An analytical solution for rainfall infiltration into an unsaturated infinite slope and its application to slope stability analysis

Surficial slope failures in residual soils are common in tropical and subtropical regions as a result of rainfall infiltration. This study develops an analytical solution for simulating rainfall infiltration into an infinite unsaturated soil slope. The analytical solution is based on the general partial differential equation for water flow through unsaturated soils. It can accept soil–water characteristic curve and unsaturated permeability function of the exponential form into account. Numerical simulations are conducted to verify the assumptions of the analytical solution and demonstrate that the proposed analytical solution is acceptable for the coarse soils with low air entry values. The pore‐water pressure (pwp) distributions obtained from the analytical solution can be incorporated into a limit equilibrium method to do infinite slope stability analysis for a rain‐induced shallow slip. The analysis method takes into account the influence of the water content change on unit weight and hence on factor of safety. A series of analytical parametric analyses have been performed using the developed model. The analyses indicate that when the residual soil slope, consisting of a completely decomposed granite layer underlain by a less permeable layer, is subjected to a continuous heavy rainfall, the loss of negative pwp and the reduction in factor of safety were found to be most significant for the shallow soil layer and during the first 12 h. The antecedent and subsequent rainfall intensity, depth of a less permeable layer and slope angle all have a significant influence on the pwp response and hence the slope stability. Copyright © 2012 John Wiley & Sons, Ltd.     

Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland: Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.     

The partial molal volume of silicic acid in 0.725 m NaCl

The partial molal volume ($\text{V}\text{?}$) of silicic acid in 0.725 m NaCl at 20°C has been calculated from (1) direct volume changes due to the dissolution of anhydrous sodium silicate and (2) some literature values for the partial molal volumes of NaOH and water. , unconnected for electrostriction effects, was found to be 53 ± 2 ml mole^?1. , corrected for volume changes due to solvent electrostriction by charged Si species, was estimated to be in the range 58–62 ml mole^?1; this range is 7–11 ml mole^?1 greater than the calculated from Willey's (Mar. Chem. 2, 239–250, 1974) solubility data obtained from the dissolution, in seawater, of amorphous silica subjected to hydrostatic pressure. Our does, however, agree within experimental error with the calculated from Jones and Pytkowicz's (Bull. Soc. Roy. Sci. Liege 42, 118–120, 1973) data for the solubility of amorphous silica in seawater at high pressure and is nearly in agreement with Willey's (Ph.D. thesis, Dalhousie University, 1975) solubility data for amorphous silica in 0.6 m NaCl.     

World Cities in the Pacific Rim: A New Global Test of Regional Coherence

A new evaluation of the Pacific Rim concept is presented. The originality of this test for regional coherence is to be found in the basic units being analysed: cities instead of states. Based on a theoretical framework that identifies world city and world city network formation in terms of the office networks of advanced producer service firms, we use a principal components analysis to analyse a data set of 28 Pacific Rim cities and 46 global service firms. This identifies five main groupings of cities in terms of similar mixes of corporate service firms: a western Rim group; a group of ‘old Commonwealth’ cities; a market communist group of cities; Tokyo as a global city; and US cities as a specific separate group. These results confirm numerous earlier studies that were sceptical of the existence of a coherent Pacific Rim region. However, the particular approach adopted here allows us to identify the Pacific Rim generically as a particularly pernicious construct. We conclude that the Pacific Rim is a geographical chaotic conception.     

Development of two novel CYP-antibodies and their use in a PCB exposure experiment with Mytilus edulis

In an attempt to learn more about the cytochrome P450 (CYP) system of mussels, we used protein databases and alignment software to extract highly conserved CYP sequences. From these alignments synthetic peptides were produced and used for rabbit immunisation, which yielded polyclonal antibodies against the CYP families 2 and 4. The antibodies were evaluated with Western Blot and ELISA assays, using digestive gland microsomal samples from the mussel Mytilus edulis. Western Blots revealed immunoreactions for both antibodies. The anti-CYP2 sequence rendered one major immunopositive protein of approximately 49 kDa size, and weak signals for proteins of approximately 41 and 56 kDa size. The anti-CYP4 sequence rendered two major bands of approximately 56 and 59 kDa size, and also a weak immunoreaction with a protein of approximately 43 kDa size. ELISA rendered only weak signals even with a 1:50 dilution of IgG-purified serum. A 10-day exposure to Aroclor 1254 did not appear to affect any of the immunopositive proteins, while total PCBs in soft bodies increased from 14-40 ng/g DW in controls to 373-638 ng/g DW in exposed mussels.     

Use of suppressive subtractive hybridization and cDNA arrays to discover patterns of altered gene expression in the liver of dihydrotestosterone and 11-ketotestosterone exposed adult male largemouth bass (Micropterus salmoides)

In this study male largemouth bass (LMB) were exposed to the naturally occurring androgens, dihydrotestosterone (DHT) or 11-ketotestosterone (11-KT) in order to identify genes that are differentially regulated by these steroid hormones. Using subtractive hybridization on livers of fish treated with DHT against vehicle control, many novel LMB genes were cloned. These genes were added to our gene library and arrayed. Six genes were up-regulated and five were down-regulated by both androgens. But, each androgen also regulated specific genes. One gene that was identified as a potential androgen marker was spermidine-spermine-N(1)-acetyltransferase that was up-regulated by both androgens. Determining which genes are responsive to natural androgens will help to identify biochemical pathways that are impacted.     

Atlas of Japan (East) Sea hydrographic properties in summer, 1999

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.