关 性的数学模型。该文研究结果为利用现场实测的电阻率指标间接求取土体的导热系数提供了依据。     

川北下寒武统仙女洞组台缘斜坡碳酸盐岩重力流沉积

基于重力流剖面的野外观察、露头解剖及镜下鉴定等分析手段,对四川盆地北部下寒武统仙女洞组台缘斜坡碳酸盐 岩重力流沉积及发育机制进行了研究。研究区位于仙女洞组,主要沉积粉砂质泥岩、生屑泥晶灰岩、藻灰岩等3种岩石类 型;根据层面上产出形态的不同,将该区碳酸盐岩重力流沉积分为似瘤状碳酸盐岩重力流沉积和角砾型碳酸盐岩重力流沉 积2类。结合露头区重力流沉积物粒度及岩性变化,将碳酸盐岩重力流沉积由下至上划分出5个发育期次,期次内部重力流 沉积物由细变粗,纵向上呈现出明显的叠置关系,与仙女洞组时期所经历的海退环境大致吻合。地震、风暴浪等触发机制 导致台缘斜坡上部松散沉积的灰泥丘块体发生破碎并沿斜坡发生滑塌,伴随水体注入,大块砾石在沉积物-水体混合的环 境中发生破碎搅动,形成大小不等的块体,深水底流等作用对未固结或弱固结的砾屑灰岩进行溶蚀、改造,最终形成了层 面形态特征不同的2类似瘤状碳酸盐岩重力流沉积。角砾型碳酸盐岩重力流沉积则主要是未破碎的巨型灰泥丘块体经搬运 和短距离滑塌,最终与似瘤状砾屑灰岩共同沉积而成。     

北京通州某改造区土壤中PAHs的来源分析及风险评价

近些年,随着我国城市化进程不断加快,土壤中多环芳烃污染已经成为威胁土壤环境质量和人体健康的主要因素。文章采集了北京市通州某改造区15件表层土壤（0~20 cm）样品,利用GC-MS分析技术,研究了土壤中美国环境保护署（USEPA）优控的16种多环芳烃（PAHs）的含量及组分特征,根据多环芳烃的空间分布特征和特定成分之间的浓度比值结合多元统计法分析了其污染来源,初步评价了其污染水平,并进行健康风险评价。结果表明:表层土壤中16种多环芳烃含量范围为6.57~8 307.2 μg/kg,均值为1 004.08 μg/kg。多环芳烃组分特征及Fla与（Fla+Pyr）、BaA与(BaA+Chr)的相对质量比值特征显示改造区是燃煤和汽车尾气混合型来源;多元统计后发现石油烃类污染源和化石燃料燃烧源是两种主要成分。最后参照《污染场地风险评估技术导则（HJ 25.3—2014）》对土壤中PAHs进行了健康风险评价,除苯并（a）芘（BaP）致癌风险值略偏高不可接受外,其余致癌与非致癌风险值均可接受。