Abundance of Boron in International Geochemical Standards by Prompt-Gamma Neutron Activation Analysis

Eighteen international reference standards, mostly geochemical standards, have been analysed for boron using prompt-gamma neutron activation analysis (PGNAA). There is good agreement between the results for samples with high boron abundances and the few published values using PGNAA and other methods. However, correlation is poor at low boron abundances, especially in those standards with low boron/sodium ratios. Corrections for sodium interference on boron have been critically evaluated and the data corrected using two different methods.     

Mechanism of continental crust subsidence in the Alpine Belt

Formation of deep basins on continental crust in fold belts is often explained by stretching. This mechanism inevitably produces large deformations in the upper crust. No deformations typical of significant stretching were revealed in the predominant part of deep basins on continental crust in the Alpine Belt. This means that these basins were not produced by stretching. Most basins were formed during a short period of time of a few million years. The short duration of the subsidences eliminates thermal relaxation as the mechanism. The space and time relationships between the subsidence and orogeny and the profile of the basin floor exclude thrust loading as a cause of formation for practically all large basins. Gabbro to eclogite transformation is suggested as a mechanism of rapid subsidence. This occurs under the upwelling of hydrous asthenosphere at moderate temperature to the base of the crust. Eclogite sinking into the mantle results in a strong attenuation of the crust and lithosphere, which permits intense subsequent folding. The major part of deep basins in continental crust that formed by rapid subsidence was intensely shortened in the Alpine Belt. Significant crustal shortening did not spread over the cratonic lithosphere.     

Lithostratigraphic development and neotectonic significance of the Quaternary sediments along the Kachchh Mainland Fault (KMF) zone,western India

The Kachchh Mainland Fault (KMF) is a major E–W trending seismically active fault of the Kachchh palaeorift basin whose neotectonic evolution is not known. The present study deals with the eastern part of the KMF zone where the fault is morphologically expressed as steep north facing scarps and is divisible into five morphotectonic segments. The Quaternary sediments occurring in a narrow zone between the E–W trending KMF scarps and the flat Banni plain to the north are documented. The sediments show considerable heterogeneity vertically as well as laterally along the KMF zone. (The Quaternary sediments for a northward sloping and are exposed along the north flowing streams which also show rapid decrease in the depth of incision in the same direction.) The deposits, in general, comprise coarse as well as finer gravelly deposits, sands and aeolian and fluvial miliolites. The Quaternary sediments of the KMF zone show three major aggradation phases. The oldest phase includes the colluvio-fluvial sediments occurring below the miliolites. These deposits are strikingly coarse grained and show poor sorting and large angular clasts of Mesozoic rocks. The sedimentary characteristics indicate deposition, dominantly by debris flows and sediment gravity flows, as small coalescing alluvial fans in front of the scarps. These deposits suggest pre-miliolite neotectonic activity along the KMF. The second aggradation phase comprises aeolian miliolites and fluvially reworked miliolites that have been previously dated from middle to late Pleistocene. The youngest phase is the post-miliolite phase that includes all deposits younger than miliolite. These are represented by comparatively finer sandy gravels, gravelly sands and sand. The sediment characteristics suggest deposition in shallow braided stream channels under reduced level of neotectonic activity along the KMF during post-miliolite time evidenced by vertical dips of miliolites and tilting of gravels near the scarps. The tectonically controlled incision and dissection of the Quaternary deposits is the result of neotectonic activity that continues at present day. The overall nature, sedimentary characteristics and geomorphic setting of the sediments suggest that the KMF remained neotectonically active throughout the Quaternary period.     

Oxyphlogopite K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2: A new mineral species of the mica group

Oxyphlogopite is a new mica-group mineral with the idealized formula K(Mg,Ti,Fe)₃[(Si,Al)₄O₁₀](O,F)₂. The holotype material came from a basalt quarry at Mount Rothenberg near Mendig at the Eifel volcanic complex in Rhineland-Palatinate, Germany. The mineral occurs as crystals up to 4 × 4 × 0.2 mm in size encrusting cavity walls in alkali basalt. The associated minerals are nepheline, plagioclase, sanidine, augite, diopside, and magnetite. Its color is dark brown, its streak is brown, and its luster is vitreous. D _meas = 3.06(1) g/cm³ (flotation in heavy liquids), and D _calc = 3.086 g/cm³. The IR spectrun does not contain bands of OH groups. Oxyphlogopite is biaxial (negative); α = 1.625(3), β = 1.668(1), and γ = 1.669(1); and 2V _meas = 16(2)° and 2V _calc = 17°. The dispersion is strong; r < ν. The pleochroism is medium; X > Y > Z (brown to dark brown). The chemical composition is as follows (electron microprobe, mean of 5 point analyses, wt %; the ranges are given in parentheses; the H₂O was determined using the Alimarin method; the Fe²⁺/Fe³⁺ was determined with X-ray emission spectroscopy): Na₂O 0.99 (0.89–1.12), K₂O 7.52 (7.44–7.58), MgO 14.65 (14.48–14.80), CaO 0.27 ((0.17–0.51), FeO 4.73, Fe₂O₃ 7.25 (the range of the total iron in the form of FeO is 11.09–11.38), Al₂O₃ 14.32 (14.06–14.64), Cr₂O₃ 0.60 (0.45–0.69), SiO₂ 34.41 (34.03–34.66), TiO₂ 12.93 (12.69–13.13), F 3.06 (2.59–3.44), H₂O 0.14; O=F₂ −1.29; 99/58 in total. The empirical formula is (K_0.72Na_0.14Ca_0.02)(Mg_1.64Ti_0.73Fe_0.30²⁺ Fe_0.27³⁺Cr_0.04)_Σ2.98(Si_2.59Al_1.27Fe_0.14³⁺ O₁₀) O_1.20F_0.73(OH)_0.07. The crystal structure was refined on a single crystal. Oxyphlogopite is monoclinic with space group C2/m; the unit-cell parameters are as follows: a = 5.3165(1), b = 9.2000(2), c = 10.0602(2) ?, β = 100.354(2)°. The presence of Ti results in the strong distortion of octahedron M(2). The strongest lines of the X-ray powder diffraction pattern [d, ? (I, %) [hkl]] are as follows: 9.91(32) [001], 4.53(11) 110], 3.300(100) [003], 3.090(12) [112], 1.895(21) [005], 1.659(12) [−135], 1.527(16) [−206, 060]. The type specimens of oxyphlogopite are deposited at the Fersman Mineralogical Museum in Moscow, Russia; the registration numbers are 3884/2 (holotype) and 3884/1 (cotype).     

Geochemistry of isotopes (δ<Superscript>13</Superscript>C, δ<Superscript>18</Superscript>O) and formation conditions of lower-middle permian rocks in the Soyana River region (Arkhangel’sk district)

The results of study of the isotopic-lithological compositions of carbonate and terrigenous-carbonate rocks in the Soyana River section (northern East European Platform, Arkhangel’sk district) are presented. The results make it possible to identify 10 main lithotypes and show a wide variation range of δ¹³C (from −2.2 to +3.6‰, PDB) and δ¹⁸O (from 22.5 to 30.5‰, SMOW). These lithological features and isotopic compositions suggest that the rocks were formed in a shallow-marine setting characterized by rapidly changing sedimentation conditions in various facies (and/or paleoecological) zones: inlets, lagoons, supralittoral, littoral, and shoals. Periods of aridization and humidization are recorded. The results also indicate numerous synsedimentary short-term hiatuses and stages of increased continental runoff—episodic pulsatory input of clastic material with the continental paleoflows.     

Modelling carbon isotopes of carbonates in cave drip water

C isotopes in cave drip water are affected by both the C isotope composition of soil air and host rock carbonate. Furthermore, the C isotope composition of cave drip water strongly depends on the calcite dissolution system, i.e., open, closed and intermediate conditions. Here, we present a calcite dissolution model, which calculates the ¹⁴C activity and δ¹³C value of the dissolved inorganic carbon of the drip water. The model is based on the chemical equations describing calcite dissolution (). The most important improvement, relative to previous models, is the combination of the open and closed system conditions in order to simulate the C isotope composition during intermediate states of calcite dissolution and the application to carbon isotope measurements on cave drip waters from Grotta di Ernesto, Italy. The major changes in the C isotope composition of the drip water occur in response to variations in the open-closed system ratio. Additionally, the ¹⁴C activity and the δ¹³C value of the drip water depend on changes in the partial pressure of soil CO₂. Radiocarbon and δ¹³C values of the Grotta di Ernesto drip water are well reproduced by the model.     

Equivalent Permeability and Simulation of Two-Phase Flow in Heterogeneous Porous Media

The problem of calculating equivalent grid block permeability tensors for heterogeneous porous media is addressed. The homogenization method used involves solving Darcy's equation subject to linear boundary conditions with flux conservation in subregions of the reservoir and can be readily applied to unstructured grids. The resulting equivalent permeability tensor is stable as defined relative to G-convergence. It is proposed to use both conforming and mixed finite elements to solve the local problems and compute approximations from above and below of the equivalent permeability, respectively. Comparisons with results obtained using periodic, pressure and no-flux boundary conditions and the renormalization method are presented. A series of numerical examples demonstrates the effectiveness of the methodology for two-phase flow in heterogeneous reservoirs.     

AreSpartina marshes a replaceable resource? A functional approach to evaluation of marsh creation efforts

Marsh creation has come into increasing use as a measure to mitigate loss of valuable wetlands. However, few programs have addressed the functional ecological equivalence of man-made marshes and their natural counterparts. This study addresses structural and functional interactions in a man-made and two natural marshes. This was done by integrating substrate characteristics and marsh utilization by organisms of two trophic levels. Sediment properties, infaunal community composition, andFundulus heteroclitus marsh utilization were compared for a man-madeSpartina salt marsh (between ages 1 to 3 yr) in Dills Creek, North Carolina, and adjacent natural marshes to the east and west. East natural marsh and planted marsh sediment grain-size distributions were more similar to each other than to the west natural marsh due to shared drainage systems, but sediment organic content of the planted marsh was much lower than in either natural marsh. This difference was reflected in macrofaunal composition. Natural marsh sediments were inhabited primarily by subsurface, deposit-feeding oligochaetes whereas planted marsh sediments were dominated by the tube-building, surface-deposit feeding polychaetesStreblospio benedicti andManayunkia aestuarina. Infaunal differences were mirrored inFundulus diets. Natural marsh diets contained more detritus and insects, because oligochaetes, though abundant, were relatively inaccessible. Polychaetes and algae were major constituents of the planted marshFundulus diet. Though naturalmarsh fish may acquire a potentially less nutritive, detritus-based diet relative to the higher animal protein diet of the planted marsh fish,Fundulus abundances were markedly lower in the planted marsh than in the natural marshes, indicating fewer fish were being supported. LowerSpartina stem densities in the planted marsh may have provided inadequate protection from predation or insufficient spawning sites for the fundulids. After three years, the planted marsh remained functionally distinct from the adjacent natural marshes. Mitigation success at Dills Creek could have been improved by increasing tidal flushing, thereby enhancing, access to marine organisms and by mulching withSpartina wrack to increase sediment organic-matter content and porosity. Results from this study indicate that salt marshes should not be treated as a replaceable resource in the short term. The extreme spatial and temporal variability inherent to salt marshes make it virtually impossible to exactly replace a marsh by planting one on another site.