Distinguishing extensive and intensive properties for meaningful geocomputation and mapping

A most fundamental and far-reaching trait of geographic information is the distinction between extensive and intensive properties. In common understanding, originating in Physics and Chemistry, extensive properties increase with the size of their supporting objects, while intensive properties are independent of this size. It has long been recognized that the decision whether analytical and cartographic measures can be meaningfully applied depends on whether an attribute is considered intensive or extensive. For example, the choice of a map type as well as the application of basic geocomputational operations, such as spatial intersections, aggregations or algebraic operations such as sums and weighted averages, strongly depend on this semantic distinction. So far, however, the distinction can only be drawn in the head of an analyst. We still lack practical ways of automation for composing GIS workflows and to scale up mapping and geocomputation over many data sources, e.g. in statistical portals. In this article, we test a machine-learning model that is capable of labeling extensive/intensive region attributes with high accuracy based on simple characteristics extractable from geodata files. Furthermore, we propose an ontology pattern that captures central applicability constraints for automating data conversion and mapping using Semantic Web technology.     

RECOGNISING THE UNCERTAINTY IN THE QUANTIFICATION OF THE EFFECTS OF CLIMATE CHANGE ON HYDROLOGICAL RESPONSE

A widely used method of evaluating effects of climate change on flow regime is to perturb the climate inputs to a rainfall–runoff model and examine the effect on a statistic of the modelled flows. Such studies require four elements: a method of perturbing the climate, a rainfall–runoff model, a study catchment and a flow index. In practice the direction and magnitude of the estimated effects depend on each of the four elements, leading to concern over the usefulness and generality of the results. To investigate these uncertainties two climate scenarios and eight climate sensitivity tests have been applied to three UK catchments using two conceptual rainfall–runoff models in order to quantify effects of climate change on three flow indices representing mean runoff, flood magnitudes and low flows. The sensitivity tests were found to be useful to assess the suitability of the models to simulate flows outside the conditions experienced in their calibration. Both models gave internally consistent results but, on close examination, one model was found inappropriate for this application. Results show that the effect of climate change on flow varies between catchments and that different flow response indices can change in opposite directions, e.g. floods increased in magnitude while low flows reduced. Contrasting results were obtained from the two climate scenarios.     

Photometric monitoring of 2060 Chiron''s brightness at perihelion

The results of photometric and spectroscopic observations of comet/asteroid 2060 Chiron carried on at the Observatório do Pico-dos-Dias (Brazil), at the European Southern Observatory (Chile) and at the Mauna Kea Observatory (Hawaii) during 1996 are presented. The analysis of the photometric data shows that even at a minimum of brightness 2060 Chiron presents some activity. The absolute magnitude, H_v, varied from 6.79 in February to 6.22 in March. Therefore 2060 Chiron is still in a minimum of activity close to that of 1983–1985 and of 1994–1995.     

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.     

Statistical models for the assessment of nitrate contamination in urban groundwater using GIS

The purpose of this study is to develop statistical models for groundwater quality assessment in urban areas using Geographic Information Systems (GIS). To develop the models, the concentrations of nitrate (expressed as nitrogen, NO₃-N), which are different according to the type of land use, well depth and distribution of rainfall, were analyzed in the Seoul (the capital of South Korea) area. Data such as land use, location of wells and groundwater quality data for nitrate contamination were collected and a database constructed within GIS. The distribution of NO₃-N concentrations is not normal, and the results of the Mann-Whitney U-test analysis show the difference of NO₃-N concentration by well depth and by distribution of rainfall. In both the shallow and deep wells, the radius of influence is 200 m in the dry season and 250 m in the rainy season, showing the tendency to increase in the rainy season. The results of correlation and regression analysis indicate that mixed residential and business areas and cropped field areas are likely to be the major contributor of increasing NO₃-N concentration. Land uses are better correlated with NO₃-N in deep wells than in shallow wells.     

Marine mammals from northeast Atlantic: relationship between their trophic status as determined by delta13C and delta15N measurements and their trace metal concentrations

The relationship between trophic position through delta13C and delta15N and trace metal concentrations (Zn, Cd, Cu and Hg) was investigated in the tissues of six marine mammal species from the Northeast Atlantic: striped dolphin Stenella coeruleoalba, common dolphin, Delphinus delphis, Atlantic white-sided dolphin Lagenorhynchus acutus, harbour porpoise Phocoena phocoena, white beaked-dolphin Lagenorhynchus albirostris, grey seal Halichoerus grypus stranded on French Channel and Irish coasts. White-beaked dolphins, harbour porpoises, white-sided dolphins, common and striped dolphins display the same relative and decreasing trophic position, as measured by delta15N values, along both the Irish and French channel coasts, reflecting conservative trophic habits between these two places. Hepatic and renal Cd concentrations were significantly correlated to muscle delta13C and delta15N values while Hg, Zn and Cu did not. These results suggest that Cd accumulation is partly linked to the diet while other factors such as age or body condition might explain Hg, Zn or Cu variability in marine mammals. Combined stable isotope and trace metal analyses appear to be useful tools for the study of marine mammal ecology.     

Assessment of Submarine Groundwater Discharge (SGD) as a Source of Dissolved Radium and Nutrients to Moorea (French Polynesia) Coastal Waters

Previous work has documented large fluxes of freshwater and nutrients from submarine groundwater discharge (SGD) into the coastal waters of a few volcanic oceanic islands. However, on the majority of such islands, including Moorea (French Polynesia), SGD has not been studied. In this study, we used radium (Ra) isotopes and salinity to investigate SGD and associated nutrient inputs at five coastal sites and Paopao Bay on the north shore of Moorea. Ra activities were highest in coastal groundwater, intermediate in coastal ocean surface water, and lowest in offshore surface water, indicating that high-Ra groundwater was discharging into the coastal ocean. On average, groundwater nitrate and nitrite (N + N), phosphate, ammonium, and silica concentrations were 12, 21, 29, and 33 times greater, respectively, than those in coastal ocean surface water, suggesting that groundwater discharge could be an important source of nutrients to the coastal ocean. Ra and salinity mass balances indicated that most or all SGD at these sites was saline and likely originated from a deeper, unsampled layer of Ra-enriched recirculated seawater. This high-salinity SGD may be less affected by terrestrial nutrient sources, such as fertilizer, sewage, and animal waste, compared to meteoric groundwater; however, nutrient-salinity trends indicate it may still have much higher concentrations of nitrate and phosphate than coastal receiving waters. Coastal ocean nutrient concentrations were virtually identical to those measured offshore, suggesting that nutrient subsidies from SGD are efficiently utilized.     

Age and Geochemical Characteristics of a Mafic Dyke Swarm in the Archaean Vestfold Block, Antarctica: Inferences about Proterozoic Dyke Emplacement in Gondwana

Archaean gneisses in the Vestfold Block, Antarctica are cutby abundant tholeiite and rare alkaline dykes. At least fivegenerations of dykes have been recognized on the basis of intrusiverelationships, petrography and geochemistry. Rb-Sr isotopicdata indicate that intrusion of the tholeiites occurred overa period of c. 1000 Ma, during three clearly defined events(viz. c. 2400, 1800, and 1400 Ma). Dykes in the southwesternpart of the Vestfold Block were recrystallized during a lateProterozoic (c. 1000-1100 Ma) high-grade event. Mineral-wholerock Rb-Sr isotopic data show that the terrain was also variablyaffected by an even younger thermal event c. 500 Ma ago whichis correlated with the Pan-African Orogeny. Isotopic, major element and trace element data suggest thatthe tholeiite dyke suites were derived by varying degrees ofpartial melting of compositionally distinct, in some cases ratherheterogeneous subcontinental mantle source regions, combinedwith variations in the extent and nature of crystal fractionation.Extensive crustal contamination does not appear to have playeda significant role in determining compositional trends withinthe different suites, although minor contamination cannot bediscounted. The oldest dykes, a diverse group of high-Mg tholeiites,and the youngest, c. 1400 Ma tholeiites, appear to have beenderived from isotopically similar source regions, which werenevertheless characterized by quite different abundances ofhighly incompatible elements (Pb, Rb, Ba, Th, K, La, and Ce).1800 Ma tholeiites were derived from a more radiogenic mantlesource region, characterized by long-term enrichment in incompatibleelements. Such enrichment is interpreted to be a consequenceof metasomatism of their mantle source region. 2400 Ma high-Mg dykes in Enderby Land have virtually identicalchemical and isotopic compositions to those in the VestfoldBlock, indicating generation from a similar source region; however,1200 Ma tholeiites were apparently derived from a more radiogenicsource region like that of the c. 1800 Ma Vestfold Block dykes.Hence, both Sr isotopic and geochemical data indicate that theancient subcontinental lithospheric mantle beneath Gondwanawas extremely heterogeneous.