Full 3D MHD calculations of accretion flow structure in magnetic cataclysmic variables with strong,complex magnetic fields

We have performed three-dimensional magnetohydrodynamical calculations of stream accretion in cataclysmic variable stars for which the white dwarf primary possesses a strong, complex magnetic field. These calculations were motivated by observations of polars: cataclysmic variables containing white dwarfs with magnetic fields sufficiently strong to prevent the formation of an accretion disk. In this case, an accretion stream flows from the L1 point and impacts directly onto one or more spots on the surface of the white dwarf. Observations indicate that the white dwarfs in some binaries possess complex (non-dipolar) magnetic fields. We performed simulations of ten polars, with the only variable being the azimuthal angle of the secondary with respect to the white dwarf. These calculations are also applicable to asynchronous polars, where the spin period of the white dwarf differs by a few percent from the orbital period. Our results are equivalent to calculating the structure of one asynchronous polar at ten different spin-orbit beat phases. Our models have an aligned dipolar plus quadrupolar magnetic field centered on the whitedwarf primary. We find that, with a sufficiently strong quadrupolar component, an accretion spot arises near the magnetic equator for slightly less than half our simulations, while a polar accretion zone is active for most of the remaining simulations. For two configurations, accretion at a dominant polar region and in an equatorial zone occurs simultaneously. Most polar studies assume that the magnetic field is dipolar, especially for single-pole accretors. We demonstrate that, with the orbital parameters and magnetic-field strengths typical of polars, the accretion flow patterns can vary widely in the case of a complex magnetic field. This may make it difficult formany polars to determine observationally whether the field is pure dipolar or is more complex, but there shoulid be indications for some systems. In particular, a complex magnetic field should be suspected if there is an accretion zone near the white dwarf’s equator (assumed to be in the orbital plane) or if there are two or more accretion regions that cannot be fitted by dipolar magnetic field. Magnetic-field constraints are expected to be substantially stronger for asynchronous polars, with clearer signs of complex field geometry due to changes in the accretion flow structure as a function of azimuthal angle. These indications become clearer in asynchronous polars because each azimuthal angle corresponds to a different spin-orbit beat phase.     

Phosphate defects and apatite inclusions in coral skeletal aragonite revealed by solid-state NMR spectroscopy

Recent development of paleo-nutrient proxies based on the phosphorus/calcium (P/Ca) ratio in tropical- and deep-water corals (also known as cold-water corals) require an understanding of the processes by which P is incorporated into the coral skeletal aragonite. Here, we apply single- and double-resonance solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the speciation of P in coral aragonite. The results show that the majority of P occurs as phosphate defects in the aragonite structure, but in many samples a significant fraction of the P occurs also in crystalline hydroxylapatite inclusions. Quantification of the amount of hydroxylapatite indicates that its presence is not related simply to external environmental factors and that it can occur at varying abundances in different parts of the same corallite. Since there is currently no model available to describe the relationship between dissolved inorganic phosphate and its incorporation as apatite inclusions into carbonates, careful screening of samples which contain only phosphate in the aragonite structure or selective microsampling could improve proxy development.     

An Acetic Acid‐Based Extraction Protocol for the Recovery of U,Th and Pb from Calcium Carbonates for U‐(Th)‐Pb Geochronology

A new method for the simultaneous recovery of U, Th and Pb from ca. 0.5 g calcium carbonate samples for the purpose of U‐(Th)‐Pb geochronometry is presented. The protocol employs ion‐exchange chromatography. Standard anion exchange resin (AG 1‐X8 100–200 mesh) was used as the static phase, and 90% acetic acid was used as the mobile phase to elute the unwanted matrix components; dilute nitric acid was used to elute the U, Th and Pb. Blanks of 1.8 pg Th, 6.4 pg Pb and 8.4 pg U were obtained. The protocol was evaluated by determining the isotopic composition of U‐Th‐Pb separates obtained from an in‐house reference material (prepared from a natural speleothem) by MC‐ICP‐MS. An independently dated speleothem was also reanalysed. Based on these tests, the extraction protocol had an acceptable blank and produced a Pb separate sufficiently free of matrix‐induced instrumental biases to be appropriate for U‐Th‐Pb chronology.     

Optically stimulated luminescence dating of aeolian sand in the Otindag dune field and Holocene climate change

The dune system in Otindag sand field of northern China is sensitive to climate change, where effective moisture and related vegetation cover play a controlling role for dune activity and stability. Therefore, aeolian deposits may be an archive of past environmental changes, possibly at the millennial scale, but previous studies on this topic have rarely been reported. In this study, thirty-five optically stimulated luminescence (OSL) ages of ten representative sand-paleosol profiles in Otindag sand field are ob-tained, and these ages provide a relatively complete and well-dated chronology for wet and dry varia-tions in Holocene. The results indicate that widespread dune mobilization occurred from 9.9 to 8.2 ka, suggesting a dry early Holocene climate. The dunes were mainly stabilized between 8.0 and 2.7 ka, implying a relatively wet climate, although there were short-term penetrations of dune activity during this wet period. After ~2.3 ka, the region became dry again, as inferred from widespread dune activity. The "8.2 ka" cold event and the Little Ice Age climatic deterioration are detected on the basis of the dune records and OSL ages. During the Medieval Warm Period and the Sui-Tang Warm Period (570-770 AD), climate in Otindag sand field was relatively humid and the vegetation was denser, and the sand dunes were stabilized again. These aeolian records may indicate climate changes at millennial time scale during Holocene, and these climatic changes may be the teleconnection to the climate changes elsewhere in the world.     

The effect of annealing on the luminescence decay-time of synthetic calcite:Mn

Calcite was synthesized by four methods, and the luminescence decay-time was measured for nine samples before and after heating hydrothermally in the temperature range 200–400°C. Decay-time data were collected between room temperature and approximately 15 K. The decay time at room temperature is approximately 50 ms, with little difference between a given calcite before and after hydrothermal treatment. The decay time at 15 K is always greater than at room temperature as the effect of thermal quenching diminishes. Differences in decay time before and after heating are more apparent at low temperature owing to this reduction in thermal quenching. The decay time decreased significantly in two samples, and an increase in decay time was observed in the remaining seven samples following heating. Among the latter group, the change in decay time was insignificant in three samples. The results are compared with previous data in which it was shown that the effect of heating is to increase the intensity of luminescence.     

Mapping hydrothermal alteration in the Comstock mining district,Nevada, using simulated satellite‐borne hyperspectral data

Hydrothermal alteration mapping with spaceborne hyperspectral data was simulated in the Comstock mining district, Nevada in order to evaluate the mineral mapping capabilities of the proposed Australian Resource Information and Environment Satellite (ARIES‐1). As a result, a suite of hydrothermal alteration minerals, including kaolinite, dickite, illite, chlorite, alunite and carbonate was identified from the simulated data in the 0.4–2.5 μm wavelength region and their areal abundance variations mapped accordingly. The recognised alteration zoning shows a major change in alteration assemblages across the Comstock and Silver City Faults, and a gradual variation from north to south along the faults. In the bleached Miocene volcanic rocks, dickite, kaolinite, illite and alunite were recognised. Coexistence of dickite of relatively high temperature, high‐crystallinity kaolinite of medium temperature and low‐crystallinity kaolinite of low temperature suggests supergene processes overprinting earlier hypogene alteration. The bleached rocks probably represent hydrothermal alteration in the fluid up‐flow zones in the central and shallower parts of the hydrothermal system. Illite in the bleached zones is characterised by relatively short AI–OH band wavelengths (2190–2200 nm), indicating no or very low Fe and/or Mg contents. Fault‐controlled propylitic alteration is mapped in the central part of the district mainly in the footwall of the Comstock Fault. The associated illite is characterised mainly by medium AI–OH band wavelengths (2200–2208 nm). This propylitic alteration may be contemporaneous with Au–Ag mineralisation. Additional and more extensive propylitic zones, containing illite with long AI–OH band wavelengths (2204–2216 nm), were mapped in the southern part of the district. These zones resulted from either a pre‐mineralisation propylitic alteration, or the peripheral hydrothermal alteration in the fluid down‐flow zones of the Miocene hydrothermal system.     

Preparation and Measurement of Cassiterite for Sn Isotope Analysis

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.     

Summer temperature variability across four urban neighborhoods in Knoxville,Tennessee, USA

The urban heat island (UHI) is a well-documented effect of urbanization on local climate, identified by higher temperatures compared to surrounding areas, especially at night and during the warm season. The details of a UHI are city-specific, and microclimates may even exist within a given city. Thus, investigating the spatiotemporal variability of a city’s UHI is an ongoing and critical research need. We deploy ten weather stations across Knoxville, Tennessee, to analyze the city’s UHI and its differential impacts across urban neighborhoods: two each in four neighborhoods, one in more dense tree cover and one in less dense tree cover, and one each in downtown Knoxville and Ijams Nature Center that serve as control locations. Three months of temperature data (beginning 2 July 2014) are analyzed using paired-sample t tests and a three-way analysis of variance. Major findings include the following: (1) Within a given neighborhood, tree cover helps negate daytime heat (resulting in up to 1.19 ^°C lower maximum temperature), but does not have as large of an influence on minimum temperature; (2) largest temperature differences between neighborhoods occur during the day (0.38–1.16 ^°C difference), but larger differences between neighborhoods and the downtown control occur at night (1.04–1.88 ^°C difference); (3) presiding weather (i.e., air mass type) has a significant, consistent impact on the temperature in a given city, and lacks the differential impacts found at a larger-scale in previous studies; (4) distance from city center does not impact temperature as much as land use factors. This is a preliminary step towards informing local planning with a scientific understanding of how mitigation strategies may help minimize the UHI and reduce the effects of extreme weather on public health and well-being.     

A verification framework for interannual-to-decadal predictions experiments

Decadal predictions have a high profile in the climate science community and beyond, yet very little is known about their skill. Nor is there any agreed protocol for estimating their skill. This paper proposes a sound and coordinated framework for verification of decadal hindcast experiments. The framework is illustrated for decadal hindcasts tailored to meet the requirements and specifications of CMIP5 (Coupled Model Intercomparison Project phase 5). The chosen metrics address key questions about the information content in initialized decadal hindcasts. These questions are: (1) Do the initial conditions in the hindcasts lead to more accurate predictions of the climate, compared to un-initialized climate change projections? and (2) Is the prediction model’s ensemble spread an appropriate representation of forecast uncertainty on average? The first question is addressed through deterministic metrics that compare the initialized and uninitialized hindcasts. The second question is addressed through a probabilistic metric applied to the initialized hindcasts and comparing different ways to ascribe forecast uncertainty. Verification is advocated at smoothed regional scales that can illuminate broad areas of predictability, as well as at the grid scale, since many users of the decadal prediction experiments who feed the climate data into applications or decision models will use the data at grid scale, or downscale it to even higher resolution. An overall statement on skill of CMIP5 decadal hindcasts is not the aim of this paper. The results presented are only illustrative of the framework, which would enable such studies. However, broad conclusions that are beginning to emerge from the CMIP5 results include (1) Most predictability at the interannual-to-decadal scale, relative to climatological averages, comes from external forcing, particularly for temperature; (2) though moderate, additional skill is added by the initial conditions over what is imparted by external forcing alone; however, the impact of initialization may result in overall worse predictions in some regions than provided by uninitialized climate change projections; (3) limited hindcast records and the dearth of climate-quality observational data impede our ability to quantify expected skill as well as model biases; and (4) as is common to seasonal-to-interannual model predictions, the spread of the ensemble members is not necessarily a good representation of forecast uncertainty. The authors recommend that this framework be adopted to serve as a starting point to compare prediction quality across prediction systems. The framework can provide a baseline against which future improvements can be quantified. The framework also provides guidance on the use of these model predictions, which differ in fundamental ways from the climate change projections that much of the community has become familiar with, including adjustment of mean and conditional biases, and consideration of how to best approach forecast uncertainty.