Monin–Obukhov similarity functions for the structure parameters of temperature and humidity are needed to derive surface heat and water vapour fluxes from scintillometer measurements and it is often assumed that the two functions are identical in the atmospheric surface layer. Nevertheless, this assumption has not yet been verified experimentally. This study investigates the dissimilarity between the turbulent transport of sensible heat and water vapour, with a specific focus on the difference between the Monin–Obukhov similarity functions for the structure parameters. Using two datasets collected over homogeneous surfaces where the surface sources of sensible heat and water vapour are well correlated, we observe that under stable and very unstable conditions, the two functions are similar. This similarity however breaks down under weakly unstable conditions; in that regime, the absolute values of the correlations between temperature and humidity are also observed to be low, most likely due to large-scale eddies that transport unsteadiness, advection or entrainment effects from the outer layer. We analyze and demonstrate how this reduction in the correlation leads to dissimilarity between the turbulent transport of these two scalars and the corresponding Monin–Obukhov similarity functions for their structure parameters. A model to derive sensible and latent heat fluxes from structure parameters without measuring the friction velocity is tested and found to work very well under moderately to strongly unstable conditions (−z/L > 0.5). Finally, we discuss the modelling of the cross-structure parameter over wet surfaces, which is crucial for correcting water vapour effects on optical scintillometer measurements and also for obtaining surface sensible and latent heat fluxes from the two-wavelength scintillometry. 相似文献
The mechanical property of frozen saline sandy soil is complicated due to its complex components and sensitivity to salt content and confining pressure. Thus, a series of triaxial compression tests were carried out on sandy samples with different Na2SO4 contents under different confining pressures to explore the effects of particle breakage, pressure melting, shear dilation and strain softening or hardening. The test results indicate that the stress–strain curves exhibit strain softening/hardening phenomena when the confining pressures are below or above 6 MPa, respectively. A shear dilation phenomenon was observed in the loading process. With increasing confining pressure, the strength firstly increases and then decreases. By taking into consideration the changes between the grain size distributions before and after triaxial compression tests, a failure strength line incorporating the influences of both particle breakage and pressure melting is proposed. In order to describe the deformation characteristics of frozen saline sandy soil, an elastoplastic incremental constitutive model is established based on the test results. The proposed model considers the plastic compressive, plastic shear and breakage mechanisms by adopting the non-associated flow rule. The breakage mechanism can be reflected by an index related to the initial, current and ultimate grain size distributions. The hardening parameters corresponding to compressive and shear mechanisms consider the influence of particle breakage. Then the effect of particle breakage on both the stress–strain and volumetric strain curves is analyzed. The calculated results fit well with the test results, indicating that the developed constitutive model can well describe the mechanical and deformation features of frozen saline sandy soil under various stress levels and stress paths. In addition, the strain softening/hardening, contraction, high dilation and particle breakage can be well captured.
Acta Geotechnica - This paper studies the dilative behavior of clay during drained creep along triaxial tests under constant mean effective stress, where the volumetric strain is caused by the sole... 相似文献
Natural sinhalites, MgAlBO4, from the Ratnapura District, Sri Lanka, and from Bodnar Quarry near Hamburg, Sussex Co., New Jersey, USA, have been characterized by 57Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine the oxidation state and site occupancy of iron in the sinhalite structure. The samples contain about 3.35 and 1.46 wt% of total iron oxide, respectively. The structure refinement is successful and reproduces the total iron content provided that the substitution of Mg2+ by Fe2+ on the M2 position only is assumed. The 57Fe Mössbauer spectra at 77, 293, 573 and 773 K can be resolved into two doublets with hyperfine parameters common for octahedrally coordinated high-spin Fe2+. There is no evidence for iron in the tetrahedral site. Electronic structure calculations in local spin density approximation yield hyperfine parameters for Fe2+ on the M2-site at 0, 293, 573 and 773 K in quantitative agreement with experiments. Calculated spectroscopic properties for Fe2+ on the M1-site are at variance with the experimental data and, thus, indicate that substitution of Al3+ by Fe2+, if occurring at all, must be accompanied by considerable local expansion and distortion of the M1-octahedron. 相似文献