Archeointensity investigation on pottery vestiges from Puertas de Rolón, Capacha culture: In search for affinity with other Mesoamerican pre-Hispanic cultures

We report the results of a rock magnetic and archeointensity study on pottery fragments recovered at the archaeological site of Puertas de Rolón, Capacha culture (Colima), that is considered one of the most important pre-Classic cultural developments of western Mesoamerica, Mexico. Standard rock magnetic experiments were carried out in order to investigate the reliability of the ancient field strength recovered from studied materials. Six out of the seven analyzed fragments gave reliable intensity determinations. The mean archeointensity value obtained in this study is 35.3 ± 3.4 μT. It is in good agreement with another contemporaneous Mesoamerican mean archeointensity of 34.3 ± 1.1 μT obtained for El Opeño. Statistically similar rock-magnetic parameters between ceramics from El Opeño and Puertas de Rolón potsherds appear to be related to clay-sources with similar geological settings and weathering processes. Alternatively, ancient trade or interexchange between western (Capacha Culture) and eastern Mesoamerica locations, as it has been proposed earlier, seem to be supported by results obtained in this study.     

Predicting seasonal ocean variability around New Zealand using a coupled ocean-atmosphere model

We present a first assessment of the Sea Surface Temperature (SST) and 300m Heat Content (HC) ensemble mean skill of the Australian Community Climate and Earth-System Simulator-Seasonal v1.0 (ACCESS-S1) around New Zealand on seasonal timescales, using a set of retrospective ensemble forecasts for 1990-2012. This was verified against Reynolds AVHRR analysis and Bluelink ReANalysis 3.5 (BRAN3.5). For inshore areas with depth <300m, the model shows skill forecasting for summer at a lead time of 0 months, with 66% and 65% of model grid cells having correlation coefficients exceeding 0.6 for SST and 300m HC respectively. Regions of lower skill seem to be associated with the model representation of the complex and variable frontal systems around New Zealand, and an overly-strong response to the El Niño Southern-Oscillation (ENSO). Nevertheless, the skill of ACCESS-S1 around New Zealand suggests there is potential for the development of useful seasonal forecast products for the region.     

Trace element geochemistry of K-rich impact spherules from howardites

The howardite–eucrite–diogenite (HED) achondrites are a group of meteorites that probably originate from the asteroid Vesta. Howardites are complex polymict breccias that sometimes contain, in addition to various rock debris, impact melt glasses which show an impressive range of compositions. In this paper we report on the geochemistry and O isotopes of a series of 6 Saharan polymict breccias (4 howardites and 2 polymict eucrites), and on the trace element abundances of high-K impact spherules found in two of them, Northwest Africa (NWA) 1664 and 1769, which are likely paired.The high-K impact spherules found in the howardites NWA 1664 and NWA 1769 display remarkable trace element patterns. Compared to eucrites or howardites, they all show prominent enrichments in Cs, Rb, K, Li and Ba, strong depletion in Na, while the REE and other refractory elements are unfractionated. These features could not have been generated during impact melting of their host howardites, nor other normal HED target materials. The involvement of Na-poor rocks, and possibly rocks of granitic composition, appears likely. Although these lithologies cannot be well constrained at present, our results demonstrate that the surface of Vesta is certainly more diverse than previously thought. Indeed, despite the large number of available HED meteorites (about 1000 different meteorites), the latter are probably not sufficient to describe the whole surface of their parent body.     

Identifying sources of organic matter in sediments of shallow lakes using multiple geochemical variables

We analyzed ²¹⁰Pb-dated sediment cores from four relatively shallow lakes (z_max < 10 m) in the Upper Ocklawaha River Basin, Florida, USA to compare primary producer community structure before and after anthropogenic impacts. We measured physical and chemical sediment variables including density, organic matter (OM), water-soluble phosphorus, polyphosphate (Poly-P), total P (TP), total carbon to total nitrogen mass ratios of OM (TC:TN), biogenic silica (diatoms, sponge spicules), total amorphous silica, and stable carbon and nitrogen isotope ratios of bulk OM. Principal component analysis showed that diatom biogenic silica, TC:TN, Poly-P and TP displayed discernible stratigraphic changes associated with the shift in the primary producer community. We applied k-means cluster analysis to these variables to identify macrophyte-derived, transitional, and phytoplankton-derived sediments. Our approach provides an objective method for identifying sediment sources that may be applied to shallow lakes in other regions. The four study lakes shifted from a macrophyte-dominated state to a transitional state before major anthropogenic disturbances, and became phytoplankton-dominated after ~1950.     

Longues séries d'insolation homogénéisées en France

Prior to have long-term sunshine-duration series, data rescue effort has to be engaged. Eighteen series have been homogenized over the period 1931–2000. These series complete the set of diagnoses on climate change at a regional scale, confirm part of the diagnosis established for the temperatures, and offer new tracks for the mechanisms of climate change. To cite this article: J.-M. Moisselin, C. Canellas, C. R. Geoscience 337 (2005).     

Kinetics and mechanism of natural fluorapatite dissolution at 25 °C and pH from 3 to 12

The dissolution rates of natural fluorapatite (FAP), Ca₁₀(PO₄)₆F₂, were measured at 25 °C in mixed-flow reactors as a function of pH from 3.0 to 11.7, and aqueous calcium, phosphorus, and fluoride concentration. After an initial preferential Ca and/or F release, stoichiometric Ca, P, and F release was observed. Measured FAP dissolution rates decrease with increasing pH at 3 ? pH ? 7, FAP dissolution rates are pH independent at 7 ? pH ? 10, and FAP dissolution rates again decrease with increasing pH at pH ? 10. Measured FAP dissolution rates are independent of aqueous Ca, P, and F concentration at pH ≈ 3 and pH ≈ 10.Apatite dissolution appears to be initiated by the relatively rapid removal from the near surface of F and the Ca located in the M1 sites, via proton for Ca exchange reactions. Dissolution rates are controlled by the destruction of this F and Ca depleted surface layer. The destruction of this layer is facilitated by the adsorption/penetration of protons into the surface at acidic conditions, and by surface hydration at neutral and basic conditions. Taking into account these two parallel mechanisms, measured fluorapatite forward dissolution rates can be accurately described using

     

Fluid flow and sediment entrainment in the Garonne River bore and tidal bore collision

A detailed field study was carried out on a tidal bore to document the turbulent processes and sediment entrainment which occurred. The measured bore, within the Arcins Channel of the Garonne River (France), was undular in nature and was followed by well‐defined secondary wave motion. Due to the local river geometry a collision between the Arcins channel tidal bore and the bore which formed within the main Garonne River channel was observed about 800 m upstream of the sampling site. This bore collision generated a transient standing wave with a black water mixing zone. Following this collision the bore from the main Garonne River channel propagated ‘backward’ to the downstream end of the Arcins channel. Velocity measurements with a fine temporal resolution were complemented by measurements of the sediment concentration and river level. The instantaneous velocity data indicated large and rapid fluctuations of all velocity components during the tidal bore. Large Reynolds shear stresses were observed during and after the tidal bore passage, including during the 'backward' bore propagation. Large suspended sediment concentration estimates were recorded and the suspended sediment flux data showed some substantial sediment motion, consistent with the murky appearance of the flood tide waters. Copyright © 2015 John Wiley & Sons, Ltd.