An experimental study of the effects of melt composition on plagioclase-melt equilibria at 5 and 10 kbar: implications for the origin of magmatic high-An plagioclase

An experimental investigation of plagioclase crystallization in broadly basaltic/andesitic melts of variable Ca# (Ca/(Ca+Na)*100) and Al# (Al/(Al+Si)*100) values and H₂O contents has been carried out at high pressures (5 and 10 kbar) in a solid media piston-cylinder apparatus. The H₂O contents of glasses coexisting with liquidus or near-liquidus plagioclases in each experiment were determined via an FTIR spectroscopic technique. This study has shown that melt Ca# and Al#, H₂O content and crystallization pressure all control the composition of liquidus plagioclase. Increasing melt Ca# and Al# increase An content of plagioclase, whereas the effect of increasing pressure is the opposite. However, the importance of the role played by each of these factors during crystallization of natural magmas varies. Melt Ca# has the strongest control on plagioclase An content, but melt Al# also exerts a significant control. H₂O content can notably increase the An content of plagioclase, up to 10 mol % for H₂O-undersaturated melts, and 20 mol % for H₂O-saturated melts. Exceptionally calcic plagioclases (up to An₁₀₀) in some primitive subduction-related boninitic and related rocks cannot be attributed to the presence of the demonstrated amounts of H₂O (up to 3 wt %). Rather, they must be due to the involvement of extremely refractory (CaO/Na₂O>18) magmas in the petrogenesis of these rocks. Despite the refractory nature of some primitive MORB glasses, none are in equilibrium with the most calcic plagioclase (An₉₄) found in MORB. These plagioclases were likely produced from more refractory melts with CaO/Na₂O = 12–15, or from melts with exceptionally high Al₂O₃(>18%). Magmas of appropriate compositions to crystallize these most calcic plagioclases are sometimes found as melt inclusions in near liquidus phenocrysts from these rocks, but are not known among wholerock or glass compositions. The fact that such melts are not erupted as discrete magma batches indicates that they are effectively mixed and homogenized with volumetrically dominant, less refractory magmas. The high H₂O contents (∼ 6 wt%) in some high-Al basaltic arc magmas may be responsible for the existence of plagioclases up to An₉₅ in arc lavas. However, an alternative possibility is that petrogenesis involving melts with abnormally high CaO/Na₂O values (> 8) may account for the presence of highly anorthitic plagioclases in these rocks. Received: 31 August 1993 / Accepted: 20 May 1994     

Correcting airborne flux measurements for aircraft speed variation

Airplane aerodynamic characteristics correlate aircraft speed with vertical wind velocity, making the time average inappropriate for estimating the ensemble average in airborne eddy-correlation flux computations. The space average, the proper form, is implemented as a time integral by a transformation of variables, which can be interpreted as a ground-speed correction to the time average. The mathematical forms are presented, and the importance of the speed correction is illustrated with airborne data. The computed correction is found to be highly variable, depending on both the turbulent flow encountered and the aircraft used. In general, the speed connection becomes more important as airplane size is reduced. For a small, single-engine Long-EZ airplane, used as an example, the straight time average erred, half the time, by 12%, 10%, 20%, and 15%, respectively, for computed fluxes of momentum, heat, moisture, and CO₂. For a much heavier Twin Otter airplane, also used as an example, the straight time average erred, half the time by only 1%. These errors increased with decreasing altitude for the Long-EZ and with increasing altitude for the Twin Otter.Oak Ridge Associated Universities, assigned to NOAA/ATDD.     

Petrology, geochemistry and tectonic implications of volcanics dredged from the intersection of the Yap and Mariana trenches

Rocks dredged from the forearc very close to the intersection of the Yap and Mariana trenches include a suite of highly depleted arc tholeiites, and several samples of transitional to slightly alkaline basalt. The tholeiites range from magnesian quartz tholeiites with 0.46–0.6% TiO₂, to andesites with up to 62% SiO₂ and 8.2% FeO^*. All show pronounced LREE depletion and have very low contents of Ba and Sr. They are postulated to have been produced by partial melting of upper mantle peridotite residual after MORB extraction, following influx of hydrous fluids from the subducted slab. While these fluids were responsible for small enrichments in Ba, K, Rb and Sr in melts generated, LREE were not involved in the metasomatism, and the strong LREE depletion probably reflects the unmodified, depleted source peridotite.

The second lava suite includes slightly Ne-normative, Ti-augite-bearing basalts with convex-upward REE patterns, showing slight LREE depletion ((La/Sm)_N = 0.76). The chemical features of these basalts support affinities with basalts erupted during the earliest stages of backarc basin opening. A KAr age on one sample(7.8 ± 1.3m.y.) is in good agreement with the initial opening of the Mariana Trough.

The tectonic significance of the dredged arc tholeiite suite is less obvious. A KAr age of10.8 ± 0.4 My on one andesite, and the occurrence of similar lavas in dredges from at least 300 km along the length of the Yap arc, suggest that subduction was occurring beneath the Yap arc in the Late Miocene, after overthrusting of the Yap greenschist allochthon, and while calc-alkaline arc magmatism was occurring further north on the West Mariana Ridge. We suggest that the depleted arc tholeiites in dredge 1438 were generated by abnormally shallow melting of upper mantle beneath the Yap forearc following subduction beneath this area of young, hot Sorol Trough crust. These arc tholeiites represent a magma type transitional between more typical arc tholeiites (e.g. Tongan) and high-Mg andesites and boninites.     

Biological markers from Green River kerogen decomposition

Isoprenoid and other carbon skeletons that are formed in living organisms and preserved essentially intact in ancient sediments are often called biological markers. The purpose of this paper is to develop improved methods of using isoprenoid hydrocarbons to relate petroleum or shale oil to its source rock. It is demonstrated that most, but not all, of the isoprenoid hydrocarbon structures are chemically bonded in kerogen (or to minerals) in Green River oil shale. The rate constant for thermally producing isoprenoid, cyclic, and aromatic hydrocarbons is substantially greater than for the bulk of shale oil. This may be related to the substantial quantity of CO₂ which is evolved coincident with the isoprenoid hydrocarbons but prior to substantial oil evolution. Although formation of isoprenoid alkenes is enhanced by rapid heating and high pyrolysis temperatures, the ratio of isoprenoid alkenes plus alkanes to normal alkenes plus alkanes is independent of heating rate. High-temperature laboratory pyrolysis experiments can thus be used to predict the distribution of aliphatic hydrocarbons in low temperature processes such as in situ shale oil production and perhaps petroleum formation. Finally, we demonstrate that significant variation in biological marker ratios occurs as a function of stratigraphy in the Green River formation. This information, combined with methods for measuring process yield from oil composition, enables one to relate time-dependent processing conditions to the corresponding time-dependent oil yield in a vertical modified-in situ retort even if there is a substantial and previously undetermined delay in drainage of shale oil from the retort.