Effects of oilfield brine effluent on sediments and benthic organisms in trinity bay,Texas

Field studies have established the concentrations of naphthalenes in bay sediments and water in the vicinity of an oil separator platform and their effects on the benthic fauna. Fifteen stations were occupied monthly, from July, 1974 to December, 1975, along three transects extending from the separator platform outfall outwards for a distance of 4·0 to 5·6 km. A lesser number of stations were occupied from April, 1974 to June, 1974. Bottom sediments at each station were analysed for total naphthalenes content and for number of species and individuals. All stations were located in 2 to 3 m of water. The outfall was located 1 m off the bay bottom.There was a definite correlation between sediment naphthalenes concentration and number of species and individuals. As expected, the first station, located 15 m from the outfall, had the highest concentration of naphthalenes of all stations sampled. The naphthalenes levels dropped sharply from the outfall to the stations located 75 m from the platform where levels were about 20–50% of those found 15 m from the outfall. Naphthalenes concentrations then decreased gradually to near background levels at stations farther out. Hydrocarbon concentrations in bottom water 15 m from the outfall were three orders of magnitude lower than those in the full strength effluent, but sediments 15 m from the outfall had hydrocarbon concentrations four times as great as in the full strength effluent. There were approximately four orders of magnitude more hydrocarbons in the sediment than in the overlying water.The bay bottom was almost completely devoid of organisms within 15 m of the effluent outfall. Stations located 150 m from the outfall had severely depressed benthic faunas but not to the extent of stations nearer the outfall. Stations located 455 m from the platform were unaffected. Both numbers of species and individuals increased with distance from the platform and reached a peak at the first station medial to the control on each transect (685 to 1675 m from the platform) and then dropped at the control station. Physical environmental factors such as temperature, salinity, water depth and sediment type were essentially the same at all stations.The temporary use of a second outfall located 275 m from the main platform outfall resulted in a rapid build up of naphthalenes in surrounding sediments which persisted for at least six months following the termination of use of the second outfall. The benthic fauna was also severely depressed in the vicinity of the second outfall. The use of multiple outfalls, located some distance apart, appears to be more harmful than the use of a single outfall.Trinity Bay, Texas, the site of this investigation, has a mean depth of 2·5 m. The bay water is highly turbid due to the presence of a high concentration of clay-sized particulate material. The brine outfall was located approximately 1 m above the bay bottom. These special conditions undoubtedly contributed significantly to the observed impact of the brine. Therefore, extrapolations from the results of this study to offshore oil production and brine disposal should be made with extreme caution.     

Source spectra and RMS acceleration of Mexican subduction zone earthquakes

Strong motion (SM) data of six Mexican subduction zone earthquakes (6.4M _S8.1) recorded near the epicentral zone are analyzed to estimate their far-field source acceleration spectra at higher frequencies (f0.3 Hz). Apart from the usual corrections such as geometrical spreading (1/R), average radiation pattern (0.6), free surface amplification (a factor of 2), and equal partitioning of the energy into two orthogonal horizontal components (a factor of 1/ ), the observed spectra are corrected for a frequency dependentQ(Q=100f), a site dependent filter (e ^–kf ), and amplification ofS waves near the surface (a factor of about 2 atf2Hz). We takeR as the average distance from the rupture area to the site. If we model the high frequency plateau (f1 Hz) of the source spectra, by a point source ^–2-model, and interpret them in terms of Brune's model we obtain between 50 and 100 bars for all earthquakes. The low-frequency broadband teleseismicP wave spectra, corrected witht ^*=1.0 s, agrees within a factor of two with SM source spectra near 1 Hz. The ^–2-model is inadequate to explain the observed source spectra in a broad frequency range; these resemble spectra given byGusev (1983) with some differences.SM source acceleration spectra require significant corrections to explain observed spectra and RMS acceleration (a_rms) (a) at farther coastal sites for extended sources due to directivity effect and (b) at inland sites (100R200 km) because of unaccounted path and site amplification and/or invalidity of body-wave approximation. The observed spectra and a_rms at these sites are significantly greater than the predicted values from the estimated source spectra.     

Omphacite breakdown reactions and relation to eclogite exhumation rates

Clinopyroxene + plagioclase (±Hbl ± Qtz) symplectites after omphacite are widely cited as evidence for prior eclogite-facies or high-pressure (HP) metamorphism. Precursor omphacite compositions of retrograde eclogites, used for reconstructing retrograde P–T paths, are commonly estimated by reintegrating symplectite phases with the assumption that the symplectite-forming reactions were isochemical. Comparisons of broadbeam symplectite compositions to adjacent unreacted pyroxene from various symplectites after clinopyroxene from the Appalachian Blue Ridge (ABR) and Western Gneiss Region (WGR) suggest that the symplectite forming reactions are largely isochemical. Endmember calculations based on reintegrated symplectite compositions from the ABR and WGR suggest that a minor Ca-Eskola (CaEs) component (X_CaEs = 0.04–0.15) was present in precursor HP clinopyroxene. WGR symplectites consist of fine-grained (∼1 μm-scale), vermicular intergrowths of Pl + Cpx II ± Hbl that occur at grain boundaries or internally. ABR symplectites contain coarser (∼10 μm-scale) planar lamellae and rods of Pl + Cpx II + Qtz + Hbl within clinopyroxene cores. The contrasting textures correlate with decompression and cooling rate, and degree of overstepping of the retrograde reaction (lamellar: slow, erosionally controlled exhumation with slow/low overstepping; fine-grained, grainboundary symplectite: rapid, tectonic exhumation with rapid/high overstepping). Variations in X_CaEs, X_jd, and X_CaTs of precursor HP omphacite are related to the symplectic mineral assemblages that result from decompression. Quartz-normative symplectities indicate quartz-producing retrograde reactions (e.g., breakdown of precursor CaEs); quartz-free symplectities (e.g., diopside + plagioclase after omphacite) indicate quartz-consuming reactions (jd, CaTs breakdown) outpaced quartz-producing reactions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Using a remote sensing field experiment to investigate flux-footprint relations and flux sampling distributions for tower and aircraft-based observations

During a remote sensing field experiment conducted in the Southern Great Plains in 1997 (SGP97), tower and aircraft-based flux observations were collected over one of the main study sites in central Oklahoma. This is an agricultural region and contains primarily grassland/pasture and winter wheat, which was recently harvested leaving a significant number of fields either as wheat stubble or plowed bare soil. Multi-spectral data obtained by aircraft provided high-resolution (30 m) spatially-distributed vegetation cover and surface temperature information over the study area. The spatial variations in these surface states strongly affect the partitioning of surface fluxes between sensible and latent heat. These data, together with coarser resolution (5 km) satellite data, are used in a remote sensing-based energy balance modeling system that disaggregates flux estimates from 5 km to 30-m resolution. The resulting high-resolution flux maps provide a means for evaluating whether tower and aircraft-based flux measurements sample a full range in flux conditions for this landscape. In addition, this remote sensing-based modeling system can be used to investigate the influence of variability in these key surface states on tower and aircraft measurements through flux-footprint modeling. Under the light wind and unstable conditions that existed during the observations, highest correlation between aircraft and modeled estimated heat and water vapor fluxes were obtained using different flux-footprint estimates. More specifically, the source area for heat was estimated to be much closer to the aircraft flight line than for water vapor.     

Look again

Don Anderson argues that there is abundant evidence against the plume hypothesis, for an objective eye to consider.     

Spatial Simulation and Fuzzy Threshold Analyses for Allocating Restoration Areas

This paper presents a methodology for the evaluation of land condition and for the allocation of areas requiring restoration. It is based on spatial simulation analysis and fuzzy logic. The method is demonstrated in a restoration allocation problem within a military training area in Texas. Fuzzy logic is integrated with spatial analysis through Geographic Information Systems (GIS) to make land condition assessment geographically specific. Two sources of uncertainty in Land Condition Analysis are considered in this paper. First is the uncertainty due to incomplete information on land condition. Second is the uncertainty emanating from identifying the condition of a particular parcel of land. The first is addressed by using sequential Gaussian simulation, a geostatistical tool. Erosion status is selected as the land condition factor, and uncertainty associated with it is considered in this study. Land allocation is based on fuzzy logic to reflect the continuous transition between different land conditions and the minimization of loss that is expected to occur in the case of misallocation. Various forms of loss functions are used for allocating areas in need of restoration. An important result of the study is a map showing the areas allocated for restoration. The proposed method is compared to two alternative methods with varying degrees of determinism and uncertainty. The incorporation of uncertainty led to better allocation strategies and results that are more realistic.     

Aerosol bacteria over the Southern Ocean during ACE-1

Individual bacterial cells occur in many samples that were collected at Cape Grim, Tasmania and during the Lagrangian “B” experiment of the Aerosol Characterization Experiment 1 (ACE-1) campaign that was conducted above the Southern Ocean. They are present in samples from altitudes as high as 5.4 km. Morphologically, almost all bacteria are rod-shaped, about 1 μm long or smaller, have one polar flagellum, and contain inclusions that are rich in P and K. Their morphological features suggest that these bacteria are motile, marine species. It seems likely that the cells became airborne by the same bubble-bursting mechanism that ejects sea-salt aerosol particles into the atmosphere; however, the bacteria and sea-salt particles are typically not aggregated with one another. The estimated number ratio of bacteria and the dominant aerosol species, sea salt, varies in the samples and averages about 1%. The aerosol bacteria seem to represent an important atmospheric reservoir of P and organic compounds; on the other hand, since they are externally mixed with sea salt, they are unlikely to be effective as cloud condensation nuclei.     

Partitioning Spatial Model Uncertainty Based on Joint Spatial Simulation

In this study, an uncertainty analysis procedure for joint sequential simulation of multiple attributes of spatially explicit models used in geographical informational systems was developed based on regression analysis. This procedure utilizes information obtained from joint sequential simulation to establish the relationship between model uncertainty and variation of model inputs. Using this procedure, model variance can be partitioned by model input parameters on a cell by cell basis. In the partitioning, the correlation of neighboring cells is accounted for. With traditional uncertainty analysis methods, this is not possible. In a case study, spatial variation of soil erodibility from a joint sequential simulation of soil properties was analyzed. The results showed that the regression approach is a very effective method in the analysis of the relationship between variation of the model output and model input parameters. It was also shown for the case study that: (1) the uncertainty of soil erodibility of a cell is mainly propagated from its own soil properties; (2) the interactions of soil properties of neighboring cells could reduce uncertainty of soil erodibility; (3) it is sufficient for uncertainty analysis to include the nearest three neighboring cell groups; and (4) the largest uncertainty contributors vary by soil properties and location.