Somma-Vesuvius’ activity: a mineral chemistry database

Mineralogy and Petrology - Clinopyroxene and olivine are ubiquitous phases in Somma-Vesuvius (SV) volcanics and for the first time they were systematically studied in several products younger than...     

Drinking water production from surface water sources in the tropics: Brasília DF,Brazil

Drinking water production at three waterworks was evaluated with respect to variable weather conditions in the Brasília Distrito Federal. Results of the investigation revealed that seasonal variations in rainfall play an important role in influencing the quality of the surface water sources used for drinking water production in the district. In most surface sources, particles and apparent colour are likely to originate from erosion during rain events. This represents the primary challenge facing waterworks, notably when the raw water qualities of the sources to be treated at one facility differ by one order of magnitude, as well significantly varying from one season to the next. Treatment efficiencies in terms of turbidity, apparent colour and dissolved organic carbon (DOC) removal were evaluated. Drinking water quality was found to be significantly influenced by raw water quality at all considered treatment plants. With regard to DOC removal, treatment was most efficient in waterworks which treated raw water with high percentages of biopolymers and humics. Most dissolved organics were removed by coagulation. Finally, conclusions are drawn on how to better cope with challenges facing drinking water production in a tropical climate. The first of these recommendations is the introduction of online turbidity and dissolved organic matter monitoring in order to optimise the coagulation process for the removal of these two parameters. A combination of different coagulants could also be considered for this process. Additional more sophisticated improvements to process stability, such as determination of floc characteristics, introduction of artificial neural networks or the eventual upgrade of the treatment train using membrane filtration, are also suggested.     

Benthic foraminifera distribution in a tourist lagoon in Rio de Janeiro, Brazil: a response to anthropogenic impacts

Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.     

Identifying rift zones on volcanoes: an example from La Réunion island,Indian Ocean

We describe a methodology for identifying complex rift zones on recent or active volcanoes, where structures hidden by recent deposits and logistical conditions might prevent carrying out detailed fieldwork. La Réunion island was chosen as a test-site. We used georeferenced topographic maps, aerial photos and digital terrain models to perform a statistical analysis of several morphometric parameters of pyroclastic cones. This provides a great deal of geometric information that can help in distinguishing the localisation and orientation of buried magma-feeding fractures, which constitute the surface expression of rift zones. It also allowed the construction of a complete GIS database of the pyroclastic cones. La Réunion is a perfect example where past and active volcanic rift zones are mostly expressed by clusters of monogenic centres. The data has been validated in the field and compared and integrated with the distribution and geometry of dyke swarms. Results show the presence of several main and secondary rift segments of different ages, locations and orientations, whose origin is discussed considering regional tectonics, local geomorphology, and volcano deformation.     

The dual-beam mini-DOAS technique—measurements of volcanic gas emission,plume height and plume speed with a single instrument

The largest error in determining volcanic gas fluxes using ground based optical remote sensing instruments is typically the determination of the plume speed, and in the case of fixed scanning instruments also the plume height. We here present a newly developed technique capable of measuring plume height, plume speed and gas flux using one single instrument by simultaneously collecting scattered sunlight in two directions. The angle between the two measurement directions is fixed, removing the need for time consuming in-field calibrations. The plume height and gas flux is measured by traversing the plume and the plume speed is measured by performing a stationary measurement underneath the plume. The instrument was tested in a field campaign in May 2005 at Mt. Etna, Italy, where the measured results are compared to wind fields derived from a meso-scale meteorological model (MM5). The test and comparison show that the instrument is functioning and capable of estimating wind speed at the plume height.     

Spectroscopic Characterization of Organic Structures and Organic‐Inorganic Interactions in Paper Mill Sludge

The organic composition and organic‐inorganic interaction in paper mill sludge (PS) solvent extracts (hexane, ethyl acetate, acetone and ethanol) and humic fractions, humic acid (HA) and humin (HU) were studied by electron paramagnetic resonance spectroscopy (EPR), proton and carbon‐13 nuclear magnetic resonance spectroscopy (¹H NMR; ¹³C NMR), Fourier‐transformed infrared spectroscopy (FTIR), and ultraviolet‐visible spectroscopy (UV‐vis). The strategy of fractionating the PS, sequentially, with organic solvents of increasing polarity is a reliable analytical procedure for humic substance sample separation because it results in more purified fractions. FTIR, ¹H NMR and ¹³C NMR results showed that hexane extract consisted mainly of aliphatic hydrocarbon structures. Their contents in the extracts decreased as the polarity of the extracting solvent increased and the content of oxygen functional groups increased. Carboxylic and carboxylate functional groups were found in the acetone extract, and ester and ether functions were predominantly found in the ethanol extract. EPR spectra revealed some Fe³⁺ complexes with rhombic structure (g₁ = 4.3; g₂ = 9.0) in the humic fractions and in all solvent extracts, except hexane. Quasi‐octahedral Fe³⁺ complexes (g = 2.3; ΔH_pp ≤ 400 G) were found in the HU fraction and in the acetone extract. The organic free radical content in the HA fraction was higher than the non‐fractionated PS sample and HU fraction.     

A concept for global access to information on geographical databases

Monitoring of the ecological as well as economical aspects of the planet Earth will in future require more sophisticated data obtaining systems (e. g. satellites) and data processing devices (e. g. GIS). In order to process the great amount of data, detailed information on geographical databases has to be provided in an easy way. In this paper a concept of an information system on geographical databases is presented which encompasses a centrally managed international directory with summary information as well as local information interfaces geographical databases. An information interface provides detailed information on the extent, structure and geographical meaning of the data stored in the geographical database belonging to it. To describe this information a conceptual scheme, based on an object oriented approach, is developed.     

Ecology of Quaternary benthic foraminiferal assemblages on the Amazon shelf,northern Brazil

The distribution of benthic foraminiferal microfauna recovered from two offshore transects on the Amazon shelf was studied. Eight box-core samples were collected along the inner, middle, and outer parts of the continental shelf. Each box-core sample was divided into 10 subsamples, of 1- to 5-cm intervals, in order to investigate the foraminiferal microhabitat preferences. The variations of salinity, oxygen, lithology, and sediment accumulation rates were used to evaluate ecological patterns. Four benthic foraminiferal assemblages identified in the study area characterize a record of oceanographic changes from early Holocene to the present. An abundant assemblage, with opportunistic species, was found near the river mouth. Two assemblages were identified northwest of the river mouth, with dominant epifaunal and infaunal species, respectively. A relict assemblage was encountered northwest of the river mouth.     

Microplastics as contaminants in the marine environment: a review

Since the mass production of plastics began in the 1940s, microplastic contamination of the marine environment has been a growing problem. Here, a review of the literature has been conducted with the following objectives: (1) to summarise the properties, nomenclature and sources of microplastics; (2) to discuss the routes by which microplastics enter the marine environment; (3) to evaluate the methods by which microplastics are detected in the marine environment; (4) to assess spatial and temporal trends of microplastic abundance; and (5) to discuss the environmental impact of microplastics. Microplastics are both abundant and widespread within the marine environment, found in their highest concentrations along coastlines and within mid-ocean gyres. Ingestion of microplastics has been demonstrated in a range of marine organisms, a process which may facilitate the transfer of chemical additives or hydrophobic waterborne pollutants to biota. We conclude by highlighting key future research areas for scientists and policymakers.     

Numerical modeling for analyzing thermal surface anomalies induced by underground coal fires

Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.