甘南玛曲沼泽湿地土壤微生物量、理化因子与土壤酶活的关系

对甘南玛曲沼泽湿地6个样地的微生物量与土壤酶活性及其土壤理化性质之间的关系进行了研究.结果表明:纤维素酶活性在冬季达到高峰,其余5种土壤酶活性分别在春季和秋季达到高峰;硝化细菌数量与过氧化氢酶、纤维素酶、脲酶、碱性磷酸酶有较显著的负相关关系;微生物量与酶活性之间存在极显著相关关系,其中微生物量因子中的放线菌、氨化细菌、硝化细菌和土壤酶活性因子中的酸性磷酸酶、碱性磷酸酶、中性磷酸酶是引起相关性的主要因素;酸性磷酸酶活性与土壤含水率、pH值、硝态氮含量、氨态氮含量都有密切的关系,过氧化氢酶活性可以通过有机质的含量来反映,脲酶活性可以通过土壤的含水率来反映,碱性磷酸酶活性可以通过电导率来反映.     

相似误差订正方法在风电短期风速预报中的应用研究

为降低风电场短期预报风速误差,减少风电场短期风功率偏差积分电量,提高风电场发电功率预测准确率,分季节研究了相似误差订正方法对ECMWF单台风机预报风速的订正效果.结果表明:相似误差订正后不同风机预报风速的误差差距减小;预报风速的平均绝对偏差和均方根误差明显降低,其中夏季和秋季华能义岗风电场两个指标降低幅度均超过0.1 ...     

冀北窟窿山流纹斑岩锆石SHRIMP U-Pb年龄、地球化学特征及地质意义

冀北窟窿山流纹斑岩位于赤峰—开原断裂以南、尚义—平泉断裂带以北的华北克拉通北缘隆起带和沽源—红山子铀成矿带的西南段,主要分布于窟窿山北西部,出露面积约25 km~2。本文通过SHRIMP锆石U-Pb定年和主量元素、微量元素、稀土元素、Sr—Nd—Pb—O同位素组成测试,查明流纹斑岩形成的地质时代,探讨流纹斑岩的物质来源和形成的构造背景,分析流纹斑岩与铀矿化的关系。分析结果显示:流纹斑岩SHRIMP锆石n(~(206)Pb)/n(~(238)U)年龄为138.4±1.3 Ma(n=12,MSWD=0.25),属早白垩世早期;流纹斑岩具有高硅、富钾、钠,高FeO~T/MgO值,贫Al、Mg、Ca、P的高分异特征,属准铝质—弱过铝质高钾钙碱性系列岩石,在SiO_2—[(Na_2O+K_2O)—CaO]和SiO_2—FeO~T/(FeO~T+MgO)图解中落于A型花岗岩区;∑REE含量较低,Eu负异常明显,具轻稀土富集型稀土配分曲线特征,富集Rb、Th、U、Nb、Ta、Zr、Hf、Y等元素,亏损Sr、Ba、P、Ti等元素,10000Ga/Al=3.74～4.29(2.6),Zr+Nb+Ce+Y=374×10~(-6)～402×10~(-6)(350×10~(-6)),显示A型花岗岩微量元素的特征。流纹斑岩的[n(~(87)Sr)/n(~(86)Sr)]_i值变化范围较大(=0.690385～0.724000),ε_(Nd)(t)值较低(=-16.2～-14.9)、T_(DM2)较大(=2163～2244 Ma),Pb同位素比值较低{[n(~(206)Pb)/n(~(204)Pb)]_i=16.893～16.922、[n(~(207)Pb)/n(~(204)Pb)]_i=15.393～15.424、[n(~(208)Pb)/n(~(204)Pb)]_i=37.716～37.771},在铅同位素图解中窟窿山流纹斑岩同时带有下地壳物质和富集地幔印记;δ~(18)O_(V-SMOW)=3.5‰～4.9‰,低于正常地幔的δ~(18)O_(V-SMOW)值(=5.3‰±0.3‰),具低氧流纹岩特征。Sr—Nd—Pb—O同位素特征显示,流纹斑岩可能是源于DMM型、EMI型地幔和少量古老下地壳混合形成的年轻下地壳部分熔融的产物,而且与高温热液蚀变有关。对比表明,窟窿山流纹斑岩与中国东部绝大多数与火山岩有关的热液型铀矿的赋矿围岩时代一致,特别是与沽源—红山子铀成矿带西南段张麻井铀矿的赋矿流纹斑岩特征一致,而且在流纹斑岩的接触带内已揭露到铀矿化,指示窟窿山流纹斑岩的内、外接触带具有良好的找矿前景。     

Geothermal structure revealed by curie isothermal surface under Guangdong Province,China

Guangdong Province in Southeast China is noted for its numerous geothermal resources due to tectonic episodes, mainly occurred during the Cretaceous. The surface heat flow and geothermal gradient are the most direct ways to understand the temperature of the Earth. However, geothermal resources are poorly utilized in Guangdong Province due to limited numbers of boreholes and surficial hydrothermal fluids. To improve the understanding of underground temperature distribution in Guangdong Province, we have applied power-density spectral analysis to aeromagnetic anomaly data to calculate the depth of the Curie isothermal surface. Upward continuation is applied and tested to the magnetic data. The calculated Curie isotherm is between 18.5 km and 25 km below surface. The fluctuation in the depth range reflects lateral thermal perturbations in the Guangdong crust. In particular, the eastern, northern, western and coastline areas of the province have a relatively shallow Curie isotherm. By comparing the surface heat flow, geothermal gradient, distribution of Mesozoic granite-volcanic rocks, and natural hot springs, we conclude that during Mesozoic, magmatism exerted great influence on the deep thermal state of Guangdong Province. A shallow Curie isotherm surface, as well as numerous natural hot springs and high heat flow,show clear signatures of shallow heat sources.     

清水河水文特性分析

依据清水河克尔古提水文站实测资料及河流所处的地理位置,分析了该河的降水、蒸发、径流、泥沙、冰情、洪枯水及水质等水文特性,为进一步了解洪水特性和发生发展规律,合理开发利用水资源,为下游工农业生产服务提供了依据。     

The Stable Carbon Isotope Ratio of Biogenic Emissions of Isoprene and the Potential Use of Stable Isotope Ratio Measurements to Study Photochemical Processing of Isoprene in the Atmosphere

A technique was developed that allows the determination of the stable carbon isotope ratio of isoprene in air. The method was used for a limited number of ambient measurements as well as laboratory studies of isoprene emitted from Velvet Bean (Mucana pruriens L. var. utilis), including the light and temperature dependence. The mean stable carbon isotope ratio ( ¹³C) of isoprene emitted from Velvet Bean (Mucana pruriens L. var. utilis) for all our measurements is –27.7 ± 2.0 (standard deviation for 23 data points). Our results indicate a small dependence of the stable carbon isotope ratios on leaf temperature and photosynthetic photon flux density (PPFD). The light dependence is 0.0026 ± 0.0012/( mol of photons m^–2 s^–1) for the studied range from 400 to 1700 mol of photons m^–2 s^–1. The temperature dependence is 0.16 ± 0.09/K. On average, the emitted isoprene is 2.6 ± 0.9 lighter than the leaf carbon. An uncertainty analysis of the possibility to use stable carbon isotope ratio measurements of isoprene for estimates of its mean photochemical age suggests that meaningful results can be obtained. This is supported by the results of a small number of measurements of the stable carbon isotope composition of ambient isoprene at different locations. The results range from approximately –29 to –16. They are consistent with vegetation emissions of isoprene that is slightly depleted in ¹³C relative to the plant material and enrichment of ¹³C in the atmosphere due to isotope fractionation associated with the reaction with OH-radicals. The stable carbon isotope ratio of ambient isoprene at locations directly influenced by isoprene emissions is very close to the values we found in our emission studies, whereas at sites located remote from isoprene emitting vegetation we find substantial enrichment of ¹³C. This suggests that stable carbon isotope ratio measurements will be a valuable, quantitative method to determine the extent of photochemical processing of isoprene in ambient air.     

Testing the utility of structure‐from‐motion photogrammetry reconstructions using small unmanned aerial vehicles and ground photography to estimate the extent of upland soil erosion

Quantifying the extent of soil erosion at a fine spatial resolution can be time consuming and costly; however, proximal remote sensing approaches to collect topographic data present an emerging alternative for quantifying soil volumes lost via erosion. Herein we compare terrestrial laser scanning (TLS), and both unmanned aerial vehicle (UAV) and ground photography (GP) structure‐from‐motion (SfM) derived topography. We compare the cost‐effectiveness and accuracy of both SfM techniques to TLS for erosion gully surveying in upland landscapes, treating TLS as a benchmark. Further, we quantify volumetric soil loss estimates from upland gullies using digital surface models derived by each technique and subtracted from an interpolated pre‐erosion surface. Soil loss estimates from UAV and GP SfM reconstructions were comparable to those from TLS, whereby the slopes of the relationship between all three techniques were not significantly different from 1:1 line. Only for the TLS to GP comparison was the intercept significantly different from zero, showing that GP is more capable of measuring the volumes of very small erosion features. In terms of cost‐effectiveness in data collection and processing time, both UAV and GP were comparable with the TLS on a per‐site basis (13.4 and 8.2 person‐hours versus 13.4 for TLS); however, GP was less suitable for surveying larger areas (127 person‐hours per ha^?1 versus 4.5 for UAV and 3.9 for TLS). Annual repeat surveys using GP were capable of detecting mean vertical erosion change on peaty soils. These first published estimates of whole gully erosion rates (0.077 m a^?1) suggest that combined erosion rates on gully floors and walls are around three times the value of previous estimates, which largely characterize wind and rainsplash erosion of gully walls. Copyright © 2017 John Wiley & Sons, Ltd.     

巢湖表层沉积物中多溴联苯醚的分布和污染源解析

在巢湖不同区域采集了16个表层沉积物样品,利用气相色谱-质谱仪测定沉积物中低溴代多溴联苯醚(LPBDEs)和BDE209的含量,并对其残留、组成、空间分布和污染来源进行分析.结果表明,巢湖沉积物中共计检测到9种多溴联苯醚(PBDEs)化合物.∑LPBDEs的含量为0.001~2.75 ng/g,平均值为1.15 ng/g,平均检测率为44.83%;BDE209的含量为1.16~5.49 ng/g,平均值为2.83 ng/g,检测率为100%.与国内其他区域相比,巢湖沉积物中PBDEs含量总体处于中等水平.巢湖沉积物中各类LPBDEs和BDE209同系物含量为:西半湖东半湖湖心.巢湖沉积物中PBDEs以BDE209为主要成分,不同采样点PBDEs同系物的组成不同.相关性分析表明BDE209与LPBDEs在环境中的迁移存在相关性.     

三十年来长江中下游湖泊富营养化状况变迁及其影响因素

为弄清长江中下游通江/历史通江湖泊富营养化现状、成因及修复策略,对该区域27个大型湖泊和水库开展了4个季度的水质调查,并结合部分湖泊1988-1992年及2008年两个时段富营养化调查成果,分析近30年来长江中下游地区大型湖泊富营养化关键指标变化的特征及其驱动因素.结果表明,目前该区域绝大多数湖泊处于富营养水平,较1980s有明显加重,浮游植物叶绿素a及总磷是最主要的营养状态指数贡献因子;湖泊的富营养化状况与湖泊的江湖连通状况、换水周期等流动性状况、渔业养殖及管理、流域纳污、治理强度等人类活动方式和强度密切相关;与历史调查结果相比,氮、磷的增幅相对较小,而有机质污染程度明显加重、浮游植物叶绿素a浓度大幅增高,表明营养盐之外的其他因素,如水文节律的变化、江湖阻隔、不合理的渔业养殖活动等,对该区域湖泊的富营养化问题加剧、浮游植物生产力增高起到更为重要的作用.因此,从治理途径和策略上来看,增加湖泊的流通性、恢复部分湖泊的自然水文波动节律、优化湖泊渔业管理、提升湖泊流域营养盐的有效截留能力、实施湖泊生态修复工程是控制长江中下游湖泊富营养化、提升区域湖泊生态质量的关键.     

2002-2017年千岛湖浮游植物群落结构变化及其影响因素

为认识大型水库中浮游植物群落结构的演替特征及其驱动机制,以钱塘江流域新安江水库（下称"千岛湖"）为例,基于2002-2017年16年的水库浮游植物数据,结合同期千岛湖水质与水文气象资料,分析了千岛湖浮游植物结构及优势属的长期变化特征,探讨了影响浮游植物群落结构变化的主要因素.结果表明：2002-2017年千岛湖共鉴定出浮游植物7门93属,主要由硅藻门、绿藻门、蓝藻门及隐藻门种类组成.16年间,浮游植物年均丰度和群落结构经历了4个阶段：2008年前丰度持续低值且蓝藻不是主要类群,2009-2012年丰度较高且蓝藻成为主要类群,及2013-2015丰度降低且蓝藻占比降低,2016-2017年丰度增加且蓝藻再次成为主要类群.浮游植物门类变化的同时伴随着优势属的变化：浮游植物年优势属从2002-2008年的小环藻属（Cyclotella）、隐藻属（Cryptomonas）和蓝隐藻属（Chroomonas）转变为2009-2012年的颤藻属（Oscillatoria）、小球藻属（Chlorella）、小环藻属和蓝隐藻属,2013-2017年又转变为鱼腥藻属（Anabaena）、束丝藻属（Aphanizomenon）、小环藻属、针杆藻属（Synedra）、直链藻属（Melosira）、栅藻属（Scenedesmus）和蓝隐藻属.冗余分析表明,气温、风速、水位、入库流量等气象水文因子和总氮浓度、电导率、氮磷比、透明度等水质因子与浮游植物群落结构变化关系密切.研究结果表明,在千岛湖这种大型贫-中营养水库,浮游植物群落结构不仅受来水营养盐负荷的影响,还在很大程度上受水文、气象条件的影响,给水库藻类水华等生态风险的预测以及水库水质管理带来了挑战.